The intrinsic kinetics of iron oxide reduced by carbon monoxide is evaluated by a method of online measuring concentration of off-gas in an isothermal differential micro-packed bed. Under the condition of getting away...The intrinsic kinetics of iron oxide reduced by carbon monoxide is evaluated by a method of online measuring concentration of off-gas in an isothermal differential micro-packed bed. Under the condition of getting away from the influence of gas diffusion and gas–solid heat transfer and mass transfer, the reaction of Fe2O3 to Fe3O4, Fe3O4 to Fe O and Fe O to Fe in the process of single reaction can be clearly distinguished from each other, and the relevant activation energy is characterized to be 75.4, 74.4, and 84.0 k J·mol-1, respectively. Therefore, the change of surface area in the reaction process due to losing oxygen could be easily calculated by combining it with pre-exponential parameters of Arrhenius equations. In conclusion, these kinetic parameters are verified by the experimental data for the process of ore reduced by carbon monoxide in a packed bed.展开更多
The definitions of controllability, observability and stability were presented for fractional-order linear systems. Using the Cayley-Hamilton theorem and Mittag-Leffler function in two parameters, the sufficient and n...The definitions of controllability, observability and stability were presented for fractional-order linear systems. Using the Cayley-Hamilton theorem and Mittag-Leffler function in two parameters, the sufficient and necessary conditions of controllability and observability for such systems were derived. In terms of Lyapunov’s stability theory, using the theorems of Mittage-Leffler function in two parameters this paper directly derived the sufficient and necessary condition of stability for such systems. The results obtained are useful for the analysis and synthesis of fractional-order linear control systems.展开更多
A fast explicit finite difference method (FEFDM),derived from the differential equations of one-dimensional steady pipe flow,was presented for calculation of wellhead injection pressure.Recalculation with a traditiona...A fast explicit finite difference method (FEFDM),derived from the differential equations of one-dimensional steady pipe flow,was presented for calculation of wellhead injection pressure.Recalculation with a traditional numerical method of the same equations corroborates well the reliability and rate of FEFDM.Moreover,a flow rate estimate method was developed for the project whose injection rate has not been clearly determined.A wellhead pressure regime determined by this method was successfully applied to the trial injection operations in Shihezi formation of Shenhua CCS Project,which is a good practice verification of FEFDM.At last,this method was used to evaluate the effect of friction and acceleration terms on the flow equation on the wellhead pressure.The result shows that for deep wellbore,the friction term can be omitted when flow rate is low and in a wide range of velocity the acceleration term can always be deleted.It is also shown that with flow rate increasing,the friction term can no longer be neglected.展开更多
According to the fact that the surface of liquid with low viscosity coefficient is a good reflection plane for a broadband light beam, liquid-level measurement in micrometer resolution is designed based on a fiber-opt...According to the fact that the surface of liquid with low viscosity coefficient is a good reflection plane for a broadband light beam, liquid-level measurement in micrometer resolution is designed based on a fiber-optic low coherence interferometer in Michelson configuration. The wave front of the reflected light beam is well enough to form an interferogram with a beam reflected from an optic mirror mounted on a stepping scanning-motor. The central peak of the interferogram is read as a measure of the liquid level. Experimental results show that this noncontact method can reach a resolution of ±1.25 μm in the measurement range of 86 mm.展开更多
Differential electrolytic potentiometry (DEP) was coupled with Flow injection analysis (FIA) technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indi...Differential electrolytic potentiometry (DEP) was coupled with Flow injection analysis (FIA) technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indicating system to follow the oxidation of Procainamide with cerium(IV), and permanganate in an acidic medium. The oxidation reactions of Procainamide with Ce(IV) and/or permanganate are fast enough to permit its determination by flow injection in sulfuric acid media. The univariate method was employed to optimize the variables such as the current density, the flow rate, the oxidant concentration and the concentration of sulfuric acid. The proposed method was linear in the range 20-100 μg.mL^-1 , the DL and R2 values were 12 μg.mL^-1 and 0.995 respectively. The procedure was applied successfully to the determination of Procainamide in commercial tablets. The results of this study were favorably compared statistically with those obtained with official methods.展开更多
