网络化聚吡咯/聚氨酯复合材料的抗静电性能研究

导电剂填充树脂制备高分子抗静电复合材料时,其添加量直接决定着复合材料的导电率,但导电剂的微观形态深刻影响着导电通道的效能。利用软模板制备不同网络结构特征的聚吡咯(PPy)材料,将其与聚氨酯(PU)通过溶液共混制备PPy/PU复合材料,考察PPy的结构差异对复合材料电导率的影响。利用线径在20~35 nm和30~50 nm范围的网络化PPy材料,分析了其添加量为1%~3%(质量分数,下同)时所制备的PPy/PU复合材料的电导率,对比PPy颗粒制得复合材料电导率均达到了10^(-7) S/m数量级。复合材料在100%~500%形变下,导电率均出现降低,但网络化PPy/PU复合材料仅下降1个数量级,其中1%添加量的网络化PPy/PU复合材料与3%PPy颗粒制备PU复合材料的导电率相当。结果表明,网络化导电剂在复合材料形变条件下,其原生网络维持了复合材料中导电通道的完整性,使得材料在形变下依然保持较高的电导率。

复合材料结构受横向载荷作用的强度问题

众所周知, 各向同性材料结构的极限分析与设计只需一个应力强度条件(如采用第一或者第四强度理论)。但是在复合材料的情况下, 问题要复杂得多。本文中提出除了一个应力强度条件之外, 还须补充一个临界变形条件或者称为临界刚度条件才可以确定复合材料结构在横向载荷作用下的极限破坏状态的观点。对本文作者近期在这方面的研究工作作了介绍, 尤其侧重介绍如何确定复合材料结构的极限承载能力, 并指出复合材料结构受有横向载荷作用的一些有待研究解决的紧迫问题。

Analysis of granular assembly deformation using discrete element method

The discrete element method is used to simulate specimens under three different loading conditions（conventional triaxial compression,plane strain,and direct shear）with different initial conditions to explore the underlying mechanics of the specimen deformation from a microscale perspective.Deformations of specimens with different initial void ratios at different confining stresses under different loading conditions are studied.Results show that the discrete element models successfully capture the specimen deformation and the strain localization.Particle behaviors including particle rotation and displacement and the mesoscale void ratio distributions are used to explain the strain localization and specimen deformation.It is found that the loading condition is one of the most important factors controlling the specimen deformation mode.Microscale behavior of the granular soil is the driving mechanics of the macroscale deformation of the granular assembly.

Hot deformation behavior and constitutive modeling of Q345E alloy steel under hot compression

Q345E as one of typical low alloy steels is widely used in manufacturing basic components in many fields because of its eminent formability under elevated temperature. In this work, the deformation behavior of Q345E steel was investigated by hot compression experiments on Gleeble-3500 thermo-mechanical simulator with the temperature ranging from 850 ℃ to 1150 ℃ and strain rate ranging from 0.01 s-1 to 10 s-1. The experimental results indicate that dynamic softening of Q345E benefits from increasing deformation temperature and decreasing strain rate. The mathematical relationship between dynamic softening degree and deformation conditions is established to predict the dynamic softening degree quantitatively, which is further proved by some optical microstructures of Q345E. In addition, the experimental results also reveal that the stress level decreases with increasing deformation temperature and decreasing strain rate. The constitutive equation for flow stress of Q345E is formulated by Arrihenius equation and the modified Zener-Hollomon parameter considering the compensation of both strain and strain rate. The flow stress values predicted by the constitutive equation agree well with the experimental values, realizing the accurate prediction of the flow stress of Q345E steel under hot deformation.

