H68黄铜形变再结晶温度及晶粒尺寸变化的研究

本研究拟通过对H68黄铜进行模拟形变并使用不同温度回火的方法,来探索H68黄铜的形变及再结晶温度特征,希望能为相关企业提供可参考的加工及热处理参数。研究发现供货态的H68黄铜需要加热后方能进行成型加工,否则会开裂。故此,采取将原料加热后轧制的方式获得了60%形变的H68黄铜板材,后选用不同回火温度再探索了其再结晶特征。结论:供货态H68黄铜须加热后方可形变加工;270℃无法使H68黄铜再结晶,350℃可以使其再结晶。随着温度升高,H68黄铜再结晶晶粒尺寸会明显变大。350℃再结晶后的H68黄铜金相组织均匀,晶粒尺寸较小;推荐使用该温度对加工成型的H68黄铜产品进行热处理,以获得较好的综合性能。

高等级管线钢的超细晶粒控制

论述了高强度管线钢超细晶粒控制的材料学原理和关键技术。分析了应变诱发相变和超细奥氏体强化相变这两种超细晶粒控制方法的原理、工艺设计原则以及工业化应用需要注意的问题。讨论分析的结果表明,轧制过程中积累足够大的应变是实现超细晶粒控制的关键。在工业生产中只能通过多道次轧制工艺逐个道次的应变累加实现所需的应变积累。而抑制道次之间的静态再结晶又是实现多道次应变积累的关键。对利用CSP工艺生产管线钢的特点和工艺设计原则进行了初步的探讨。指出了X100/X120管线钢超细贝氏体组织表征和细化机理研究的现状和存在的问题。

Microstructural evolution of 2026 aluminum alloy during hot compression and subsequent heat treatment

2026 aluminum alloy was compressed in a temperature range of 300-450 ℃ and strain rate range of 0.01-10 s^-1. The correlation between compression conditions and microstructural evolution after solution and aging heat treatment was investigated. It is found that the recrystallization and precipitation behavior after heat treatment are associated with the temperature compensated strain rate Z value during hot deformation. Under low Z parameter condition, a small quantity of free recrystallized grains are formed, and the well formed subgrains with clean high-angle boundaries and coarse precipitates seem to be remained during heat treatment. Under high Z parameter condition, a large number of fine equiaxed recrystallized grains are produced, and a high dislocation density with poorly developed cellularity and considerable fine dynamic precipitates are replaced by the well formed subgrains and relatively coarse precipitates after heat treatment. The average recrystallized grain size after heat treatment decreases with increasing Z value and a quantitative relation between the average grain size and the Z value is obtained.

Hot deformation behavior of Al-Zn-Mg-Cu-Zr aluminum alloys during compression at elevated temperature

The hot compression tests of Al-Zn-Mg-Cu-Zr aluminum alloys （7056 alloy and 7150 alloy） were performed in a temperature range from 300 to 450 °C and at strain rate range from 0.01 to 10 s-1. The results show that the true stress-true strain curves exhibit a peak stress at a critical strain, then the flow stresses decrease monotonically until high strains, showing a dynamic flow softening. The peak stresses depend on the temperature compensated strain rate, which can be represented by the Zener-Hollomon parameter Z in the hyperbolic-sine equation with hot deformation activation energy of 244.64 kJ/mol for 7056 alloy and 229.75 kJ/mol for 7150 alloy, respectively, while the peak stresses for the former are lower than those for the latter under the similar compression condition. The deformed microstructures consist of a great amount of precipitates within subgrains in the elongated grains at high Z value and exhibit well formed subgrains in the recrystallized grains at low Z value. The smaller subgrains and greater density of fine precipitates in 7150 alloy are responsible for the high peak stresses because of the substructural strengthening and precipitating hardening compared with 7056 alloy.