Six kinds of terbium ternary complexes with halo-benzoic acids were synthesized. Their compositions were determined by C, H elemental analyzer and EDTA titration. The infrared spectra, ultraviolet absorption spectra, ...Six kinds of terbium ternary complexes with halo-benzoic acids were synthesized. Their compositions were determined by C, H elemental analyzer and EDTA titration. The infrared spectra, ultraviolet absorption spectra, and fluorescence spectra were also measured to identify the complexes. Elemental analysis showed that the compositions of these complexes were Tb(p-BrBA)3- H20, Tb(p-CIBA)3- 2H20, Tb(p-FBA)3- H20, Tb(o-FBA)3·2H20, Tb(o-CIBA)3· H20, and Tb(o-BrBA)3. H20, respectively. The monodispersed Ag@SiO2 core-shell nanoparticles with silica thicknesses of 10, 15, and 25 nm were success- fully prepared and characterized by transmission-electron microscopy. Fluorescence intensities of the complexes were detected before and after Ag@SiO2core-shell nanoparticles were added; the enhancement times were related to the silica-shell thick- ness. The fluorescence enhancement times were largest when the thickness of the silica shell was 25 nm. The mechanism may be attributed to the localized surface-plasmon resonance. Furthermore, the enhancement effect of terbium fluoro-benzoate complexes was the strongest in these complexes. This result may be attributed to the hydrogen bond between the hydroxyl on the surface of the silica shell and the fluorine atom.展开更多
Micro-displacement measurement based on self-mixing interference using a fiber laser system was demonstrated. The sinusoidal phase modulation technique was introduced into the fiber laser self-mixing interference meas...Micro-displacement measurement based on self-mixing interference using a fiber laser system was demonstrated. The sinusoidal phase modulation technique was introduced into the fiber laser self-mixing interference measurement system to improve the measurement resolution. The phase could be demodulated by the Fourier analysis method. Error sources were evaluated in detail, and the system was experimentally applied to reconstruct the motion of a high-precision commercial piezoelectric ceramic transducer (PZT). The displacement measurement resolution was well beyond a half-wavelength. It provides a practical solution for displacement measurement based on all optical-fiber sensing applications with high precision.展开更多
基金Supported by the State Key Development Program for Basic Research of China(2015CB251402)the National Natural Science Foundation of China(21206159)
文摘The intrinsic kinetics of iron oxide reduced by carbon monoxide is evaluated by a method of online measuring concentration of off-gas in an isothermal differential micro-packed bed. Under the condition of getting away from the influence of gas diffusion and gas–solid heat transfer and mass transfer, the reaction of Fe2O3 to Fe3O4, Fe3O4 to Fe O and Fe O to Fe in the process of single reaction can be clearly distinguished from each other, and the relevant activation energy is characterized to be 75.4, 74.4, and 84.0 k J·mol-1, respectively. Therefore, the change of surface area in the reaction process due to losing oxygen could be easily calculated by combining it with pre-exponential parameters of Arrhenius equations. In conclusion, these kinetic parameters are verified by the experimental data for the process of ore reduced by carbon monoxide in a packed bed.
基金Shanghai Science and Technology Devel-opm ent Funds ( No.0 1160 70 3 3)
文摘The definitions of controllability, observability and stability were presented for fractional-order linear systems. Using the Cayley-Hamilton theorem and Mittag-Leffler function in two parameters, the sufficient and necessary conditions of controllability and observability for such systems were derived. In terms of Lyapunov’s stability theory, using the theorems of Mittage-Leffler function in two parameters this paper directly derived the sufficient and necessary condition of stability for such systems. The results obtained are useful for the analysis and synthesis of fractional-order linear control systems.
