气相法聚乙烯工艺树脂生片结块的原因分析

通过分析气相法聚乙烯反应器内核源块料探测器指示值超量程这一事件,查找气相流化床反应器内核源块料探测器指示值超量程的原因。同时笔者结合在日常生产过程中掌握的工艺技术和操作经验,进一步分析气相法流化床反应器内树脂出现生片结块的深层原因,期望能对气相法聚乙烯装置的稳定生产提供指导和借鉴。

聚烯烃流化床互送种子床解决措施

在聚烯烃流化床生产工艺中原有的开车输送种子床的过程中技术改造添加了由2台反应器之间的输送粉料的桥梁管线。作为一种新的操作模式,具有提高开工效率,缩短开车时间,节约开车成本,增加经济效益。尤其在没有开车种子床,需要外购粉料的情况下效果更为显著。

Hydrodynamic Behaviour of a Gas-Solid Air-loop Stripper

In this paper, the principles of airlift loop reactor in gas-liquid and gas-liquid-solid systems are extended to gas-solid system. The models on bed average voidage in draft tube and the particle circulation velocity in a gas-solid loop reactor are deduced. The experiments are also conducted on a Φ600mm×7000mm reactor. The catalyst voidage and catalyst circulation velocity are measured at different radial and axial positions in draft tube and annulus, respectively. The experimental data are analyzed systemically and represented satisfactorily by the proposed models.

Simple Model for Gas Holdup and Liquid Velocity of Annular Photocatalytic External-Loop Airlift Reactor Under both Bubble and Developing Slug Flow

Based on the momentum conservation approach, a theoretical model was developed to predict the superficial liquid velocity, and a correlation equation was established to calculate the gas holdup of an annular external-loop airlift reactor(AELAR)in the bubble flow and developing slug flow pattern. Experiments were performed by using tap-water and silicone oil with the viscosity of 2.0 mm^2/s(2cs-SiO)and 5.0 mm^2/s(5cs-SiO)as liquid phases. The effects of liquid viscosity and flow pattern on the AELAR performance were investigated. The predictions of the proposed model were in good agreement with the experimental results of the AELAR. In addition, the comparison of the experimental results shows that the proposed model has good accuracy and could be used to predict the gas holdup and liquid velocity of an AELAR operating in bubble and developing flow pattern.

Liquid Circulation in a Multi-tube Air-lift Loop Reactor

A multi-tube air-lift loop reactor (MT-ALR) is presented in this paper. Based on the energy conservation, a mathematical model describing the liquid circulation flow rate was developed, which was determined by gas velocity, the cross areas of riser and downcomer, gas hold-up and the local frictional loss coefficient. The experimental data indicate that either increase of gas flow rate or reduction of the downcomer diameter contributes to higher liquid circulation rate. The correlation between total and the local frictional loss coefficients was also established.Effects of gas flowrate in two risers and diameter of downcomer on the liquid circulation rate were examined. The value of total frictional loss coefficient was measured as a function of the cross area of downcomer and independent of the gas flow rate. The calculated results of liquid circulation rates agreed well with the experimental data with an average relative error of 9.6%.

Combustion behavior and influence mechanism of CO on iron ore sintering with flue gas recirculation

The properties of circulating gas have a significant effect on sintering with flue gas recirculation,and the influence of CO in sintering process was investigated.The results show that the post-combustion of CO conducts in sinter zone when flue gas passes through the sintering bed,which releases much heat and reduces the consumption of solid fuel.The ratio of coke breeze can be reduced from 5% to 4.7% with 2% CO in circulating flue gas.In addition,with the increase of CO content in circulating flue gas,the combustion efficiency of fuel is improved,and the flame front is increased slightly while still matches with the heat transfer front.These are beneficial to increasing the maximum temperature and prolonging the high temperature duration,especially in the upper layer of sintering bed.As a consequence,the productivity,vertical sintering velocity and quality of sinter are improved.

Mid-mantle water transportation implied by the electrical and seismic properties ofε-FeOOH

Water in the mantle transition zone and the core-mantle boundary plays a key role in Earth’s stratification,volatile cycling,and core formation.If water transportation is actively running between the aforementioned layers,the lower mantle should contain water channels with distinctive seismic and/or electromagnetic signatures.Here,we investigated the electrical conductivity and sound velocity ofε-FeOOH up to 71 GPa and 1800 K and compared them with global tomography data.An abrupt threeorder jump of electrical conductivity was observed above 50 GPa,reaching 1.24(12)×10^(3)S/m at 61 GPa.Meanwhile,the longitudinal sound velocity dropped by 16.8%in response to the high-to-low spin transition of Fe^(3+).The high-conductivity and low-sound velocity ofε-FeOOH match the features of heterogenous scatterers in the mid-lower mantle.Such unique properties of hydrousε-FeOOH,or possibly other Fe-enriched phases can be detected as evidence of active water transportation in the mid-lower mantle.