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共结晶分子筛催化剂上催化裂化汽油中烯烃芳构化 被引量:1
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作者 于海卫 刘盛林 +2 位作者 安杰 王清遐 徐龙伢 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2006年第B10期53-56,共4页
针对共结晶分子筛催化剂CDM35的特点,开发了适宜催化裂化汽油和液化气改质的高芳烃低烯烃的循环固定流化床工艺。在质量空速1.0-2.0h^-1,370-420℃、200g CDM35、循环量10%~20%的条件下,对催化裂化汽油和/或液化气进行改质,可得... 针对共结晶分子筛催化剂CDM35的特点,开发了适宜催化裂化汽油和液化气改质的高芳烃低烯烃的循环固定流化床工艺。在质量空速1.0-2.0h^-1,370-420℃、200g CDM35、循环量10%~20%的条件下,对催化裂化汽油和/或液化气进行改质,可得到烯烃质量分数20%左右、芳烃质量分数40%左右、苯质量分数〈1%汽油辛烷值(RON)95以上的汽油产品。 展开更多
关键词 催化裂化汽油 芳构化 循环固定流化床 共结晶分子筛催化剂
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Catalytic Cracking and PSO-RBF Neural Network Model of FCC Cycle Oil 被引量:3
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作者 Liu Yibin Tu Yongshan +1 位作者 Li Chunyi Yang Chaohe 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2013年第4期63-69,共7页
Catalytic cracking experiments of FCC cycle oil were carried out in a fixed fluidized bed reactor. Effects of reac- tion conditions, such as temperature, catalyst to oil ratio and weight hourly space velocity, were in... Catalytic cracking experiments of FCC cycle oil were carried out in a fixed fluidized bed reactor. Effects of reac- tion conditions, such as temperature, catalyst to oil ratio and weight hourly space velocity, were investigated. Hydrocarbon composition of gasoline was analyzed by gas chromatograph. Experimental results showed that conversion of cycle oil was low on account of its poor crackability performance, and the effect of reaction conditions on gasoline yield was obvi- ous. The paraffin content was very high in gasoline. Based on the experimental yields under different reaction conditions, a model for prediction of gasoline and diesel yields was established by radial basis function neural network (RBFNN). In the model, the product yield was viewed as function of reaction conditions. Particle swarm optimization (PSO) algorithm with global search capability was used to obtain optimal conditions for a highest yield of light oil. The results showed that the yield of gasoline and diesel predicted by RBF neural network agreed well with the experimental values. The optimized reac- tion conditions were obtained at a reaction temperature of around 520 ~C, a catalyst to oil ratio of 7.4 and a space velocity of 8 h~. The predicted total yield of gasoline and diesel reached 42.2% under optimized conditions. 展开更多
关键词 catalytic cracking cycle oil radical basis function neural network particle swarm optimization
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