基金Project(Z110803)supported by the State Key Laboratory of Geomechanics and Geotechnical Engineering,ChinaProject(2008AA062303)supported by the National High Technology Research and Development Program of China
文摘A fast explicit finite difference method (FEFDM),derived from the differential equations of one-dimensional steady pipe flow,was presented for calculation of wellhead injection pressure.Recalculation with a traditional numerical method of the same equations corroborates well the reliability and rate of FEFDM.Moreover,a flow rate estimate method was developed for the project whose injection rate has not been clearly determined.A wellhead pressure regime determined by this method was successfully applied to the trial injection operations in Shihezi formation of Shenhua CCS Project,which is a good practice verification of FEFDM.At last,this method was used to evaluate the effect of friction and acceleration terms on the flow equation on the wellhead pressure.The result shows that for deep wellbore,the friction term can be omitted when flow rate is low and in a wide range of velocity the acceleration term can always be deleted.It is also shown that with flow rate increasing,the friction term can no longer be neglected.
基金Dalian Science and Technology Foundation and National Science Foundation(30470416)
文摘According to the fact that the surface of liquid with low viscosity coefficient is a good reflection plane for a broadband light beam, liquid-level measurement in micrometer resolution is designed based on a fiber-optic low coherence interferometer in Michelson configuration. The wave front of the reflected light beam is well enough to form an interferogram with a beam reflected from an optic mirror mounted on a stepping scanning-motor. The central peak of the interferogram is read as a measure of the liquid level. Experimental results show that this noncontact method can reach a resolution of ±1.25 μm in the measurement range of 86 mm.
文摘Differential electrolytic potentiometry (DEP) was coupled with Flow injection analysis (FIA) technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indicating system to follow the oxidation of Procainamide with cerium(IV), and permanganate in an acidic medium. The oxidation reactions of Procainamide with Ce(IV) and/or permanganate are fast enough to permit its determination by flow injection in sulfuric acid media. The univariate method was employed to optimize the variables such as the current density, the flow rate, the oxidant concentration and the concentration of sulfuric acid. The proposed method was linear in the range 20-100 μg.mL^-1 , the DL and R2 values were 12 μg.mL^-1 and 0.995 respectively. The procedure was applied successfully to the determination of Procainamide in commercial tablets. The results of this study were favorably compared statistically with those obtained with official methods.
基金supported by the National Natural Science Foundation of China(21161013)the Natural Science Foundation of Inner Mongolia(2011MS0202)the Opening Foundation for Significant Fundamental Research of Inner Mongolia(2010KF03)
文摘Six kinds of terbium ternary complexes with halo-benzoic acids were synthesized. Their compositions were determined by C, H elemental analyzer and EDTA titration. The infrared spectra, ultraviolet absorption spectra, and fluorescence spectra were also measured to identify the complexes. Elemental analysis showed that the compositions of these complexes were Tb(p-BrBA)3- H20, Tb(p-CIBA)3- 2H20, Tb(p-FBA)3- H20, Tb(o-FBA)3·2H20, Tb(o-CIBA)3· H20, and Tb(o-BrBA)3. H20, respectively. The monodispersed Ag@SiO2 core-shell nanoparticles with silica thicknesses of 10, 15, and 25 nm were success- fully prepared and characterized by transmission-electron microscopy. Fluorescence intensities of the complexes were detected before and after Ag@SiO2core-shell nanoparticles were added; the enhancement times were related to the silica-shell thick- ness. The fluorescence enhancement times were largest when the thickness of the silica shell was 25 nm. The mechanism may be attributed to the localized surface-plasmon resonance. Furthermore, the enhancement effect of terbium fluoro-benzoate complexes was the strongest in these complexes. This result may be attributed to the hydrogen bond between the hydroxyl on the surface of the silica shell and the fluorine atom.
基金This work was supported by the National Natural Science Foundation of China (Grant No. 91123015, 51405240), the Specialized Research Fund for the Doctoral Program of Higher Education (20113207110004), and the Natural Science Foundation of Jiangsu Province(BK20140925). Open Access This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
文摘Micro-displacement measurement based on self-mixing interference using a fiber laser system was demonstrated. The sinusoidal phase modulation technique was introduced into the fiber laser self-mixing interference measurement system to improve the measurement resolution. The phase could be demodulated by the Fourier analysis method. Error sources were evaluated in detail, and the system was experimentally applied to reconstruct the motion of a high-precision commercial piezoelectric ceramic transducer (PZT). The displacement measurement resolution was well beyond a half-wavelength. It provides a practical solution for displacement measurement based on all optical-fiber sensing applications with high precision.