Batch experiments were conducted to study the adsorption of phenol on clay-solidified grouting curtain (CSGC) and the effects of contact time,pH and adsorbent concentration on the adsorption were investigated.Under th...Batch experiments were conducted to study the adsorption of phenol on clay-solidified grouting curtain (CSGC) and the effects of contact time,pH and adsorbent concentration on the adsorption were investigated.Under the experimental conditions used,2 d was adequate to determine the equilibrium of phenol adsorption onto CSGC.The amount of phenol adsorbed by CSGC from an initial concentration of 100mg/L was found to be 8.4mg/g.The adsorption process includes particle diffusion and liquid film diffusion,and the latter is the predominating step of the adsorption process.The adsorption ability of CSGC decreased with pH but it increased non-linearly with the CSGC concentration.The optimized concentration for CSGC was found to be 20g/L for the adsorption of 100mg/L phenol.展开更多
The effect of controlling strata movement in solid filling mining depends on the filling rate of the goal. However, the mechanical property of the overburden in the backfill stope and the designed size of the backfill...The effect of controlling strata movement in solid filling mining depends on the filling rate of the goal. However, the mechanical property of the overburden in the backfill stope and the designed size of the backfill mining workface should also be considered. In this study, we established a main roof strata model with loads in accordance with the theory of key strata to investigate the stability of the overburden in solid dense filling mining. We analyzed the stress distribution law of the main roof strata based on elastic thin plate theory. The results show that the position of the long side midpoint of the main roof strata failed more easily because of tensile yield, indicating that this position is the area where failure is likely to occur more easily. We also deduced the stability mechanics criterion of the main roof strata based on tensile yield criterion. The factors affecting the stability of the overburden in solid dense filling mining were also analyzed, including the thickness and elasticity modulus of the main roof strata, overlying strata loads, advanced distance and length of workface, and elastic foundation coefficient of backfill body. The research achievements can provide an important theoretical basis for determining the designed size of the solid dense filling mining workface.展开更多
The concentration of acetaldehyde(AA) is the main quality index of poly(ethylene terephthalate)(PET) used in food and drink packaging.A new method for AA removal has been developed by using supercritical carbon dioxid...The concentration of acetaldehyde(AA) is the main quality index of poly(ethylene terephthalate)(PET) used in food and drink packaging.A new method for AA removal has been developed by using supercritical carbon dioxide(sc CO2) during the solid-state polycondensation of PET.The influence factors of AA removal including the temperature,pressure,reaction time and the size of pre-polymer particles are systematically studied in this work.The results indicate that it is a highly efficient way to obtain high molecular weight PET with relative low concentration of AA.Correspondingly,the polymerization degree of PET could increase from 27.9 to 85.6 while the concentration of AA reduces from 0.229 × 10^(-6) to 0.055 × 10^(-6) under the optimal operation conditions of 230 °C,8 MPa and size of 0.30–0.45 mm.Thermodynamic performance tests show the increasing extent of PET crystallinity due to the fact that the plasticization of sc CO_2 is not obvious with extended reaction time,therefore the increasing crystallinity has no significant influence on AA removal.SEM observations reveal that the effects of sc CO_(2-) induced plasticization and swelling on PET increase significantly with the decrease of prepolymer size,and the surface of PET becomes more loose and porous in favor of the AA removal.展开更多
A silicone oil emulsion with 60% of solid content was prepared with methyl silicone oil used as the main material by means of the emulsifier-in-oil method.The influence of emulsification conditions on the droplet diam...A silicone oil emulsion with 60% of solid content was prepared with methyl silicone oil used as the main material by means of the emulsifier-in-oil method.The influence of emulsification conditions on the droplet diameter of silicone oil emulsion was discussed.The experimental results showed that the emulsification method,including the quantity of the emulsifier,the time and temperature of emulsification,the emulsifying water dosage,and the stirring speed,had significant impact on the droplet size.The optimal conditions were identified to achieve a smallest droplet diameter of the emulsion at an emulsifier dosage of 6%,an emulsification temperature of 70 ℃,an emulsification time of 30 min,and a stirring speed of 1100 r/min,with water added in two portions at a ratio of 1:1.The high-solid content silicone oil emulsion with a mean droplet diameter of 2.731 μm was prepared under these conditions that could ensure absence of stratification and floating oil under centrifuging at a speed of 3000 r/min for 30 min.展开更多
The cement dry jet mixing method has been used to reinforce soft cohesive ground to increase the strength of soft cohesive ground and to decrease its deformation. The study briefly introduces the curing mechanism of c...The cement dry jet mixing method has been used to reinforce soft cohesive ground to increase the strength of soft cohesive ground and to decrease its deformation. The study briefly introduces the curing mechanism of cement-soil,presents the factors of influencing on compressive strength,mainly analyses the factors including cement mixing ratio,cement strength grade,curing age,moisture content and soil texture and puts forward some rational proposals at last.展开更多
On the basis of panel data from 29 provinces and cities throughout the country in 2006-2010, a research is made on factors influencing regional industrial solid waste comprehensive utilization ability through a regres...On the basis of panel data from 29 provinces and cities throughout the country in 2006-2010, a research is made on factors influencing regional industrial solid waste comprehensive utilization ability through a regression analysis method. Research result shows that a positive influence will generate on the comprehensive utilization ability of the industrial solid waste by three factors: regional industrial soldi waste treatment earning level, regional industrial soldi waste treatment investment level and regional industrial pollution treatment subsidy strength. And this thesis will propose suggestions from improving earning ability, enhartcing treatment investment and increasing government subsidy depending on result of empirical analysis.展开更多
基金Project(40802064) supported by the National Natural Science Foundation of ChinaProject(Z110805) supported by the Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences Project(200925) supported by the Progress and Innovation Fund for the Transportation Science and Technology of Hunan Province,China
文摘Batch experiments were conducted to study the adsorption of phenol on clay-solidified grouting curtain (CSGC) and the effects of contact time,pH and adsorbent concentration on the adsorption were investigated.Under the experimental conditions used,2 d was adequate to determine the equilibrium of phenol adsorption onto CSGC.The amount of phenol adsorbed by CSGC from an initial concentration of 100mg/L was found to be 8.4mg/g.The adsorption process includes particle diffusion and liquid film diffusion,and the latter is the predominating step of the adsorption process.The adsorption ability of CSGC decreased with pH but it increased non-linearly with the CSGC concentration.The optimized concentration for CSGC was found to be 20g/L for the adsorption of 100mg/L phenol.
