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MPA包覆的银纳米粒子修饰电极制备和电化学表征 被引量:1
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作者 吕桂琴 姚爱丽 郑传明 《北京理工大学学报》 EI CAS CSCD 北大核心 2006年第10期925-928,共4页
运用自组装和电化学组装法,将MPA包裹的银纳米粒子修饰到金电极表面,制备成银纳米粒子单层和多层膜修饰电极.循环电压电流和电化学阻抗谱测定结果表明:以MPA包覆的银纳米粒子修饰电极的氧化电位明显负移,显示出银纳米粒子具有更高的活性... 运用自组装和电化学组装法,将MPA包裹的银纳米粒子修饰到金电极表面,制备成银纳米粒子单层和多层膜修饰电极.循环电压电流和电化学阻抗谱测定结果表明:以MPA包覆的银纳米粒子修饰电极的氧化电位明显负移,显示出银纳米粒子具有更高的活性.以0.5 mmol/L的K3[Fe(CN)6]溶液为检测体系,电化学阻抗谱测试得出电极表面对探针分子的阻碍作用有所增加.循环电压电流结果表明:与单层膜修饰电极相比,多层膜修饰电极的峰电流显著增加. 展开更多
关键词 MPA 银纳米 修饰电极 循环电压-电流 电化学阻抗谱
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Theoretical analysis of the harmonic characteristics of modular multilevel converters 被引量:10
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作者 XIAO HuangQing XU Zheng +1 位作者 XUE YingLin TANG Geng 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第11期2762-2770,共9页
To understand the operation principle of the modular multilevel converter(MMC)deeply,it is necessary to study the harmonic characteristics of the MMC theoretically.Besides,the analytical harmonic formulas of the MMC a... To understand the operation principle of the modular multilevel converter(MMC)deeply,it is necessary to study the harmonic characteristics of the MMC theoretically.Besides,the analytical harmonic formulas of the MMC are useful in designing the main circuit,reducing the losses and improving the waveform quality.Based on the average switching function and the Fourier series harmonic analysis,this paper deduces the analytical expressions for such electrical quantities as the arm voltage,the arm current,the capacitor voltage,the capacitor current and the circulating current of the MMC.Finally,a digital model of a 21-level MMC-HVDC system is realized in PSCAD/EMTDC.The results of the analytical expressions coincide with the simulation results,which verify the effectiveness and feasibility of the proposed analytical expressions. 展开更多
关键词 modular multilevel converter harmonic characteristics average switching function Fourier series analysis PSCAD/EMTDC
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