Effect of hot deformation conditions on grain structure and properties of 7085 aluminum alloy

The influences of deformation conditions on grain structure and properties of 7085 aluminum alloy were investigated by optical microscopy and transmission electron microscopy in combination with tensile and fracture toughness tests. The results show that the volume fraction of dynamic recrystallization increased with the decrease of Zener-Hollomon （Z） parameter, and the volume fraction of static recrystallization increased with the increasing of Z parameter. The strength and fracture toughness of the alloy after solution and aging treatment first increased and then decreased with the increase of Z parameter. The microstructure map was established on the basis of microstructure evolution during deformation and solution heat treatment. The optimization deformation conditions were acquired under Z parameters of 1.2×10^10-9.1×10^12.

Hot deformation behavior and microstructural evolution of beta C titanium alloy in β phase field

The hot deformation behavior of beta C titanium alloy in β phase field was investigated by isothermal compression testson a Gleeble？3800 thermomechanical simulator. The constitutive equation describing the hot deformation behavior was obtained anda processing map was established at the true strain of 0.7. The microstructure was characterized by optical microscopy （OM）,scanning electron microscopy （SEM） and electron back-scattered diffraction （EBSD） technique. The results show that the flow stressincreases with increasing strain rates, and decreases with increasing experimental temperatures. The calculated apparent activationenergy （167 kJ/mol） is close to that of self-diffusion in β titanium. The processing map and microstructure observation exhibit adynamic recrystallization domain in the temperature range of 900-1000 ℃ and strain rate range of 0.1-1 s^-1. An instability regionexists when the strain rate is higher than 1.7 s^-1. The microstructure of beta C titanium alloy can be optimized by proper heattreatments after the deformation in the dynamic recrystallization domain.

Hot deformation behavior and processing map of Cu-Ni-Si-P alloy

The high-temperature deformation behavior of Cu-Ni-Si-P alloy was investigated by using the hot compression test in the temperature range of 600-800 ℃ and strain rate of 0.01-5 s-1. The hot deformation activation energy, Q, was calculated and the hot compression constitutive equation was established. The processing maps of the alloy were constructed based on the experiment data and the forging process parameters were then optimized based on the generated maps for forging process determination. The flow behavior and the microstructural mechanism of the alloy were studied. The flow stress of the Cu-Ni-Si-P alloy increases with increasing strain rate and decreasing deformation temperature, and the dynamic recrystallization temperature of alloy is around 700 ℃. The hot deformation activation energy for dynamic recrystallization is determined as 485.6 kJ/mol. The processing maps for the alloy obtained at strains of 0.3 and 0.5 were used to predict the instability regimes occurring at the strain rate more than 1 s-1 and low temperature （〈650 ℃）. The optimum range for the alloy hot deformation processing in the safe domain obtained from the processing map is 750-800 ℃ at the strain rate of 0.01-0.1 s i The characteristic microstructures predicted from the processing map agree well with the results of microstructural observations.

Effect of nano TiN/Ti refiner on as-cast and hot-working microstructure of commercial purity aluminum

A novel type nano TiN/Ti composite grain refiner （TiN/Ti refiner） was prepared by high energy ball milling, and its effect on as-cast and hot-working microstructure of commercial purity aluminum （pure Al） was investigated. The results show that TiN/Ti refiner exhibits excellent grain refining performances on pure Al. With an addition of 0.2% TiN/Ti refiner, the average grain size of pure Al decreases to 82 μm, which is smaller than that of pure Ti and Al 5Ti 1B master alloy as refiners. The microstructure of weld joint of pure Al with 0.1% TiN/Ti refiner is fine equiaxed grains and the hardness of weld joint is higher than that of the base metal. For pure Al with 40% cold deformation and recrystallization at 250 °C for 1.0 h, the grains of the sample added 0.1% Ti powder have an obvious grain growth behavior. In contrast, oriented grains caused by deformation have been eliminated, and there is no obvious grain growth in pure Al refined with 0.1% TiN/Ti refiner, indicating that nano TiN in the refiner inhibits the growth of grain during recrystallization.