Design concerns of room and pillar retreat panels

Why do some room and pillar retreat panels encounter abnormal conditions？ What factors deserve the most consideration during the planning and execution phases of mining and what can be done to mitigate those abnormal conditions when they are encountered7 To help answer these questions, and to determine some of the relevant factors influencing the conditions of room and pillar （R ＆ P） retreat min- ing entries, four consecutive R ＆ P retreat panels were evaluated. This evaluation was intended to rein- force the influence of topographic changes, depth of cover, multiple-seam interactions, geological conditions, and mining geometry. This paper details observations were made in four consecutive R ＆ P retreat panels and the data were collected from an instrumentation site during retreat mining. The pri- mary focus was on the differences observed among the four panels and within the panels themselves. The instrumentation study was initially planned to evaluate the interactions between primary and secondary support, but produced rather interesting results relating to the loading encountered under the current mining conditions. In addition to the obse^ation and ｜ll^trumentation, numerical modeling was per- formed to evaluate the stress condi~!ons. Both the LaModel 3.0 and Rocscience Phase 2 programs were used to evaluate these four panels, The results of both models indicated a drastic reduction in the vertical stresses experienced in these panels due to the full extraction mining in overlying seams when compared to the full overburden load. Both models showed a higher level of stress associated with the outside entries of the panels. These results agree quite well with the observations and instrumentation studies performed at the mine. These efforts provided two overarching conclusions concerning R ＆ P retreat mine planning and execution. The first was that there are four areas that should not be overlooked during R ＆ P retreat mining： topographic relief, multiple^seaPa stress relief, stress concentrations near the gob edge, and geologic changes in the immediate roof. The second is that in order to successfully retreat an R ＆ P panel, a three-phased approach to the design and analysis of the panel should be conducted： the planning phase, evaluation phase, and monitoring phase.

关于字形规范的几个问题

文章把字形的笔画变化分为基础形变和条件形变两种基本类型 ,指出二者关涉的社会对象不同。文章还讨论了新旧字形与繁简字、正异字的关系 ,考察了新旧字形的笔数计算、笔顺、条件形变和部件、结构的归整等具体问题 ,对制定穷尽性的规范汉字字形表提出了建议。

Experimental investigation into stress-relief characteristics with upward large height and upward mining under hard thick roof

According to geological conditions of No. 3 and No. 4 coal seams （namely A3 and B4） of the Pan＇er coal mine and the parameters of panels 11223, 11224, and 11124 with fully-mechanical coal mining, we built 2D similar material simulation and FLAC3D numerical simulation models to investigate the development of mining-induced stress and the extraction effect of pressure-relief gas with large height and upward mining. Based on a comprehensive analysis of experimental data and observations, we obtained the deformation and breakage characteristics of strata overlying the coal seam, the development patterns of the mining-induced stress and fracture, and the size of the stress-relief area. The stress-relief effect was investigated and analyzed in consideration with mining height and three thick hard strata. Because of the group of three hard thick strata located in the main roof and the residual stress of mined panel 11124, the deformation, breakage, mining-induced stress and fracture development, and the stress-relief coefficient were discontinuous and asymmetrical. The breakage angle of the overlying strata, and the compressive and expansive zones of coal deformation were mainly controlled by the number, thickness, and strength of the hard stratum. Compared with the value of breakage angle derived by the traditional empirical method, the experimental value was lower than the traditional results by 3°-4°below the hard thick strata group, and by 13°-19° above the hard thick strata group. The amount of gas extracted from floor drainage roadway of B4 over 17 months was variable and the amount of gas per month differed considerably, being much smaller when panel 11223 influenced the area of the three hard thick strata. Generally, the stress-relief zone of No. 4 coal seam was small under the influence of the hard thick strata located in the main roof, which played an important role in delaying the breakage time and increasing the breakage space. In this study we gained understanding of the stress-relief mechanism influenced by the hard thick roof. The research results and engineering practice show that the main roof of the multiple hard thick strata is a critical factor in the design of panel layout and roadways for integrated coal exploitation and gas extraction, provides a theoretical basis for safe and high-efficient mining of coal resources.

