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新FIA微分光度法测合金钢中微量锡 被引量:2
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作者 赵珍义 于吉 宋金和 《现代科学仪器》 2008年第5期52-53,共2页
研究了一种高选择性、高灵敏度流动注射微分光度检测痕量锡的方法。基于十二烷硫酸钠存在下,锡与水杨基荧光酮在强酸介质中形成三元络合物最大吸收波长为503nm。利用一次进样产生的正负两个拐点的微分光度值(△A)进行定量分析。试验表明... 研究了一种高选择性、高灵敏度流动注射微分光度检测痕量锡的方法。基于十二烷硫酸钠存在下,锡与水杨基荧光酮在强酸介质中形成三元络合物最大吸收波长为503nm。利用一次进样产生的正负两个拐点的微分光度值(△A)进行定量分析。试验表明,常见干扰离子均不发生类似的显色反应,具有很高的选择性和灵敏度,不需要分离可直接测定钢铁样品中的痕量锡。 展开更多
关键词 微分吸光光度法 流动注射分析 水杨基荧光酮
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Determination of Five Metallic Elements in Guoshangye from Guizhou by Microwave Digestion-flame Atomic Absorption Spectrometry
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作者 马四补 王绍辉 +2 位作者 刘同祥 李开斌 陈维 《Agricultural Science & Technology》 CAS 2016年第2期262-264,共3页
In the study, the contents of 5 trace elements including Fe, Cu, Mg, Mn and Ca were directly analyzed by flame atomic absorption spectroscopy in Gu- oshangye. The sample was subjected to microwave digestion with HNO3 ... In the study, the contents of 5 trace elements including Fe, Cu, Mg, Mn and Ca were directly analyzed by flame atomic absorption spectroscopy in Gu- oshangye. The sample was subjected to microwave digestion with HNO3 and H2O2, and detected by the standard curve method. The results showed that Guoshangye contained abundant trace elements which rates of these trace elements were in the curacy and satisfactory. were necessary for human. The recovery range of 96%-103%. The method is ac- 展开更多
关键词 Trace elements Guoshangye Flame atomic absorption spectroscopy
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UV-Vis Spectrophotometry and AFM Observation of Diethyl Dithiophosphate Adsorption on Chalcopyrite at Varied pHs 被引量:1
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作者 Himawan T. B. M. Petrus Tsuyoshi Hirajima +1 位作者 Keiko Sasaki Hideyuki Okamoto 《Journal of Chemistry and Chemical Engineering》 2011年第11期1006-1013,共8页
Adsorption of diehtyl dithiophosphate on chalcopyrite has been studied using UV-visible spectroscopy at pH values of 4, 6, and 9. It was found that the adsorption of diethyl dithiophosphate decreased with the increasi... Adsorption of diehtyl dithiophosphate on chalcopyrite has been studied using UV-visible spectroscopy at pH values of 4, 6, and 9. It was found that the adsorption of diethyl dithiophosphate decreased with the increasing pH treatments. The inhibition of diethyl dithiophosphate adsorption was found prominent in higher pH as a result of metal hydroxide species formation onto chalcopyrite surface. First order kinetic has been proposed and represented the adsorption mechanism. Flotation test using Hallimond tube has also been conducted and the results were consistent with the proposed mechanism. Furthermore, the morphological changes of the treated chalcopyrite were observed using Atomic Force Microscopy (AFM) showing the propensity of growth of islands, the new surfaces as products of the reaction. The hydrophobicity was measured in the form of force of adhesion. The results resembled with the approached mechanism. 展开更多
关键词 CHALCOPYRITE diethyl dithiophosphate ADSORPTION kinetic study AFM FLOATABILITY
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