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表面活性剂胶束形状随浓度转变的核磁共振研究(英文) 被引量:7
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作者 卢星宇 蒋艳 +3 位作者 崔晓红 毛诗珍 刘买利 杜有如 《物理化学学报》 SCIE CAS CSCD 北大核心 2009年第7期1357-1361,共5页
运用核磁共振一维氢谱和自扩散实验方法研究了聚乙烯乙二醇异辛酚醚(TX-100)、十二烷基苯磺酸钠(SDBS)和十四烷基三甲基溴化铵(TTAB)三种不同类型的表面活性剂在重水溶液中的胶束形状转变,发现它们在临界胶束浓度以上的各自相应浓度都... 运用核磁共振一维氢谱和自扩散实验方法研究了聚乙烯乙二醇异辛酚醚(TX-100)、十二烷基苯磺酸钠(SDBS)和十四烷基三甲基溴化铵(TTAB)三种不同类型的表面活性剂在重水溶液中的胶束形状转变,发现它们在临界胶束浓度以上的各自相应浓度都有胶束形状的变化(由球状转变为椭球状或棒状).在常温常压和没有其他添加剂的情况下,表面活性剂溶液浓度高于其临界胶束浓度时,球状胶束开始形成.核磁共振一维氢谱和自扩散实验的结果显示,当溶液浓度继续增加到一定程度时,溶液中表面活性剂分子的化学位移和自扩散系数的变化速率都有明显的转折,这说明溶液中球状胶束开始发生转变.进一步通过仔细分析对比核磁共振一维氢谱中各基团谱峰,发现表面活性剂胶束亲水表面上的质子的化学位移变化速率要远高于其疏水内核中的质子,据此推测胶束形状很可能由球状转变为椭球状或棒状. 展开更多
关键词 表面活性剂 核磁共振 胶束形状转变 第二临界胶束浓度
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短切碳纤维增强环氧树脂形状记忆复合材料的制备与性能研究 被引量:1
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作者 罗发祥 魏要强 +2 位作者 武南 宋世彬 邵一川 《宇航材料工艺》 CAS CSCD 北大核心 2023年第3期60-67,共8页
为实现形状驱动能耗与复合材料力学性能的最佳配合,本文在热致环氧形状记忆聚合物基体中提高增韧剂新戊二醇二缩水醚(NGDE)含量来降低其玻璃化转变温度,同时添加短切碳纤维(SCF)来抵消由增韧剂引起的刚度降低负面效果。通过实验研究了不... 为实现形状驱动能耗与复合材料力学性能的最佳配合,本文在热致环氧形状记忆聚合物基体中提高增韧剂新戊二醇二缩水醚(NGDE)含量来降低其玻璃化转变温度,同时添加短切碳纤维(SCF)来抵消由增韧剂引起的刚度降低负面效果。通过实验研究了不同NGDE、SCF含量对复合材料形状记忆转变温度、形状记忆性能和力学性能的影响。结果表明,增加NGDE含量可将环氧聚合物基体的形状记忆转变温度从90℃降至43℃,其储能模量和弯曲模量也随之降低。在11wt%NGDE上添加SCF后,复合材料的玻璃态储能模量、橡胶态储能模量、弯曲模量最高可提高至原始试样的1.9倍、7倍和2.4倍。 展开更多
关键词 环氧形状记忆复合材料 短切碳纤维 形状记忆转变温度 储能模量 弯曲模量
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A=135核区N=79的同中异位素高自旋结构研究
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作者 朱胜江 徐强 +7 位作者 车兴来 朱凌燕 陈永静 丁怀博 王建国 竺礼华 温书贤 吴晓光 《原子核物理评论》 CAS CSCD 北大核心 2008年第3期209-217,共9页
对清华大学在束γ谱实验组近年来在A=135缺中子核区N=79的同中异位素135Ba,137Ce和139Nd的高自旋态实验研究进行了介绍。实验是在中国原子能科学研究院HI-13串列加速器上用在束γ的实验技术、分别通过重离子核反应130Te(9Be,4n),124Sn(1... 对清华大学在束γ谱实验组近年来在A=135缺中子核区N=79的同中异位素135Ba,137Ce和139Nd的高自旋态实验研究进行了介绍。实验是在中国原子能科学研究院HI-13串列加速器上用在束γ的实验技术、分别通过重离子核反应130Te(9Be,4n),124Sn(18O,5n),128Te(16O,5n)进行的。实验结果扩展了这3个核的高自旋态能级纲图。研究表明,这3个核的低自旋态结构均起源于νh1-1/12空穴与其偶偶核芯的耦合。用粒子-转子模型对其结构进行了计算,得到这3个核的形变参量γ值均稍大于30°,为偏向于扁椭的三轴形变,从而可看出Ba,Ce和Nd3个同位素链在低自旋态下由长椭边到扁椭边的形状转变都发生在中子数N=77—79之间。对于中等自旋态下一些能级的组态进行了指定与系统学比较。在高自旋态下,在137Ce中发现一条γ≈-60°的扁椭形变带,在139Nd中则发现3条这样的扁椭形变带,对这些扁椭形变带的起源及结构特性进行了讨论。 展开更多
关键词 核结构 高自旋态 形状转变 扁椭形变
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强磁场对FePt纳米粒子液相生长速率的影响
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作者 吴纯 鞠玉萍 +5 位作者 江亚男 董世知 任鑫 裴文利 王凯 王强 《中国有色金属学报》 EI CAS CSCD 北大核心 2022年第3期836-844,共9页
本文使用定量金相法分析了6 T强磁场对FePt晶体<100>、<111>方向生长行为的影响机制。结果表明:FePt晶体液相生长包括<100>、<111>方向的快速生长和缓慢生长两个阶段。强磁场通过降低原子浓度、抑制原子扩散、... 本文使用定量金相法分析了6 T强磁场对FePt晶体<100>、<111>方向生长行为的影响机制。结果表明:FePt晶体液相生长包括<100>、<111>方向的快速生长和缓慢生长两个阶段。强磁场通过降低原子浓度、抑制原子扩散、抑制表面活性剂吸附等方式降低生长速率和生长距离,细化晶粒。强磁场通过增强磁晶各向异性、影响—NH_(2)官能团在(100)面吸附、促进Fe原子在(100)面吸附生长等方式,减小<100>方向生长速率的降低幅度,使生长过程中FePt晶体形状从截角立方体向立方体和凹立方体转变所需时间增加,使相同生长时间时晶体形状从立方体转变为截角立方体、从凹立方体转变为截角立方体和立方体。 展开更多
关键词 强磁场 FePt纳米粒子 生长速率 形状转变