Elastoplastic model for discontinuous shear deformation of deep rock mass

Deep rock mass possesses some unusual properties due to high earth stress,which further result in new problems that have not been well understood and explained up to date.In order to investigate the deformation mechanism,the complete deformation process of deep rock mass,with a great emphasis on local shear deformation stage,was analyzed in detail.The quasi continuous shear deformation of the deep rock mass is described by a combination of smooth functions:the averaged distribution of the original deformation field,and the local discontinuities along the slip lines.Hence,an elasto-plastic model is established for the shear deformation process,in which the rotational displacement is taken into account as well as the translational component.Numerical analysis method was developed for case study.Deformation process of a tunnel under high earth stress was investigated for verification.

Surface movement and deformation characteristics due to high- intensive coal mining in the windy and sandy region

As China＇s energy strategy moving westward, the surface movement and deformation characteristics due to high-intensive coal mining in the windy and sandy region become a research hotspot. Surface movement observation stations were established to monitor movement and deformation in one super-large working face. Based on field measurements, the surface movement and deformation characteristics were obtained, including angle parameters, subsidence prediction parameters, etc. Besides, the angle and subsidence prediction parameters in similar mining areas are summarized; the mechanism of surface movement and deformation was analyzed with the combination of key stratum theory, mining and geological conditions. The research also indicates that compared with conventional working faces, uniform subsidence area of the subsidence trough in the windy and sandy region is larger, the trough margins are relative steep and deformation values present convergence at the margins, the extent of the trough shrink towards the goaf and the influence time of mining activities lasts shorter; the overlying rock movement and breaking characteristics presents regional particularity in the study area, while the single key stratum, thin bedrock and thick sand that can rapidly propagate movement and deformation are the deep factors, contributing to it.

Deformation features and failure mechanism of steep rock slope under the mining activities and rainfall

Underground mining activities and rainfall have potential important influence on the initiation and reactivation of the slope deformations,especially on the steep rock slope. In this paper,using the discrete element method(UDEC),numerical simulation was carried out to investigate deformation features and the failure mechanism of the steep rock slope under mining activities and rainfall. A steep rock slope numerical model was created based on a case study at the Wulong area in Chongqing city,China. Mechanical parameters of the rock mass have been determined by situ measurements and laboratory measurements. A preliminary site monitoring system has been realized,aiming at getting structure movements and stresses of unstablerock masses at the most significant discontinuities. According to the numerical model calibrated based on the monitoring data,four types of operation conditions are designed to reveal the effect of mining excavation and extreme rainfall on the deformation of the steep rock slope.

Morpho-Anatomical Changes in Roots of Chickpea （Cicer arietinum L.） under Drought Stress Condition

Chickpea （Cicer arietinum L.） is a crop cultivated in semi-arid and rainfed areas of Pakistan and it experiences terminal drought stress. In this paper, the morpho-anatomical study regarding roots of chickpea was carried out to investigate the drought adaptation strategies. Twelve cultivars of chickpea were grown in pots under drought stress of 70% and 35% field capacity in addition to control （100%）. Root segments of mature chickpea plants were sectioned in 2 cm from root-shoot junction and used for making transverse sections. The development of sleeve and stele tissues and their proportion were markedly influenced by moisture availability to the root system. Roots length, flesh and dry weight, and number of secondary roots were decreased under field capacity of 70% and 35% as compared to control in 12 cultivars of chickpea. Root epidermis and cortex of CH47/04 consisted of cells with thickened walls and with 2-3 cell layers of sclerenchymatous cells below the epidermis. Increased number of medullary rays and high vascular region was observed in cultivars CH120/04, CH47/04, CH587/05 and CH87/02. Anatomical studies showed that CH47/04 was highly tolerant among 12 cultivars of chickpea, while CH587/05 and CH87/02 behaved moderately under both levels of drought stress （70% and 35% field capacity）.

