为研究褐煤直接液化反应动力学,在100 m L微型高压釜中,对艾丁褐煤进行等温加氢液化实验研究,建立了褐煤直接液化反应的动力学模型,并通过Origin软件回归出各反应速率常数及相应的活化能和指前因子。结果表明,煤中的反应组分生成各产物...为研究褐煤直接液化反应动力学,在100 m L微型高压釜中,对艾丁褐煤进行等温加氢液化实验研究,建立了褐煤直接液化反应的动力学模型,并通过Origin软件回归出各反应速率常数及相应的活化能和指前因子。结果表明,煤中的反应组分生成各产物的反应速率顺序为:非酚油>沥青质酚>气体;反应组分M1主要生成非酚油和沥青质,是直接转化成非酚油和酚的主要来源,沥青质向非酚油的转化是非酚油产率增加的速率控制步骤,沥青质向酚的转化速率是酚产率增加的速率控制步骤,实行分级加氢液化更有利于控制和提高非酚油和酚的产率;褐煤中仅生成CO2的组分M2在一定温度条件下,短时间即可转化为CO2,并转化完全;液化反应中反应组分(M1)向气体(Gas)转化,以及沥青质(PAA)向酚(Phe)转化过程对温度较敏感。展开更多
This paper discusses the technique of casting concrete ofmicropiles with pressures and the consequence of comparisons with normal way of casting concrete (casting with gravity). Preliminary geotechnical studies have...This paper discusses the technique of casting concrete ofmicropiles with pressures and the consequence of comparisons with normal way of casting concrete (casting with gravity). Preliminary geotechnical studies have been made in specific area in Sudan to predict the soil parameters and then an experimental work has been done for an estimated number ofmicropiles with different diameters and different techniques of placing concrete with various amount of pressure. This study was carried out to learn the usefulness of this technique in the field of structural foundations in Sudan. Capacities of micropiles were compared in cases of non-pressure casting (normal way of casting concrete) and pressure casting. Through the results, it was found that the entry of pressure factor in the operation of casting concrete increases the capacities of micropiles. The increased value of ultimate load depends on the amount of pressure applied.展开更多
文摘为研究褐煤直接液化反应动力学,在100 m L微型高压釜中,对艾丁褐煤进行等温加氢液化实验研究,建立了褐煤直接液化反应的动力学模型,并通过Origin软件回归出各反应速率常数及相应的活化能和指前因子。结果表明,煤中的反应组分生成各产物的反应速率顺序为:非酚油>沥青质酚>气体;反应组分M1主要生成非酚油和沥青质,是直接转化成非酚油和酚的主要来源,沥青质向非酚油的转化是非酚油产率增加的速率控制步骤,沥青质向酚的转化速率是酚产率增加的速率控制步骤,实行分级加氢液化更有利于控制和提高非酚油和酚的产率;褐煤中仅生成CO2的组分M2在一定温度条件下,短时间即可转化为CO2,并转化完全;液化反应中反应组分(M1)向气体(Gas)转化,以及沥青质(PAA)向酚(Phe)转化过程对温度较敏感。
文摘This paper discusses the technique of casting concrete ofmicropiles with pressures and the consequence of comparisons with normal way of casting concrete (casting with gravity). Preliminary geotechnical studies have been made in specific area in Sudan to predict the soil parameters and then an experimental work has been done for an estimated number ofmicropiles with different diameters and different techniques of placing concrete with various amount of pressure. This study was carried out to learn the usefulness of this technique in the field of structural foundations in Sudan. Capacities of micropiles were compared in cases of non-pressure casting (normal way of casting concrete) and pressure casting. Through the results, it was found that the entry of pressure factor in the operation of casting concrete increases the capacities of micropiles. The increased value of ultimate load depends on the amount of pressure applied.