基金Financial support for this work, provided by the National Natural Science Foundation of China (No.51404013)the Natural Science Foundation of Anhui Province (Nos.1508085ME77 and 1508085QE89)the Open Projects of State Key Laboratory for Geomechanics & Deep Underground Engineering at the China University of Mining and Technology (No.SKLGDUEK1212)
文摘The effect of controlling strata movement in solid filling mining depends on the filling rate of the goal. However, the mechanical property of the overburden in the backfill stope and the designed size of the backfill mining workface should also be considered. In this study, we established a main roof strata model with loads in accordance with the theory of key strata to investigate the stability of the overburden in solid dense filling mining. We analyzed the stress distribution law of the main roof strata based on elastic thin plate theory. The results show that the position of the long side midpoint of the main roof strata failed more easily because of tensile yield, indicating that this position is the area where failure is likely to occur more easily. We also deduced the stability mechanics criterion of the main roof strata based on tensile yield criterion. The factors affecting the stability of the overburden in solid dense filling mining were also analyzed, including the thickness and elasticity modulus of the main roof strata, overlying strata loads, advanced distance and length of workface, and elastic foundation coefficient of backfill body. The research achievements can provide an important theoretical basis for determining the designed size of the solid dense filling mining workface.
基金Supported by the National Key Research and Development Program of China(2016YFB0302702)the National Natural Science Foundation of China(21676083)+1 种基金the Shanghai Rising-Star Program(16QB140130)the 111 Project(B08021)
文摘The concentration of acetaldehyde(AA) is the main quality index of poly(ethylene terephthalate)(PET) used in food and drink packaging.A new method for AA removal has been developed by using supercritical carbon dioxide(sc CO2) during the solid-state polycondensation of PET.The influence factors of AA removal including the temperature,pressure,reaction time and the size of pre-polymer particles are systematically studied in this work.The results indicate that it is a highly efficient way to obtain high molecular weight PET with relative low concentration of AA.Correspondingly,the polymerization degree of PET could increase from 27.9 to 85.6 while the concentration of AA reduces from 0.229 × 10^(-6) to 0.055 × 10^(-6) under the optimal operation conditions of 230 °C,8 MPa and size of 0.30–0.45 mm.Thermodynamic performance tests show the increasing extent of PET crystallinity due to the fact that the plasticization of sc CO_2 is not obvious with extended reaction time,therefore the increasing crystallinity has no significant influence on AA removal.SEM observations reveal that the effects of sc CO_(2-) induced plasticization and swelling on PET increase significantly with the decrease of prepolymer size,and the surface of PET becomes more loose and porous in favor of the AA removal.
文摘A silicone oil emulsion with 60% of solid content was prepared with methyl silicone oil used as the main material by means of the emulsifier-in-oil method.The influence of emulsification conditions on the droplet diameter of silicone oil emulsion was discussed.The experimental results showed that the emulsification method,including the quantity of the emulsifier,the time and temperature of emulsification,the emulsifying water dosage,and the stirring speed,had significant impact on the droplet size.The optimal conditions were identified to achieve a smallest droplet diameter of the emulsion at an emulsifier dosage of 6%,an emulsification temperature of 70 ℃,an emulsification time of 30 min,and a stirring speed of 1100 r/min,with water added in two portions at a ratio of 1:1.The high-solid content silicone oil emulsion with a mean droplet diameter of 2.731 μm was prepared under these conditions that could ensure absence of stratification and floating oil under centrifuging at a speed of 3000 r/min for 30 min.
文摘The cement dry jet mixing method has been used to reinforce soft cohesive ground to increase the strength of soft cohesive ground and to decrease its deformation. The study briefly introduces the curing mechanism of cement-soil,presents the factors of influencing on compressive strength,mainly analyses the factors including cement mixing ratio,cement strength grade,curing age,moisture content and soil texture and puts forward some rational proposals at last.
文摘On the basis of panel data from 29 provinces and cities throughout the country in 2006-2010, a research is made on factors influencing regional industrial solid waste comprehensive utilization ability through a regression analysis method. Research result shows that a positive influence will generate on the comprehensive utilization ability of the industrial solid waste by three factors: regional industrial soldi waste treatment earning level, regional industrial soldi waste treatment investment level and regional industrial pollution treatment subsidy strength. And this thesis will propose suggestions from improving earning ability, enhartcing treatment investment and increasing government subsidy depending on result of empirical analysis.