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Influence of recovery heating rate on shape memory effect in up-quenched Cu-Al-Mn alloy
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作者 王珊玲 杨琴 +2 位作者 李小兰 彭华备 文玉华 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第10期3196-3200,共5页
The effect of recovery heating rate on shape memory effect of the up-quenched Cu-8.88Al-10.27Mn(mass fraction, %) alloy was investigated by optical microscopy, electron transmission microscopy(TEM) and electrical ... The effect of recovery heating rate on shape memory effect of the up-quenched Cu-8.88Al-10.27Mn(mass fraction, %) alloy was investigated by optical microscopy, electron transmission microscopy(TEM) and electrical resistivity measurement. It is found that the shape recovery rate decreases as the heating rate decreases. It can reach 75% when the heating rate is 20 ℃/min, while it is only 8% when the heating rate is 1 ℃/min. In situ microstructure observation indicates that the dependence of shape memory effect on recovery heating rate is caused by the stabilization of twinned martensite induced by deformation. The analysis of electrical resistivity shows that the stabilization of twinned martensite may be ascribed to formation of compound defects of vacancies and dislocations at the boundaries of twinned martensite during the slow heating. The compound defects prevent the reverse transformation of twinned martensite. 展开更多
关键词 Cu-Al-Mn alloy shape memory effect martensitic phase transformation TWINNING
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Shape change induced by g_(9/2) rotational alignment in ^(84,86)Mo 被引量:5
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作者 LIU XuDong SHI Yue XU FuRong 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第10期1811-1814,共4页
Neutron-deficient Z ≈ N nuclei84,86Mo have been investigated using pairing-deformation self-consistent cranked shell modelcalculations up to spin I > 20 . Our calculations are in good agreement with the experiment... Neutron-deficient Z ≈ N nuclei84,86Mo have been investigated using pairing-deformation self-consistent cranked shell modelcalculations up to spin I > 20 . Our calculations are in good agreement with the experimental data, indicating γ-soft triaxial shapesat low rotational frequency and well-deformed triaxial-oblate shapes at high rotational frequency for both nuclei. The shape changeis due to the alignments of the g9/2protons and g9/2neutrons. 展开更多
关键词 shape change cranked shell model MOLYBDENUM
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Reconstruction Method for Running Shape of Rotor Blade Considering Nonlinear Stiffness and Loads 被引量:2
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作者 WANG Yongliang KANG Da ZHONG Jingjun 《Journal of Thermal Science》 SCIE EI CAS CSCD 2017年第5期431-439,共9页