New approach for modeling flow stress of aluminum alloy 6A10 considering temperature variation

The flow stress behavior of aluminum alloy 6A10 was studied by the hot compression tests at temperatures from 350℃ to 550 ℃ and strain rates from 0.1 s^-1 to 10 s^-1 with Gleeble-1500 thermo-mechanical simulator. The result demonstrates that the temperatures of specimen differ from initial ones affected by deformation conditions, and that the softening mechanism is dynamic recovery. A new approach was proposed to analyze the flow stress character directly from actual stress, strain, temperature and strain rate data, without performing any previous flow stress correction caused by temperature variation. Comparisons between the experimental and predicted results confirm that the established flow stress model can give reasonable estimation, indicating that the mentioned approach can be used in flow stress model analysis of the materials that undergo only dynamic recovery based on the data obtained under variable deformation temperature.

Deformation and Failure Mechanism of Phyllite under the Effects of THM Coupling and Unloading

Although the study of TM(Thermo Mechanics),HM(Hydraulic-Mechanics) and THM(Thermo-Hydraulic-Mechanics) coupling under a loading test have been under development,rock failure analysis under THM coupling and unloading is an emerging topic.Based on a high temperature triaxial unloading seep test for phyllite,this paper discusses the deformation and failure mechanism of phyllites under the "H M,T→H,T→M" incomplete coupling model with unloading conditions.The results indicate that the elastic modulus and initial permeability decrease and the Poisson's ratio increases with increasing temperature;the elastic modulus decreases and the Poisson's ratio and initial permeability increase with increasing water pressure.During the unloading process,rock penetrability is small at the initial elastic deformation phase,but the penetrability increases near the end of the elastic deformation phase;mechanisms involving temperature and water pressure affect penetrability differently.Phyllite failure occurs from the initial thermal damage of the rock materials,splitting and softening(which is caused by pore water pressure),and the pressure difference which is formed from the loading axial pressure and unloading confining pressure.The phyllite failure mechanism is a transtensional(tension-shearing) failure.

The Preparation of Ultra-fine Calcium Carbonate and Its properties Study

This article adopts the double decomposition method, select the appropriate experimental conditions and operation process, respectively add appropriate amount of sodium carboxymethyl cellulose （CMC） as crystal control agent to study the influence of crystalline of ultrafine calcium carbonate. The experimental results show that the different concentrations of CMC as crystal control agent on the morphology and crystal structure of calcium carbonate have obvious effect, which emerge morphology change from square to spherical, crystalline transition from calcite to aragonite. Thus, the results provide experimental data and theoretical basis for the use of different additives, and provide experimental basis and feasible solution for this kind of reaction.

Effects of deformation parameters on formation of pro-eutectoid cementite in hypereutectoid steels

Brittle pro-eutectoid cementite that forms along prior-austenite in hypereutectoid steels is deleterious to mechanical properties. The optimum process parameters which suppress the formation of pro-eutectoid cementite in hypereutectoid steels with carbon content in the range of 0.8%-1.3% in mass fraction, were investigated. Pro-eutectoid cementite formation is effectively hindered by increasing the deformation temperature and decreasing the amount of strain. Transformation at lower temperatures close to the nose of the cooling-transformation diagram also reduces the tendency of the formation of pro-eutectoid cementite. Control of prior-austenite grain size and grain boundary conditions is important. Due to larger number of nucleation sites, finer prior-austenite grain size results in the acceleration of transformation to pro-eutectoid cementite. However, large prior-austenite and straight boundaries lead to less nucleation sites of pro-eutectoid cementite. The cooling rate and carbon content should be reduced as much as possible. The transformation temperature below 660 °C and the strain of 0.5 at deformation temperature of 850 °C are suggested.

Hot compression deformation characteristics of Mg-Mn alloys

The hot deformation behaviors of solution treated Mg-1.8Mn-0.4Er-0.2Al alloys were investigated by means of compression tests on Gleeble-1500 in strain rate range of 0.01-10s-1,deformation temperature range of 250-450℃ and a true strain of 0.6.The constitutive relationships among flow stress,strain rate and deformation temperature were described by Arrhenius-type equations,based on the fact that the material constants could be calculated under a wide range of strains.The results show that the flow stress of the experimental alloy decreases with temperature increasing and strain rate decreasing.Under the experimental conditions,the products of constant α and n in the constitutive equation are stable within certain strains,and the deformation activation energy ranges from 160 to 220 kJ/mol.It is proved that the values of calculated flow stress are close to the experimental results with average error of 2.01%.