Effect of deformation temperature on microstructure and mechanical properties of 7055 aluminum alloy after heat treatment

The multi-pass hot compression test of 7055 aluminum alloy was performed at different temperatures and then the samples were heat treated by T6 heat treatment.The compressed samples were analyzed by OM and TEM.The results reveal that the average aspect ratio of the grains in the specimens compressed first decreases and then increases,the dislocation density decreases and subgrain diameter increases with the increase of deformation temperature.The effects of deformation temperature on the microstructure and mechanical properties of 7055 aluminum alloy after heat treatment were investigated by means of OM and mechanical property test.The results indicate that the deformation temperature significantly influences microstructure and mechanical property of 7055 aluminum alloy.The volume fraction of recrystallization grains presents a ＂fall-rise＂ pattern with the deformation temperature rising.The mechanical properties get better when the volume fraction of recrystallization grains decreases.Moreover,the volume fraction of recrystallization grain has a minimum value,appropriately 45%,and the sample exhibits the highest strength and elongation at the deformation temperature of 400 ℃.

Modeling of strain hardening and dynamic recrystallization of ZK60 magnesium alloy during hot deformation

The flow stress behavior of ZK60 alloy at elevated temperature was investigated. The strain hardening and dynamic recrystallization of the alloy were modeled by Kocks-Meching model and Avrami equation, respectively. A new constitutive equation during hot deformation was constructed to predict the flow stress considering the dynamic recrystallization. The results show that the flow stress curves predicted by the proposed equation have high correlation coefficients with the experimental data, which confirms that the developed model is accurate and effective to establish the flow stress equation of ZK60 magnesium alloy during hot deformation. Microstructure observation shows that dynamic recovery occurs in the initial stage of hot deformation. However, the microstructure turns to recrvstallization structure as the strain increases.

Hot deformation behavior of Al-9.0Mg-0.5Mn-0.1Ti alloy based on processing maps

Hot deformation behavior of extrusion preform of the spray-formed Al-9.0Mg-0.5Mn-0.1Ti alloy was studied using hot compression tests over deformation temperature range of 300-450 ℃ and strain rate range of 0.01-10 s-1. On the basis of experiments and dynamic material model, 2D processing maps and 3D power dissipation maps were developed for identification of exact instability regions and optimization of hot processing parameters. The experimental results indicated that the efficiency factor of energy dissipate （η） lowered to the minimum value when the deformation conditions located at the strain of 0.4, temperature of 300 ° C and strain rate of 1 s-1. The softening mechanism was dynamic recovery, the grain shape was mainly flat, and the portion of high angle grain boundary （〉15°） was 34%. While increasing the deformation temperature to 400 ° C and decreasing the strain rate to 0.1 s-1, a maximum value of η was obtained. It can be found that the main softening mechanism was dynamic recrystallization, the structures were completely recrystallized, and the portion of high angle grain boundary accounted for 86.5%. According to 2D processing maps and 3D power dissipation maps, the optimum processing conditions for the extrusion preform of the spray-formed Al？9.0Mg？0.5Mn？0.1Ti alloy were in the deformation temperature range of 340-450 ° C and the strain rate range of 0.01-0.1 s-1 with the power dissipation efficiency range of 38%？43%.

Deformation mechanism and softening effect of extruded AZ31 magnesium alloy sheet at moderate temperatures

The flow stress behavior of extruded AZ31 magnesium alloy sheet was investigated by means of compression tests at temperatures between 473 and 523 K and strain rates ranging from 0.001 to 1.0 s-1. The deformation activation energy of the sheet in extrusion direction （ED） was calculated, and the relationship between the softening effect and deformation mechanism was elucidated by optical microscopy and transmission electron microscopy. The results show that when the extruded AZ31 magnesium alloy samples were compressed at moderate temperatures in ED direction, the deformation activation energy is 174.18 kJ/mol, which means that dynamic recrystallization （DRX） is the main softening effect and is controlled by cross slip of thermal active dislocation. Dislocation slip is the main deformation mechanism in moderate-temperature deformation process except twinning. The main DRX effect at moderate temperatures can be considered to be continuous dynamic recrystallization accommodated with twinning DRX.

