In this study,we considered the wetting phenomenon on a general substrate from a new viewpoint of continuum mechanics.The analyses first show how the Wenzel and the Cassie models deviate the practical results in some ...In this study,we considered the wetting phenomenon on a general substrate from a new viewpoint of continuum mechanics.The analyses first show how the Wenzel and the Cassie models deviate the practical results in some special substrates,and then elucidate the mechanism of the triple contact line(TCL) moving.Based upon variational theory of the total free functional dealing with the movable boundary condition,we show that the macroscopic contact angle(MCA) expression is the corresponding transversality condition.It manifests that the MCA depends only on the chemical and geometric property at the TCL,and is not affected by the gravity of the droplet and the contact area beneath the liquid.Our continuum model also shows the exploration of the pinning effect on a sharp wedge or the interface between two different phases.This investigation will help designing super-hydrophobic materials for novel micro-fluidic devices.展开更多
The bias stability of differential interferometric fiber optical gyroscope is analyzed.Thermal error causing long-term bias drift are reduced by putting the 90°splice in the middle of the fiber coil and applying ...The bias stability of differential interferometric fiber optical gyroscope is analyzed.Thermal error causing long-term bias drift are reduced by putting the 90°splice in the middle of the fiber coil and applying a wide spectrum light source.Also,a kind of novel optical differential processing,which is much more precise than the electronic differential processing,is proposed for reducing the residual nonreciprocal error in the final differential output.An experimental setup based on optical differential processing was built.An^100 fold reduction in the long-term bias drift is demonstrated experimentally compared with the primary differential interferometric fiber optical gyroscope.展开更多
Molecularly imprinted polymers are generated by curing a cross-linked polymer in the presence of a template. During the curing process, noncovalent bonds form between the polymer and the template. The interaction site...Molecularly imprinted polymers are generated by curing a cross-linked polymer in the presence of a template. During the curing process, noncovalent bonds form between the polymer and the template. The interaction sites for the noncovalent bonds become "frozen" in the cross-linking polymer and maintain their shape even after the template is removed. The resulting cavities reproduce the size and shape of the template and can selectively reincorporate the template when a mixture containing it flows over the imprinted surface. In the last few decades the field of molecular imprinting has evolved from being able to selectively capture only small molecules to dealing with all kinds of samples. Molecularly imprinted polymers (MIPs) have been generated for analytes as diverse as metal ions, drug molecules, environmental pollutants, proteins and viruses to entire cells. We review here the relatively new field of surface imprinting, which creates imprints of large, biologically relevant templates. The traditional bulk imprinting, where a template is simply added to a prepolymer before curing, cannot be applied if the analyte is too large to diffuse from the cured polymer. Special methods must be used to generate binding sites only on a surface. Those techniques have solved crucial problems in separation science as well as chemical and biochemical sensing. The implementation of imprinted polymers into microfluidic chips has greatly improved the applicability of microfluidics. We present the latest advances and different approaches of surface imprinting and their applications for microfluidic devices.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.10802099,11272357 and 11102140)the Doctoral Fund of Ministry of Education of China(Grant No.20110141120024)+2 种基金the Natural Science Foundation of Shandong Province(Grant No.ZR2009AQ006)the Opening Project of State Key Laboratory of Explosion Science and Technology(Beijing Institute of Technology)(Grant No. KFJJ12-11M)the support from the Brain Korea 21 Program at Seoul National University
文摘In this study,we considered the wetting phenomenon on a general substrate from a new viewpoint of continuum mechanics.The analyses first show how the Wenzel and the Cassie models deviate the practical results in some special substrates,and then elucidate the mechanism of the triple contact line(TCL) moving.Based upon variational theory of the total free functional dealing with the movable boundary condition,we show that the macroscopic contact angle(MCA) expression is the corresponding transversality condition.It manifests that the MCA depends only on the chemical and geometric property at the TCL,and is not affected by the gravity of the droplet and the contact area beneath the liquid.Our continuum model also shows the exploration of the pinning effect on a sharp wedge or the interface between two different phases.This investigation will help designing super-hydrophobic materials for novel micro-fluidic devices.
基金supported by the National Natural Science Foundation of China(Grant No.61205077)
文摘The bias stability of differential interferometric fiber optical gyroscope is analyzed.Thermal error causing long-term bias drift are reduced by putting the 90°splice in the middle of the fiber coil and applying a wide spectrum light source.Also,a kind of novel optical differential processing,which is much more precise than the electronic differential processing,is proposed for reducing the residual nonreciprocal error in the final differential output.An experimental setup based on optical differential processing was built.An^100 fold reduction in the long-term bias drift is demonstrated experimentally compared with the primary differential interferometric fiber optical gyroscope.
文摘Molecularly imprinted polymers are generated by curing a cross-linked polymer in the presence of a template. During the curing process, noncovalent bonds form between the polymer and the template. The interaction sites for the noncovalent bonds become "frozen" in the cross-linking polymer and maintain their shape even after the template is removed. The resulting cavities reproduce the size and shape of the template and can selectively reincorporate the template when a mixture containing it flows over the imprinted surface. In the last few decades the field of molecular imprinting has evolved from being able to selectively capture only small molecules to dealing with all kinds of samples. Molecularly imprinted polymers (MIPs) have been generated for analytes as diverse as metal ions, drug molecules, environmental pollutants, proteins and viruses to entire cells. We review here the relatively new field of surface imprinting, which creates imprints of large, biologically relevant templates. The traditional bulk imprinting, where a template is simply added to a prepolymer before curing, cannot be applied if the analyte is too large to diffuse from the cured polymer. Special methods must be used to generate binding sites only on a surface. Those techniques have solved crucial problems in separation science as well as chemical and biochemical sensing. The implementation of imprinted polymers into microfluidic chips has greatly improved the applicability of microfluidics. We present the latest advances and different approaches of surface imprinting and their applications for microfluidic devices.