Ultrasonic elastic characteristics of five kinds of metamorphic deformed coals under room temperature and pressure conditions

The calibration of the elastic characteristics of deformed coals is essential for seismic inversion of such units, because the prediction of coal deformation is essential for both mining safety and methane production. Therefore, many samples of broken and mylonitic deformed coal were tested with ultrasonic waves in the laboratory. These samples came from four mining areas: the Huainan, Pingdingshan, Hebi and Jiaozuo coal mines, which present five different metamorphic ranks shown as cylinders striking across circular limits of steel. Under normal pressures and temperatures, ultrasonic P- and S-wave tests show that the velocities, quality factors, and elastic moduli of the deformed coals were greatly reduced compared with undeformed coals. Also, some correlation was found between the P- and S-wave velocities in the deformed coals. However, there is no evidence of linear correlations between velocity and density, velocity and quality factor, or the quality factors of P- and S-waves. Compared with the elastic characteristics of undeformed coals, such as P- and S-wave velocity ratios or Poisson's ratio, those of deformed coals generally decrease and the P-wave quality factors are less than those of S-waves. Moreover, the analysis of the relationship between pore structure and elastic modulus shows a better correlation between the P- and S-wave velocities and effective porosity, pore volume and specific surface area. Also, there are similar relationships between the pore structure and the Young's and shear moduli. However, there are no such correlations with other moduli. Correlations between these elastic moduli, pore structure, coal rank and density were not found for the various samples of deformed coals, which is consistent with only structural destruction occurring in the deformed coals with other physical properties remaining unchanged. The experimental results show that it is possible to predict the deformation of coals with multi-component seismic elastic inversion.

Effect of high temperature on compression property and deformation recovery of ceramic fiber reinforced silica aerogel composites

Ceramic fiber reinforced silica aerogel composites are novel insulation materials in the thermal protection field for hypersonic vehicles. Before the aerogel composites are applied in load-bearing structures, it is necessary to investigate their mechanical properties including load-bearing and deformation recovery capabilities. High temperature from service conditions will have important effects on the mechanical properties of thermal protection materials. In this paper, compression tests including loading and unloading stages were conducted for ceramic fiber reinforced silica aerogel composites at room temperature and elevated temperatures(300℃, 600℃ and 900℃). Influences of thermal exposure to high temperature and high temperature service environment on the compression property and deformation recovery were both investigated. Scanning electron microscopy(SEM), Fourier transform infrared spectroscopy(FT-IR) and X-ray diffraction(XRD) were applied to help understand the mechanisms of mechanical property variations. The experimental results show that the compression modulus and strength both increase with the increasing thermal exposure temperature and testing temperature,but the deformation recovery capability decreases. The micro structure changes caused by thermal sintering are considered as the main reason for the property variations.Viscous flow and matter transport due to high temperature resulted in the fusion of aerogel particles. This made the particle skeleton thicker and stronger, which led to higher stiffness and strength of the composites. However, matrix cracks induced by the formation and fracture of larger pores made unrecoverable deformation more serious. In the tests at elevated temperatures,the aggregation of aerogel particles in a fused state got more severe because of the addition of mechanical load. As a result, the degradation of deformation recovery capability became more significant.

Study on Drying Characteristic of Chinese Fir and Poplar Plantation Wood

The drying characteristic was studied for plantation wood of Chinese fir and poplar, which are typical plantation wood of southern and northern part of China, respectively. Through 100-degree-method the drying characteristic and basic drying condition were gotten, then drying schedule was developed for practical drying, the results showed that the drying schedule is suitable for Chinese fir and poplar plantation lumber, but shrinkage is large. The recommendation was made that enough dead weight is needed to decrease shrinkage in drying process. The drying quality of the two species of lumber is good in conventional drying method.