Thermo-responsive shape memory hydrogels generally achieve shape fixation at low temperatures,and shape recovery at high temperatures.However,these hydrogels usually suffer from poor mechanical properties.Herein,we pr...Thermo-responsive shape memory hydrogels generally achieve shape fixation at low temperatures,and shape recovery at high temperatures.However,these hydrogels usually suffer from poor mechanical properties.Herein,we present a unique poly(acrylic acid)/calcium acetate shape memory hydrogel with cold-induced shape recovery performances as ultrastrong artificial muscles.Since the acetate groups could form aggregate at high temperatures and thus induce the association of the hydrogel network,the hydrogel can be fixed into a temporary shape upon heating and recover to its original shape in a cold environment.Moreover,a programmable shape recovery process is realized by adjusting the shape fixing time.In addition,the unique shape memory process enables the application demonstration as bio-inspired artificial muscles with an ultrahigh work density of45.2 kJ m^(-3),higher than that of biological muscles(~8 kJ m^(-3)).展开更多
Conductive and adhesive hydrogels are promising materials for designing bioelectronics.To satisfy the high conductivity of bioelectronic devices,metal nanomaterials have been used to fabricate composite hydrogels.Howe...Conductive and adhesive hydrogels are promising materials for designing bioelectronics.To satisfy the high conductivity of bioelectronic devices,metal nanomaterials have been used to fabricate composite hydrogels.However,the fabrication of a conductive-nanomaterial-incorporated hydrogel with high performance is a great challenge because of the easy aggregation nature of conductive nanomaterials making processing difficult.Here,we report a kind of adhesive aero-hydrogel hybrid conductor(AAHC)with stretchable,adhesive and anti-bacteria properties by in situ formation of a hydrogel network in the aerogel-silver nanowires(AgNWs)assembly.The AgNWs with good conductivity are wellintegrated on the inner-surface of shape-memory chitosan aerogel,which created a conductive framework to allow hydrogel back-filling.Reinforcement by the aerogel-silver makes the hybrid hydrogel tough and stretchable.Functional groups from the hydrogel allow strong adhesion to wet tissues through molecular stitches.The inherent bacteria-killing ability of silver ions endows the conductive hydrogel with excellent anti-bacteria performance.The proposed facile strategy of aerogel-assisted assembly of metal nanomaterials with hydrogel opens a new route to incorporate functional nanoscale building blocks into hydrogels.展开更多
基金supported by the National Natural Science Foundation of China(51873223 and 22075154)the Natural Science Foundation of Zhejiang Province(LY19B040001)。
文摘Thermo-responsive shape memory hydrogels generally achieve shape fixation at low temperatures,and shape recovery at high temperatures.However,these hydrogels usually suffer from poor mechanical properties.Herein,we present a unique poly(acrylic acid)/calcium acetate shape memory hydrogel with cold-induced shape recovery performances as ultrastrong artificial muscles.Since the acetate groups could form aggregate at high temperatures and thus induce the association of the hydrogel network,the hydrogel can be fixed into a temporary shape upon heating and recover to its original shape in a cold environment.Moreover,a programmable shape recovery process is realized by adjusting the shape fixing time.In addition,the unique shape memory process enables the application demonstration as bio-inspired artificial muscles with an ultrahigh work density of45.2 kJ m^(-3),higher than that of biological muscles(~8 kJ m^(-3)).
基金the National Natural Science Foundation of China(51732011,51702310,21431006,and 21761132008)the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(21521001)+2 种基金the Key Research Program of Frontier Sciences,CAS(QYZDJ-SSW-SLH036)the Users with Excellence and Scientific Research Grant of Hefei Science Center of CAS(2015HSC-UE007)Anhui Provincial Natural Science Foundation(1808085ME115)。
文摘Conductive and adhesive hydrogels are promising materials for designing bioelectronics.To satisfy the high conductivity of bioelectronic devices,metal nanomaterials have been used to fabricate composite hydrogels.However,the fabrication of a conductive-nanomaterial-incorporated hydrogel with high performance is a great challenge because of the easy aggregation nature of conductive nanomaterials making processing difficult.Here,we report a kind of adhesive aero-hydrogel hybrid conductor(AAHC)with stretchable,adhesive and anti-bacteria properties by in situ formation of a hydrogel network in the aerogel-silver nanowires(AgNWs)assembly.The AgNWs with good conductivity are wellintegrated on the inner-surface of shape-memory chitosan aerogel,which created a conductive framework to allow hydrogel back-filling.Reinforcement by the aerogel-silver makes the hybrid hydrogel tough and stretchable.Functional groups from the hydrogel allow strong adhesion to wet tissues through molecular stitches.The inherent bacteria-killing ability of silver ions endows the conductive hydrogel with excellent anti-bacteria performance.The proposed facile strategy of aerogel-assisted assembly of metal nanomaterials with hydrogel opens a new route to incorporate functional nanoscale building blocks into hydrogels.
