The formation mechanisms and growth kinetics of Al3 Ni and Al3Ni2 in Ni-Al diffusion couple prepared by electrodeposition of Ni on Al substrate were investigated. The nickel coating with 20 μm thickness was applied o...The formation mechanisms and growth kinetics of Al3 Ni and Al3Ni2 in Ni-Al diffusion couple prepared by electrodeposition of Ni on Al substrate were investigated. The nickel coating with 20 μm thickness was applied on 6061 aluminum alloy by direct current electroplating. The samples were then heat-treated for different durations at 450, 500 and 550 °C under argon atmosphere. The intermetallic phases were identified by means of scanning electron microscopy（SEM）, energy dispersive spectrometry（EDS） and X-ray diffraction（XRD）. The results showed that the formation of intermetallic phases consisted of two important steps. The first step was the lateral growth of intermetallic phase from separate sites, resulting in the formation of a continuous layer. The second step was the growth of the continuous intermetallic layer in the direction perpendicular to the interface. However, excessive increase in thickness of intermetallic phases led to the detachment of reaction products, i.e., Al3 Ni and Al3Ni2, from the substrate. It was also observed that aluminum was the dominant diffusing element during Al3 Ni growth, while nickel diffusion was dominant during Al3Ni2 growth. The growth kinetics of both Al3 Ni and Al3Ni2 phases obeyed a parabolic law.展开更多
This paper describes changes in the structure of buds and vascular cambium as well as in protein content of one-year-old dormant branches of Eucommia ulmoides Oliv. in water-culture conditions. Results confirm the exi...This paper describes changes in the structure of buds and vascular cambium as well as in protein content of one-year-old dormant branches of Eucommia ulmoides Oliv. in water-culture conditions. Results confirm the existence of 2 quiescences (Q1, Q2) and 1 rest (R) phases in this tree during the dormancy period. In the R time, the E. ulmoides cambium was unable to reactivate even though the tree was subjected to exogenous IAA, suitable temperature or required luminosity. Furthermore, pistillate trees entered the dormant phase earlier than staminate ones. The protein content in the bark during Q1 increased significantly ( P < 0.01), but drastically decreased in the R period, before rising up again at the onset of Q2 ( P < 0.01). Even though the change pattern of protein content was similar, its occurrence is much earlier in staminate than in pistillate plants. SDS-PAGE revealed a 'special' protein band of 11.8 kD in the transitional Q1-R-Q2 stages. This 'special' protein bands would be related to the cambial dormancy and to the regulation of the Q1-R-Q2 transition.展开更多
Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al inte...Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al interface;most of TiAl_(3) grains were fine equiaxed with average sizes ranging from hundreds of nanometers to several microns and the TiAl_(3) grain size increased with increasing annealing time and/or temperature,but the effect of annealing temperature on the TiAl_(3) grain size was far greater than that of annealing time.The growth of the TiAl_(3) phase consisted of two stages.The initial stage was governed by chemical reaction with a reaction activation energy of 195.75 kJ/mol,and the reaction rate constant of the TiAl_(3) phase was larger as the Ti/Al interface was bonded with fresh surfaces.At the second stage,the growth was governed by diffusion,the diffusion activation energy was 33.69 kJ/mol,and the diffusion growth rate constant of the TiAl_(3) phase was mainly determined by the grain boundary diffusion owing to the smaller TiAl_(3) grain size.展开更多
Based on a shallow-buried coal seam covered with thick loose layers in hilly loess areas of western China,we developed a mechanical model for a mining slope with slope stability analysis, and studied the mechanism of ...Based on a shallow-buried coal seam covered with thick loose layers in hilly loess areas of western China,we developed a mechanical model for a mining slope with slope stability analysis, and studied the mechanism of formation and development of a sliding ground fissure by the circular sliding slice method.Moreover, we established a prediction model of a sliding fissure based on a mechanical mechanism,and verified its reliability on face 52,304, an engineering example, situated at Daliuta coal mine of Shendong mining area in western China. The results show that the stress state of a mining slope is changed by its gravity and additional stress from the shallow-buried coal seam and gully terrain. The mining slope is found to be most unstable when the ratio of the down-sliding to anti-sliding force is the maximum, causing local fractures and sliding fissures. The predicted angles for the sliding fissure of face 52,304 on both sides of the slope are found to be 64.2° and 82.4°, which are in agreement with the experimental data.展开更多
Bubble formation in an opposite-flowing T-shaped microchannel with 40 μm in depth and 120 μm in width was real-time visualized and investigated experimentally by means of a high speed camera. N2 bubbles were generat...Bubble formation in an opposite-flowing T-shaped microchannel with 40 μm in depth and 120 μm in width was real-time visualized and investigated experimentally by means of a high speed camera. N2 bubbles were generated in glycerol-water mixtures with different concentrations of surfactant sodium dodecyl sulfate (SDS). And the images were captured by the high speed camera linked to a computer. Results indicated that the bubble formation process can be distinguished into three consecutive stages, i.e., expansion, collapse and pinching off. The bubble size decreases with the increase of liquid flow rate and viscosity of liquid phase as well as the decrease of gas flow rate. The surface tension of the liquid phase has no measurable influence on the bubble size. Moreover, a new approach to predicting the size of bubbles formed in the T-shaped microchannel is proposed. And the predicted values agree well with the experimental data.展开更多
