Existence of positive solution is established for boundary value problems of nonsingular for a class quasi-linear ordinary differential equation on the semi-infinite interval. The results are obtained by using the non...Existence of positive solution is established for boundary value problems of nonsingular for a class quasi-linear ordinary differential equation on the semi-infinite interval. The results are obtained by using the nonlinear alternative of Leray-Schauder method.展开更多
The fundamental problem of an elastic-plastic body subjected to incremental loading is reviewed using a compact internal variable approach based on work carried out at the University of Cape Town in which a quadratic ...The fundamental problem of an elastic-plastic body subjected to incremental loading is reviewed using a compact internal variable approach based on work carried out at the University of Cape Town in which a quadratic functional was developed for the free energy using Taylor series. Now the departure from that approach is the focus on developing the Liapunov function for the nonlinear differential equations of motion. Static and dynamic equations of motion are derived and shown to meet the requirements of the Liapunov function. As a consequence, time integration parameters that are used in the discrete formulations are easily obtained based on the same requirements. The resulting generalized Newton-Raphson scheme is stable in the sense of Liapunov＇s direct method.展开更多
Differential electrolytic potentiometry （DEP） was coupled with Flow injection analysis （FIA） technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indi...Differential electrolytic potentiometry （DEP） was coupled with Flow injection analysis （FIA） technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indicating system to follow the oxidation of Procainamide with cerium（IV）, and permanganate in an acidic medium. The oxidation reactions of Procainamide with Ce（IV） and/or permanganate are fast enough to permit its determination by flow injection in sulfuric acid media. The univariate method was employed to optimize the variables such as the current density, the flow rate, the oxidant concentration and the concentration of sulfuric acid. The proposed method was linear in the range 20-100 μg.mL^-1 , the DL and R2 values were 12 μg.mL^-1 and 0.995 respectively. The procedure was applied successfully to the determination of Procainamide in commercial tablets. The results of this study were favorably compared statistically with those obtained with official methods.展开更多
文摘Existence of positive solution is established for boundary value problems of nonsingular for a class quasi-linear ordinary differential equation on the semi-infinite interval. The results are obtained by using the nonlinear alternative of Leray-Schauder method.
文摘The fundamental problem of an elastic-plastic body subjected to incremental loading is reviewed using a compact internal variable approach based on work carried out at the University of Cape Town in which a quadratic functional was developed for the free energy using Taylor series. Now the departure from that approach is the focus on developing the Liapunov function for the nonlinear differential equations of motion. Static and dynamic equations of motion are derived and shown to meet the requirements of the Liapunov function. As a consequence, time integration parameters that are used in the discrete formulations are easily obtained based on the same requirements. The resulting generalized Newton-Raphson scheme is stable in the sense of Liapunov＇s direct method.
文摘Differential electrolytic potentiometry （DEP） was coupled with Flow injection analysis （FIA） technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indicating system to follow the oxidation of Procainamide with cerium（IV）, and permanganate in an acidic medium. The oxidation reactions of Procainamide with Ce（IV） and/or permanganate are fast enough to permit its determination by flow injection in sulfuric acid media. The univariate method was employed to optimize the variables such as the current density, the flow rate, the oxidant concentration and the concentration of sulfuric acid. The proposed method was linear in the range 20-100 μg.mL^-1 , the DL and R2 values were 12 μg.mL^-1 and 0.995 respectively. The procedure was applied successfully to the determination of Procainamide in commercial tablets. The results of this study were favorably compared statistically with those obtained with official methods.
