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应用气相色谱-质谱联用仪及微分流技术测定重芳烃中萘 被引量:1
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作者 王红卫 王华 +2 位作者 张晓冬 王爱国 陆彩霞 《理化检验(化学分册)》 CAS CSCD 北大核心 2009年第1期27-29,共3页
将微分流技术与气相色谱-质谱相结合并应用于重芳烃中萘的定性与定量检测,用甲苯作溶剂稀释重芳烃样品制成试样溶液,测定中采用火焰离子化检测器,峰面积的测定值与相应的萘浓度在0.200 g/100 mL以内呈线性关系。对同一样品分析5次,算得... 将微分流技术与气相色谱-质谱相结合并应用于重芳烃中萘的定性与定量检测,用甲苯作溶剂稀释重芳烃样品制成试样溶液,测定中采用火焰离子化检测器,峰面积的测定值与相应的萘浓度在0.200 g/100 mL以内呈线性关系。对同一样品分析5次,算得测定结果的相对标准偏差为0.45%,用标准加入法进行了回收试验,测得回收率在92.8%~100.2%之间。 展开更多
关键词 气相色谱-质谱联用法 微分流技术 重芳烃
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Comparative analysis of residence and diffusion times in rotating bed used for biogas upgrading 被引量:1
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作者 Liang Zhang Akiber Chufo Wachemo +2 位作者 Hairong Yuan Yunzhi Pang Xiujin Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第10期2148-2152,共5页
Rotating bed can be used in desorption operation of biogas upgrading as a new technology. For enough time to desorb, it is important to study the relationship between the residence time of liquid in rotating bed and t... Rotating bed can be used in desorption operation of biogas upgrading as a new technology. For enough time to desorb, it is important to study the relationship between the residence time of liquid in rotating bed and the material diffusion time of liquid droplet in desorption process. By theoretical deduction, the exponential relation between residence time and liquid flow rate and rotational speed and kinematic viscosity is obtained. By analyzing the solution of nonlinear partial differential equation, the time law of material diffusion in the droplet is obtained. Moreover, by comparing the residence and diffusion times, the diffusion time can be within or out of residence time range, which has a direct relationship to rotational speed and liquid flow. By experiment, the comparison between residence and diffusion times is more realistic when the rotational speed is higher. 展开更多
关键词 Rotating bed Biogas upgrading DESORPTION RESIDENCE Diffusion Mass transfer
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Imaging dynamic water invasion behavior in microfractures based on microfluidics
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作者 ZHANG Ji-cheng CHEN Shao-jie +3 位作者 JI Song-tao FENG Fan ALEKSEY A.Khoreshok ZAKI M.Mohammed 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第12期3986-4001,共16页
Fluid invasion through fractures is frequently observed in subsurface engineering. To elucidate the microkinetic behavior of fracture fluids, the microfracture structure of coal from the Surat Basin was reconstructed ... Fluid invasion through fractures is frequently observed in subsurface engineering. To elucidate the microkinetic behavior of fracture fluids, the microfracture structure of coal from the Surat Basin was reconstructed using a 3D morphometric system and stitching algorithm, then the transparent models characterizing the fracture structure were produced using microfluidics, and water invasion in the microfracture model was measured via visualization experiments under various conditions. High flow rate facilitated the invasion of the water phase into the closed channel, improving the efficiency of water invasion in the neutral wetting system. Wettability reversal changed the dominant channel for water invasion in the hydrophobic system. The invasion efficiency in closed and small aperture bypass channels was low.The reduction of effective seepage channels led to the fastest breakthrough time. Higher surface tension and interfacial curvature promoted the hysteresis effect. The reduction of effective seepage channels led to the fastest breakthrough time. The larger surface tension and interfacial curvature make the hysteresis effect more significant. These results will enable a better understanding of the rock-gas-liquid multiphase interaction mechanisms under unsaturated conditions of rocks. 展开更多
关键词 MICROFRACTURE visualized models MICROFLUIDICS phase distribution capillary hysteresis
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400kA高低块阴极结构铝电解槽焙烧启动工艺实践 被引量:1
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作者 禹玉江 李文超 邱国利 《有色冶金节能》 2013年第2期26-29,共4页
针对异性结构阴极电解槽,从不同工艺的升温策略和操作步骤对阴极寿命的影响,工艺实施的复杂程度等方面进行了详细探讨,最终选择焦粒结合碎炭块作为阴极块处填充料,解决了异型阴极结构中电解槽焦粒焙烧的核心问题。经过对多台异型阴极结... 针对异性结构阴极电解槽,从不同工艺的升温策略和操作步骤对阴极寿命的影响,工艺实施的复杂程度等方面进行了详细探讨,最终选择焦粒结合碎炭块作为阴极块处填充料,解决了异型阴极结构中电解槽焦粒焙烧的核心问题。经过对多台异型阴极结构电解槽焙烧启动的实践验证,该法对阳极和阴极均无损伤。 展开更多
关键词 铝电解 高低块阴极装炉 焙烧 启动 分流调整、均恒温技术
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