Dynamic recovery and dynamic recrystallization of NiTi shape memory alloy under hot compression deformation

Mechanical behavior of nickel？titanium shape memory alloy（NiTi SMA） under hot deformation was investigated according to the true stress—strain curves of NiTi samples under compression at the strain rates of 0.001-1 s-1 and at the temperatures of 600？1000℃.Dynamic recovery and dynamic recrystallization of NiTi SMA were systematically investigated by microstructural evolution.The influence of the strain rates,the deformation temperatures and the deformation degree on the dynamic recovery and dynamic recrystallization of NiTi SMA was obtained as well.NiTi SMA was characterized by the combination of dynamic recovery and dynamic recrystallization at 600℃ and 700℃,but the complete dynamic recrystallization occurred at other deformation temperatures.Increasing the deformation temperatures or decreasing the stain rates leads to larger equiaxed grains.The deformation degree has an important influence on the dynamic recrystallization of NiTi SMA.There exists the critical deformation degree during the dynamic recrystallization of NiTi SMA,beyond which the larger deformation degree contributes to obtaining the finer equiaxed grains.

Microstructure and texture characterization of superplastic Al-Mg-Li alloy

A novel thermomechanical processing was developed for producing fine grained Al-Mg-Li alloy sheets. The influences of static recrystallization annealing on the grain structure and superplastic behavior were investigated. The results show that the refined microstructure has a variation in the distribution of grain size, shape and texture across the normal direction of the sheet. The surface layer （SL） has fine, nearly equiaxed grains with a rotated cUbeND {001 }（310） orientation, whereas the center layer （CL） has coarse, elongated grains with a portion of a fiber orientation. Increasing static recrystallized temperature results in grain growth in the full thickness, decreasing of grain aspect ratio in the center layer, texture sharpening in the surface layer, but weakening in the center layer as well as decreasing of superplastic elongation. Increasing the annealing temperature also produces an sharpening of the rotated cube {001}（310） component and a decreasing of the a fiber texture in the full thickness of the sheet. The formation mechanisms of recrystallization texture at various temperatures and layers were discussed.

Hot compression behavior and deformation microstructure of Mg-6Zn-1Al-0.3Mn magnesium alloy

The hot compression behavior of a wrought Mg-6Zn-1Al-0.3Mn magnesium alloy was investigated using Gleeble test at 200-400 °C with strain rates ranging from 0.01 to 7 s-1. The true stress-strain curves show that the hot deformation behavior significantly depends on the deformation temperature and strain rate. The calculated hot deformation activation energy Q is 166 kJ/mol with a stress exponent n=5.99, and the constitutive equation is deduced to be ε＆ =3.16×1013[sinh（0.010σ）]5.99exp [-1.66×105/（RT）]· Deformation microstructure shows that the incompletely dynamically recrystallized grains can be found at grain boundaries and twins with the strain rates ranging from 0.01 to 1 s^-1 at 250 °C, and completely dynamic recrystallization occurs when the temperature is 350 °C or above during hot compression, the size of recrystallized grains decreases with the increment of the strain rate at the same temperature. The relatively suitable deformation condition is considered temperature 330-400 °C and strain rate of 0.01-0.03 s-1, and temperature of 350 °C and strain rate of 1 s-1.

Rate controlling mechanisms in hot deformation of 7A55 aluminum alloy

The hot deformation behavior of 7A55 aluminum alloy was investigated at the temperature ranging from 300 ℃ to 450 ℃ and strain rate ranging from 0.01 s-1 to 1 s-1 on a Gleeble-3500 simulator. Processing maps were established in order to apprehend the kinetics of hot deformation and the rate controlling mechanism was interpreted by the kinetic rate analysis obeying power-law relation. The results indicated that one significant domain representing dynamic recrystallization （DRX） existed on the processing maps and lying in 410-450 ＆#176;C and 0.05-1 s-1. The conclusions of kinetic analysis correlated well with those obtained from processing maps. The apparent activation energy values calculated in the dynamic recrystallization （DRX） domain and the stability regions except dynamic recrystallization （DRX） domain were 91.2 kJ/mol and 128.8 kJ/mol, respectively, which suggested that grain boundary self-diffusion and cross-slip were the rate controlling mechanisms.

