几种空气源热泵热水器工质的实验研究

对三种混合工质(TJM01、TJM02、TJM03)的基本物理性质、安全环保性及溶油性进行了分析,又通过实验对三种混合工质的循环系统性能进行了分析。分析结果表明,三种混合工质在安全环保性和溶油性方面的差别都很小;在基本物性方面,TJM03较好;在系统性能方面,TJM03性能较好,而TJM01性能一般,TJM02性能较差。

Simulation of CO_2 Brayton Cycle for Engine Exhaust Heat Recovery under Various Operating Loads

A bottoming cycle system based on CO2 Brayton cycle is proposed to recover the engine exhaust heat. Its performance is compared with the conventional air Brayton cycle under five typical engine conditions. The results show that CO2 Brayton cycle proves to be superior to the air Brayton cycle in terms of the system net output power, thermal efficiency and recovery efficiency. In most cases, the recovery efficiency of CO2 Brayton cycle can be higher than 9% and the system has a better performance at the engine＇s high operating load, The thermal efficiency can be as large as 24.83% under 100% olaerating load, accordingly, the net outnut nower of 14.86 kW in nhtnined

Laccase Immobilized on Mesoporous Silica Materials and Its Corrosion Inhibition Performance in Circulating Cooling Water System

Mesoporous SiO_2 microspheres were synthesized using the sol-gel method and were characterized by TEM, FT-IR and BET techniques. The diameter of the microspheres is about 100—150 nm, and the average mesopore diameter is 2.55 nm, while the specific surface area is 1 088.9 m2/g. Mesoporous SiO_2 microspheres adsorb glutaraldehyde and immobilize laccase by means of the aldehyde group in glutaral which can react with the amidogen of laccase. The immobilization conditions were optimized at a glutaraldehyde concentration of 0.75%, a crosslinking time of 8 h, a laccase concentration of 0.04 L/L and an immobilization time of 10 h. When diesel leakage concentration was 80 mg/L, the highest corrosion inhibition efficiency of immobilized laccase reached 49.23%, which was slightly lower than the corrosion inhibition efficiency of free laccase(59%). The diesel degradation ratio could reach up to 45%. It has been proved that the immobilized laccase could degrade diesel to inhibit corrosion.

A Molecular Adsorbent Recycling System in Treating Posthepatectomy Acute Hepatic Failure Patients with Hepatocellular Carcinoma:a Bridge to Liver Transplantation

OBJECTIVE To evaluate the effect and safety of a Molecular Adsorbent Recycling System （MARS） in treating posthepatoectomy hepatic failure （AHF） patients surgically treated for primary hepatocellular carcinoma （HCC）. METHODS 12 AHF patients induced by resection of HCC were treated with MARS before orthotopic liver transplantation （OLT）. Their vital signs, urine volume, APACHElll and Glasgow scores were monitored. Routine laboratory blood tests, measurements of coagulatory function, liver and kidney function, serum ammonia, lactic acid and blood gas were conducted before and after treatment with MARS. All of the patients were followed up for a period of 6 months after OLT for prognosis and complication assessment. RESULTS Each patient was treated with MARS for 2-5 times （average of 3.6） with a length of 8-24 h each time. Their mean arterial blood pressure and urine volume were improved, APACHE III and Glasgow scores were better. Liver function was improved with the following alterations before and after treatment with MARS： serum ammonia （127.1±21.4 umol/L vs. 77.4±19.7 umol/L, P〈0.05）, lactic acid （6.53±0.45 mmol/L vs. 3.75± 0.40 mmol/L, P〈0.05） and total bilirubin （452.3±153.7 umol/L vs. 230.9± 115.2 umol/L, P〈0.05）. However, there was no significant change in platelet count （44.25±3.60×10^9/L vs. 43.19±8.26×10^9/L, P〉0.05） on international normalized ratio （INR） （2.74±0.50 vs. 2.82±0.60, P〉0.05）, which showed the safety of MARS. For all patients no serious adverse effects occurred during the treatment with MARS. CONCLUSION MARS is effective and safe for treatment of AHF patients with HCC, especially as a bridge to OLT when a donor organ is not available.

Study on Filtration Performance of Silica/ Alumina Slurry in the Process of Recycling Mother Liquor of NaY Zeolite

In order to recover the SiO_2 contained in the mother liquor in the course ofNaY zeolite synthesis to minimize pollution, the influence of various preparation conditions on thefiltering velocity of gel slurry was studied using the SiO_2/Al_2O_3 gel recovered from the NaYmother liquor in the laboratory. The results of study had shown that at a SiO_2/Al_2O_3 ratio in thefeed equating to 9∶1 the SiO_2 recovery rate and Al_2O_3 utilization rate were high with a fasterflow velocity of the filtrate. The pH value of the system had great impact on the flow velocity offiltrate. Between the two methods for regulating the pH value, the one for formation ofsilica/alumina gel slurry by addition of sulfuric acid prior to adding aluminium sulfate in thesolution could secure a faster filtration velocity. The filtration velocity was decreased in tandemwith increasing SiO_2 concentration in mother liquor, meanwhile an increase in dry filter cakeyield.