The aerodynamic and centrifugal loads acting on the rotating blade make the blade configuration deformed comparing to its shape at rest. Accurate prediction of the running blade configuration plays a significant role ... The aerodynamic and centrifugal loads acting on the rotating blade make the blade configuration deformed comparing to its shape at rest. Accurate prediction of the running blade configuration plays a significant role in examining and analyzing turbomachinery performance. Considering nonlinear stiffness and loads, a reconstruction method is presented to address transformation of a rotating blade from cold to hot state. When calculating blade deformations, the blade stiffness and load conditions are updated simultaneously as blade shape varies. The reconstruction procedure is iterated till a converged hot blade shape is obtained. This method has been employed to determine the operating blade shapes of a test rotor blade and the Stage 37 rotor blade. The calculated results are compared with the experiments. The results show that the proposed method used for blade operating shape prediction is effective. The studies also show that this method can improve precision of finite element analysis and aerodynamic performance analysis. 展开更多
关键词 Blade reconstruction Fluid-structure interaction Aeroelasticity NONLINEARITY
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Influence of stresses on martensitic transformation in ferromagnetic shape memory Ni_(50)Mn_(19)Fe_6Ga_(25) ribbons
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作者 MENG Fanbin LI Yangxian +4 位作者 LIU Heyan QU Jingping LIU Zhuhong CHEN Jinglian WU Guangheng 《Science China(Technological Sciences)》 SCIE EI CAS 2004年第6期710-715,共6页
The influence of stresses on martensitic transformation in Ni50Mn19Fe6Ga25 melt-spun ribbons was studied. X-ray diffraction examination shows that the ribbon has a pure cubic L21 phase at room temperature and that the... The influence of stresses on martensitic transformation in Ni50Mn19Fe6Ga25 melt-spun ribbons was studied. X-ray diffraction examination shows that the ribbon has a pure cubic L21 phase at room temperature and that the ribbon surface exhibits [100] preferentially oriented texture, while the [110] axis is about 45° tilted from the normal of the ribbon. By calculating the d spacing at different angles with the length direction of the ribbon, the tension was observed. It was found that the direction of the stress was along [010] direction of the oriented textured grains. During cooling, there is no obvious structural transition observed in as-spun ribbons. However, when the ribbons were annealed at 900 K for 24 h, the tension along [010] direction disappeared and the structural transition from cubic to tetragonal occurred obviously during cooling. It indicates that it is the tension along [010] direction to suppress the martensitic transformation in the as-spun ribbons. 展开更多
关键词 STRESS martensitic transformation ferromagnetic shape memory alloy
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