The research on the supramolecular hyperbranched polymers(SHPs) that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications. Here we ...The research on the supramolecular hyperbranched polymers(SHPs) that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications. Here we demonstrate a simple approach to prepare POSS-embedded supramolecular hyperbranched polymers(POSS-SHPs) with varied morphology and size by controlling monomer concentration and mixed solvents. The SHPs formations can further transfer into the core-shell structured micelles by addition of competitive guests based on the double supramolecular driving forces.展开更多
基金supported by the National Natural Science Foundation of China(21504096,21674120,21474115)Ministry of Science and Technology of China(2014CB932200)“Young Thousand Talents”Program
文摘The research on the supramolecular hyperbranched polymers(SHPs) that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications. Here we demonstrate a simple approach to prepare POSS-embedded supramolecular hyperbranched polymers(POSS-SHPs) with varied morphology and size by controlling monomer concentration and mixed solvents. The SHPs formations can further transfer into the core-shell structured micelles by addition of competitive guests based on the double supramolecular driving forces.