Evaluation of Feed and Feeding Regime on Growth Performance, Flesh Quality and Fecal Viscosity of Atlantic Salmon(Salmo salar L.) in Recirculating Aquaculture Systems

The effects of different feeds and feeding regimes on growth performance, flesh quality and fecal viscosity of Atlantic salmon （Salmo salar L.） in recirculating aquaculture systems （R.AS） were investigated. Fish （initial body weight of 1677 g＋ 157 g） were fed with four commercial feeds （Nosan salmon-NS, Aller gold-AG, Skretting salmon-SS and Hart ye-HY） in two feeding regimes （80% and 100% satiation） for 78 d. The results showed that salmon specific growth ratio （SGR） and weight gain ratio （WGR） were significantly affected by feed type and feeding regime （P〈0.05）. Feed conversion ratio （FCR） varied between 0.93 and 3.40, which was significantly affected by feed type （P〈0.05）, and slightly improved with increased satiation degree. The activities of digestive enzymes including protease, lipase and amylase were also significantly affected by feed type and feeding regime （P〈0.05）, increasing with satiation degree. Flesh qualities for vitamin E, hydroxyproline （HYP）, liquid loss and muscle pH among all groups showed significant differences （P〈0.05）, ranging from 26.67 to 29.67, while no obvious difference was found in flesh color. Fecal viscosity for different treatments showed no significant difference, though improvement was found in 100% satiation group. From present experiment, it was concluded that both feed type and feeding regime can affect the important quality attributes of Atlantic salmon.

Performance Improvement of Combined Cycle Power Plant Based on the Optimization of the Bottom Cycle and Heat Recuperation

Many F class gas turbine combined cycle （GTCC） power plants are built in China at present because of less emission and high efficiency. It is of great interest to investigate the efficiency improvement of GTCC plant. A combined cycle with three-pressure reheat heat recovery steam generator （HRSG） is selected for study in this paper. In order to maximize the GTCC efficiency, the optimization of the HRSG operating parameters is performed. The operating parameters are determined by means of a thermodynamic analysis, i.e. the minimization of exergy losses. The influence of HRSG inlet gas temperature on the steam bottoming cycle efficiency is discussed. The result shows that increasing the HRSG inlet temperature has less improvement to steam cycle efficiency when it is over 590℃. Partial gas to gas recuperation in the topping cycle is studied. Joining HRSG optimization with the use of gas to gas heat recuperation, the combined plant efficiency can rise up to 59.05% at base load. In addition, the part load performance of the GTCC power plant gets much better. The efficiency is increased by 2.11% at 75% load and by 4.17% at 50% load.

General construction of lithiophilic 3D skeleton for dendrite-free lithium metal anode via a versatile MOF-derived route

The pursuit of high-mileage models results in the recurrence of lithium metal batteries(LMBs)to researchers’horizon.However,the lithium(Li)metal anode for LMBs undergoes the uncontrollable formation of Li dendrites and infinite volume change during cycling,impeding its practical application.To overcome these challenges,we developed a metal-organic framework(MOF)-derived pathway to construct lithiophilic three-dimensional(3D)skeleton using different substrates(e.g.,carbon cloth(CC)and Cu mesh)for dendrite-free lithium metal anodes.As a typical example,the MOF-derived ZnO/nitrogen-doped carbon(NC)nanosheet-modified 3D CC was well-constructed as a lithiophilic hierarchical host(CC@ZnO/NC@Li)for molten Li infiltration.Benefiting from the lithiophilic N-functional groups and LiZn alloy,the synthesized CC@ZnO/NC@Li composite anode promoted the uniform distribution of Li,resulting in a dendrite-free morphology.Meanwhile,the 3D conductive carbon skeleton enhanced the reaction kinetics and buffered the volume change of the electrode.The CC@ZnO/NC@Li composite anode presented a prolonged lifespan of over 1000 cycles at 5 mA cm^(−2) with a low overpotential of 19 mV.Coupled with a LiFePO_(4) cathode,the CC@ZnO/NC@Li composite anode also exhibited superior electrochemical properties in the full-cell system.This versatile strategy may open up the channel of designing multi-functional lithiophilic 3D hosts for the Li metal anode.

Enhancement of Natural Circulation Type Domestic Solar Hot Water System Performance by using a Wind Turbine

Performance improvement of existing 200 litres capacity natural convection type domestic solar hot water system is attempted.A two-stage centrifugal pump driven by a vertical axis windmill having Savonius type rotor is added to the fluid loop.The windmill driven pump circulates the water through the collector.The system with necessary instrumentation is tested over a day.Tests on Natural Circulation System(NCS)mode and Wind Assisted System(WAS)mode are carried out during January,April,July and October,2009.Test results of a clear day are reported.Daily average efficiency of 25-28% during NCS mode and 33-37% during WAS mode are obtained.With higher wind velocities,higher collector flow rates and hence higher efficiencies are obtained.In general,WAS mode provides improvements in efficiency when compared to NCS mode.