The study concerns the use of MgCl2-supported high-activity Ziegler-Natta catalysts for the polymerization of ethylene.In particular,two types of catalysts were investigated,which were N-catalyst（BRICI）and improved ...The study concerns the use of MgCl2-supported high-activity Ziegler-Natta catalysts for the polymerization of ethylene.In particular,two types of catalysts were investigated,which were N-catalyst（BRICI）and improved polyethylene catalyst.The effects of catalyst structure on kinetic behavior were examined.The distribution of active centers in these catalysts was investigated by energy dispersive analysis by X-rays（EDAX）,and morphologies of catalyst particles and polymer products were examined by scanning electron microscope（SEM）.Hydrogen response and copolymerization performance were investigated and compared with the two catalysts.The results were correlated with the kinetic behavior of the two catalysts and appropriate models for polymer particle growth were presented.The improved polyethylene catalyst showed higher activity,better hydrogen response and copolymerization performance.展开更多
In this paper, a new method based on morphologic research named reconstruction cross-component removal （RCCR） is developed to analyze geometrical scattering waves of an underwater target. Combining the origin of the...In this paper, a new method based on morphologic research named reconstruction cross-component removal （RCCR） is developed to analyze geometrical scattering waves of an underwater target. Combining the origin of the cross-component in Wigner-ViUe distribution, the highlight model of target echoes and time-frequency features of linear frequency-modulated signal can remove cross-components produced by multiple component signals in Wigner-Ville distribution and recover the auto-components of output signals. This method is used in experimental data processing, which can strengthen the real geometric highlights, and restrain the cross components. It is demonstrated that this method is helpful to analyze the geometrical scattering waves, providing an effective solution to underwater target detection and recognition.展开更多
文摘The study concerns the use of MgCl2-supported high-activity Ziegler-Natta catalysts for the polymerization of ethylene.In particular,two types of catalysts were investigated,which were N-catalyst（BRICI）and improved polyethylene catalyst.The effects of catalyst structure on kinetic behavior were examined.The distribution of active centers in these catalysts was investigated by energy dispersive analysis by X-rays（EDAX）,and morphologies of catalyst particles and polymer products were examined by scanning electron microscope（SEM）.Hydrogen response and copolymerization performance were investigated and compared with the two catalysts.The results were correlated with the kinetic behavior of the two catalysts and appropriate models for polymer particle growth were presented.The improved polyethylene catalyst showed higher activity,better hydrogen response and copolymerization performance.
基金Foundation item： Supported by the National Natural Science Foundation of China, under Grant No.51279033 and the Natural Science Foundation of Heilongjiang Province, China, under Grant No. F201346.
文摘In this paper, a new method based on morphologic research named reconstruction cross-component removal （RCCR） is developed to analyze geometrical scattering waves of an underwater target. Combining the origin of the cross-component in Wigner-ViUe distribution, the highlight model of target echoes and time-frequency features of linear frequency-modulated signal can remove cross-components produced by multiple component signals in Wigner-Ville distribution and recover the auto-components of output signals. This method is used in experimental data processing, which can strengthen the real geometric highlights, and restrain the cross components. It is demonstrated that this method is helpful to analyze the geometrical scattering waves, providing an effective solution to underwater target detection and recognition.