Microstructure evolution of Zn-8Cu-0.3Ti alloy during hot deformation

The hot deformation behavior of homogenized zinc alloy was investigated through uniaxial compression test on a Gleeble-1500 thermal-mechanical simulator within a temperature range of 230-380°C and a strain rate range of 0.01-10 s -1 ,the corresponding flow curves and their characters were determined and analyzed,and microstructures were studied by optical,SEM and TEM microscopy.The results indicated that the microstructure evolution of zinc alloy during hot deformation involves the spheroidization of the phase of TiZn15,coarsening of the precipitated phase and dynamic recrystallization（DRX）of the phase of matrix,leading to the formation of the polyphase（η＋ε＋TiZn15）structure.The spheroidization of the phase of TiZn15 during hot deformation was beneficial to the particle nucleation stimulated and then promoted to DRX of matrix.The dynamic recrystallization grain size of the matrix phase decreased firstly and then increased with elevating the temperature,and the degree of DRX became more complete when the strain rate and strain became larger.Hot deformation accelerated the diffusion of Cu atom,which resulted in the coarsening of the precipitated phase.Thus,the microstructure was refined owing to the pinning effect of the precipitated phase.

Microstructure and texture evolution in titanium subjected to friction roll surface processing and subsequent annealing

Commercial purity and high purity titanium sheets were initially strained by a new technique, named as friction roll surface processing （FRSP）. Severe strain was imposed into the surface layer and strain gradient was formed through the thickness of the sheet. The microstructure and texture in as-strained state were investigated by optical microscopy and X-ray diffraction technique On the surface of the sheets, ultra-fine grains were found to have a sharp texture with a preferred orientation strongly related to the FRSP direction. The evolution of microstructure and crystallographic texture of FRSPed samples during recrystallization were also studied by electron back-scattered diffraction （EBSD） technique after being annealed at selected temperatures and time. The results indicated that the preferred orientations resulting from FRSP and annealing in the surface layer were formed during rolling and its recrystallization textures were reduced by FRSP. In addition, the texture evolved stably without change in main components during the annealing.

Dynamic recrystallization behavior of burn resistant titanium alloy Ti-25V-15Cr-0.2Si

Dynamic recrystallization (DRX) behavior in β phase region for the burn resistant titanium alloy Ti?25V?15Cr?0.2Si was investigated with a compression test in the temperature range of 950?1100 °C and the strain rate of 0.001?1 s?1. The results show that deformation mechanism of this alloy in hot deformation is dominated by DRX, and new grains of DRX are evolved by bulging nucleation mechanism as a predominant mechanism. DRX occurs more easily with the decrease of strain rate and the increase of deformation temperature. Grain refinement is achieved due to DRX during the hot deformation at strain rate range of 0.01?0.1 s?1 and temperature range of 950?1050 °C. DRX grain coarsening is observed for the alloy deformed at the higher temperatures of 1100 °C and the lower strain rates of 0.001 s?1. Finally, in order to determine the recrystallized fraction and DRX grain size under different deformation conditions, the prediction models of recrystallization kinetics and recrystallized grain sizes were established.

Microstructure evolution and mechanical properties of ZK60 magnesium alloy produced by SSTT and RAP route in semi-solid state

The microstructure evolution and mechanical properties of a ZK60 magnesium alloy produced by the semi-solid thermal transformation （SSTT） route and the recrystallization and partial melting （RAP） route were studied, respectively. The microstructure evolution during partial remelting was studied at different temperatures for different time. The tensile mechanical properties of thixoformed components by the two routes at room temperature were examined. The results show that coalescence is dominant in the SSTT alloy and Ostwald ripening is dominant in the RAP alloy. Compared with the SSTT route, the RAP route can produce finer semi-solid microstructure under the similar isothermal holding condition. The microstructure of the RAP alloy is much more spheroidized compared with the SSTT alloy. Thixoforming for the ZK60 magnesium alloy produced by the SSTT and RAP route results in successful filling of the die, and the thixoforming process improves the mechanical properties of ZK60 magnesium alloy. The RAP alloy shows significantly advantageous mechanical properties over that of the SSTT alloy.