MIL-88B(Fe)非均相芬顿催化降解磺胺甲恶唑

采用溶剂热法合成了铁基金属有机骨架材料MIL-88B(Fe),将其作为类芬顿催化剂用于催化降解水中磺胺甲恶唑(SMX)。通过X射线衍射(XRD)、扫描电子显微镜(SEM)、傅立叶变换红外光谱(FTIR)和X射线光电子能谱(XPS)等对催化剂的结构和性能进行表征,并研究了H2O2浓度、催化剂投加量、溶液初始pH和污染物初始浓度等对SMX降解效果的影响。结果表明,在H2O2摩尔浓度为6.0mmol/L、催化剂投加量为0.2g/L、pH为4、SMX为5mg/L的优化反应条件下,MIL-88B(Fe)对SMX的降解率可达99%。在较宽的pH(4~6)范围内,MIL-88B(Fe)仍保持较好的催化活性,且5次循环使用后对SMX去除率仍可达95%以上。表明合成的MIL-88B(Fe)具有较高的催化活性和重复性能,是一种优良的非均相类芬顿催化剂。

Optimization of the performance characteristics in an irreversible regeneration magnetic Brayton refrigeration cycle

A model of the irreversible regenerative Brayton refrigeration cycle working with paramagnetic materials is established,in which the regeneration problem in two constant-magnetic field processes and the irreversibility in two adiabatic processes are considered synthetically.Expressions for the COP,cooling rate,power input,theminimum ratio of the two magnetic fields,etc.,are derived.It is found that the influence of the irreversibility and the regeneration on the main performance parameters of the magnetic Brayton refrigerator is remarkable.It is important that we have obtained several optimal criteria,which may provide some theoretical basis for the optimal design and operation of the Brayton refrigerator.The results obtained in the paper can provide some new theoretical information for the optimal design and performance improvement of real Brayton refrigerators.