The conventional observations data,NCAR/NCEP-2 reanalysis data,and NOAA outgoing longwave radiation data are used to investigate different characteristics of Leo and Neoguri,two April typhoons that ever made landfall ...The conventional observations data,NCAR/NCEP-2 reanalysis data,and NOAA outgoing longwave radiation data are used to investigate different characteristics of Leo and Neoguri,two April typhoons that ever made landfall on the continent of China over the past 60 years.The results showed that both Leo and Neoguri occurred during the La Nina events.Strong convective activity,weak vertical wind shear and upper-level divergence were in favor of the formation of these April typhoons.Leo originated from a monsoon depression and Neoguri evolved from an easterly wave.The meandering moving track of Leo attributed to strong northeast monsoon and a weak and changeable subtropical high;the steady moving track of Neoguri was governed by a strong and stable subtropical high.Leo and Neoguri had similar terrain conditions and intensities during landfall but were different in precipitation as water vapor transport and duration of kinetic uplifting resulted in apparent discrepancies between them.展开更多
Based on the hazard development mechanism, a water solution area is closely related to the supporting effect of pressure-bearing water, the relaxing and collapsing effect of orebody interlayer, the collapsing effect o...Based on the hazard development mechanism, a water solution area is closely related to the supporting effect of pressure-bearing water, the relaxing and collapsing effect of orebody interlayer, the collapsing effect of thawless material in orebody, filling effect caused by cubical expansibility of hydrate crystallization and uplifting effect of hard rock layer over cranny belt. The movement and deformation of ground surface caused by underground water solution mining is believed to be much weaker than that caused by well lane mining, which can be predicted by the stochastic medium theory method. On the basis of analysis on the engineering practice of water solution mining, its corresponding parameters can be obtained from the in-site data of the belt water and sand filling mining in engineering analog approach.展开更多
文摘The formation mechanisms and growth kinetics of Al3 Ni and Al3Ni2 in Ni-Al diffusion couple prepared by electrodeposition of Ni on Al substrate were investigated. The nickel coating with 20 μm thickness was applied on 6061 aluminum alloy by direct current electroplating. The samples were then heat-treated for different durations at 450, 500 and 550 °C under argon atmosphere. The intermetallic phases were identified by means of scanning electron microscopy（SEM）, energy dispersive spectrometry（EDS） and X-ray diffraction（XRD）. The results showed that the formation of intermetallic phases consisted of two important steps. The first step was the lateral growth of intermetallic phase from separate sites, resulting in the formation of a continuous layer. The second step was the growth of the continuous intermetallic layer in the direction perpendicular to the interface. However, excessive increase in thickness of intermetallic phases led to the detachment of reaction products, i.e., Al3 Ni and Al3Ni2, from the substrate. It was also observed that aluminum was the dominant diffusing element during Al3 Ni growth, while nickel diffusion was dominant during Al3Ni2 growth. The growth kinetics of both Al3 Ni and Al3Ni2 phases obeyed a parabolic law.
文摘This paper describes changes in the structure of buds and vascular cambium as well as in protein content of one-year-old dormant branches of Eucommia ulmoides Oliv. in water-culture conditions. Results confirm the existence of 2 quiescences (Q1, Q2) and 1 rest (R) phases in this tree during the dormancy period. In the R time, the E. ulmoides cambium was unable to reactivate even though the tree was subjected to exogenous IAA, suitable temperature or required luminosity. Furthermore, pistillate trees entered the dormant phase earlier than staminate ones. The protein content in the bark during Q1 increased significantly ( P < 0.01), but drastically decreased in the R period, before rising up again at the onset of Q2 ( P < 0.01). Even though the change pattern of protein content was similar, its occurrence is much earlier in staminate than in pistillate plants. SDS-PAGE revealed a 'special' protein band of 11.8 kD in the transitional Q1-R-Q2 stages. This 'special' protein bands would be related to the cambial dormancy and to the regulation of the Q1-R-Q2 transition.
基金the financial supports from the S&T Program of Hebei Province,China(No.20373901D)the National Natural Science Foundation of China(Nos.51807047,51804095)+2 种基金the National Science Foundation of Hebei Province,China(No.E2019402433)the Youth Top Talents Science and Technology Research Project of Hebei Province University,China(No.BJ2019003)the Research and Development Project of Science and Technology of Handan City,China(No.19422111008-19).
