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优质立方六面体金刚石大单晶的生长研究 被引量:12
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作者 陈奎 臧传义 +3 位作者 陈立学 陈孝洲 吴杰 王杰 《人工晶体学报》 EI CAS CSCD 北大核心 2010年第2期324-327,共4页
高温高压静压触媒法合成的金刚石单晶,往往呈现六八面体形貌,因为立方六面体单晶{100}面的生长区间相对较小。本研究利用高温高压温度梯度法,自制Fe-Ni合金触媒,通过对合成组装和工艺进行合理调整后,控制晶体在相对低温适合{100}面生长... 高温高压静压触媒法合成的金刚石单晶,往往呈现六八面体形貌,因为立方六面体单晶{100}面的生长区间相对较小。本研究利用高温高压温度梯度法,自制Fe-Ni合金触媒,通过对合成组装和工艺进行合理调整后,控制晶体在相对低温适合{100}面生长区域内生长,得到的晶体均呈现完整立方六面体形貌;同时为抑制包裹体和其他杂质的进入,人为的提高晶体的径向平铺生长速度,抑制其轴向生长速度。以在33 h内合成的优质立方六面体晶体为例,晶体最大方向尺寸达到7.3 mm,重1.2克拉,其径向生长速度达到0.22 mm/h,轴向生长速度仅为0.08mm/h,增重速度为7.3 mg/h。 展开更多
关键词 高温高压温差法 立方六面体 径向生长速度 轴向生长速度
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Effect of growth rate and diameter on microstructure and hardness of directionally solidified Ti-46Al-8Nb alloy 被引量:2
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作者 刘国怀 李新中 +6 位作者 张元 陈瑞润 苏彦庆 郭景杰 傅恒志 王昭东 王国栋 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第12期4044-4052,共9页
Bridgman-type directional solidification experiments were conducted for Ti-46Al-8Nb (mole fraction, %) alloy. The effects of the growth rate and the diameter on the microstructure, phase transition and hardness of t... Bridgman-type directional solidification experiments were conducted for Ti-46Al-8Nb (mole fraction, %) alloy. The effects of the growth rate and the diameter on the microstructure, phase transition and hardness of the alloy were investigated. The results show that with the increase of the growth rate and the decrease of the diameter, the fullyβphase solidification changes to the peritectic solidification, and the final microstructure is composed of theα2/γlamellar structure and a multiphase microstructure (B2 phase,α2/γlamellar structure) respectively, which can be attributed to the solute enrichment resulting from the decreasing diffusion and convection ability. The occurrence of peritectic reaction at high growth rate promotes the solute segregation heavily and the coarse lamellar spacing in Al-and Nb-rich region, which greatly decreases the hardness values and leads to the discontinuity of the hardness curves with the increase of the growth rate. Comparatively, the Ti-46Al-8Nb alloy has lower hardness values than the other applied TiAl-based alloys in previous studies. 展开更多
关键词 TiAl alloy directional solidification growth rate DIAMETER phase transition
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