文摘Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al interface;most of TiAl_(3) grains were fine equiaxed with average sizes ranging from hundreds of nanometers to several microns and the TiAl_(3) grain size increased with increasing annealing time and/or temperature,but the effect of annealing temperature on the TiAl_(3) grain size was far greater than that of annealing time.The growth of the TiAl_(3) phase consisted of two stages.The initial stage was governed by chemical reaction with a reaction activation energy of 195.75 kJ/mol,and the reaction rate constant of the TiAl_(3) phase was larger as the Ti/Al interface was bonded with fresh surfaces.At the second stage,the growth was governed by diffusion,the diffusion activation energy was 33.69 kJ/mol,and the diffusion growth rate constant of the TiAl_(3) phase was mainly determined by the grain boundary diffusion owing to the smaller TiAl_(3) grain size.
基金Projects funded by the National Key Basic Research Development Program(No.2013CB227904)the National Natural Science Foundation of China(No.41272389)+1 种基金China Postdoctoral Science Foundation(No.2014M561931)the Natural Science Foundation of Hebei Province(No.D2014402007)
文摘Based on a shallow-buried coal seam covered with thick loose layers in hilly loess areas of western China,we developed a mechanical model for a mining slope with slope stability analysis, and studied the mechanism of formation and development of a sliding ground fissure by the circular sliding slice method.Moreover, we established a prediction model of a sliding fissure based on a mechanical mechanism,and verified its reliability on face 52,304, an engineering example, situated at Daliuta coal mine of Shendong mining area in western China. The results show that the stress state of a mining slope is changed by its gravity and additional stress from the shallow-buried coal seam and gully terrain. The mining slope is found to be most unstable when the ratio of the down-sliding to anti-sliding force is the maximum, causing local fractures and sliding fissures. The predicted angles for the sliding fissure of face 52,304 on both sides of the slope are found to be 64.2° and 82.4°, which are in agreement with the experimental data.
基金Supported by National Natural Science Foundation of China (No. 20876107)Open Project of State Key Laboratory of Chemical Engineering (No. SKL-ChE-08B06) Program of Introducing Talents of Discipline to Universities (No. B06006)
文摘Bubble formation in an opposite-flowing T-shaped microchannel with 40 μm in depth and 120 μm in width was real-time visualized and investigated experimentally by means of a high speed camera. N2 bubbles were generated in glycerol-water mixtures with different concentrations of surfactant sodium dodecyl sulfate (SDS). And the images were captured by the high speed camera linked to a computer. Results indicated that the bubble formation process can be distinguished into three consecutive stages, i.e., expansion, collapse and pinching off. The bubble size decreases with the increase of liquid flow rate and viscosity of liquid phase as well as the decrease of gas flow rate. The surface tension of the liquid phase has no measurable influence on the bubble size. Moreover, a new approach to predicting the size of bubbles formed in the T-shaped microchannel is proposed. And the predicted values agree well with the experimental data.
基金Research on Techniques of Forecasting and Pre-warning Typhoons Landing on or Seriously Affecting Guangdong,a Project of Guangdong Science and Technology Bureau (2007B060401016)Natural Science Foundation of China (40730951)
文摘The conventional observations data,NCAR/NCEP-2 reanalysis data,and NOAA outgoing longwave radiation data are used to investigate different characteristics of Leo and Neoguri,two April typhoons that ever made landfall on the continent of China over the past 60 years.The results showed that both Leo and Neoguri occurred during the La Nina events.Strong convective activity,weak vertical wind shear and upper-level divergence were in favor of the formation of these April typhoons.Leo originated from a monsoon depression and Neoguri evolved from an easterly wave.The meandering moving track of Leo attributed to strong northeast monsoon and a weak and changeable subtropical high;the steady moving track of Neoguri was governed by a strong and stable subtropical high.Leo and Neoguri had similar terrain conditions and intensities during landfall but were different in precipitation as water vapor transport and duration of kinetic uplifting resulted in apparent discrepancies between them.
基金Project(40404001) supported by the National Natural Science Foundation of China
文摘Based on the hazard development mechanism, a water solution area is closely related to the supporting effect of pressure-bearing water, the relaxing and collapsing effect of orebody interlayer, the collapsing effect of thawless material in orebody, filling effect caused by cubical expansibility of hydrate crystallization and uplifting effect of hard rock layer over cranny belt. The movement and deformation of ground surface caused by underground water solution mining is believed to be much weaker than that caused by well lane mining, which can be predicted by the stochastic medium theory method. On the basis of analysis on the engineering practice of water solution mining, its corresponding parameters can be obtained from the in-site data of the belt water and sand filling mining in engineering analog approach.
