Microwave precondition has been highlighted as a promising technology for softening the rock mass prior to rock breakage by machine to reduce drill bit/cutter wear as well as inverse production rate.To numerically exp...Microwave precondition has been highlighted as a promising technology for softening the rock mass prior to rock breakage by machine to reduce drill bit/cutter wear as well as inverse production rate.To numerically explore the effect of numerical parameters on rock static strength simulation,and determine the numerical mechanical parameters of microwave-treated basalts for future drilling and cutting simulations,numerical models of uniaxial compression strength(UCS)and Brazilian tensile strength(BTS)were established with the coupling of smoothed particle hydrodynamics and finite element method(SPH-FEM).To eliminate the large rock strength errors caused by microwave-induced damage,the cohesion and internal friction angle of microwave-treated basalt specimens with the same microwave treatment parameters were calibrated based on a linear Mohr-Coulomb theory.Based on parametric sensitivity analysis of SPH simulation of UCS and BTS,experimental UCS and BTS values were simultaneously captured according to the same set of calibrated cohesion and internal friction angle data,and the UCS modeling results are in good agreement with experimental tests.Furthermore,the effect of microwave irradiation parameter on the basalt mechanical behaviors was evaluated.展开更多
Microwave irradiation was employed to assist the synthesis of poly（amino-quinone） （PAQ） from p-benzoquinone and diamines in solid state. The effects of power, time, and pattern （continuously or intermittently） o...Microwave irradiation was employed to assist the synthesis of poly（amino-quinone） （PAQ） from p-benzoquinone and diamines in solid state. The effects of power, time, and pattern （continuously or intermittently） of microwave irradiation on yield and intrinsic viscosity of PAQs were studied. It is shown that the continuous microwave irradiation at a high power leads to rapid increase of yield and a sudden halt in polymerization afterwards, due to the subsequent loss of volatile reactants at a high reaction temperature. Alternatively, the high-power microwave irradiation is applicable to raising the yield if used intermittently. In contras4 the low-power microwave irradiation favours the way of continuous exposure to ensure sufficient heat for polymerization. In both cases of high and low power, the yield and intrinsic viscosity can be further promoted by prolonging the exposure time. It is found that under a preliminarily optimized condition of intermittent irradiation at 490 W with six sequences of 5 min irradiation followed by 5 rain interval, the yield and intrinsic viscosity of PAQ from p-benzoquinone and p-phenylene diamine can reach as high as 83% and 41.9 mL/g, respectively.展开更多
Cube-like Ag-Ag2MoO4 composite has been successfully prepared in the presence of PVP （potyvinylpyrrolidone） via a facile microwave-assisted hydrothermal process. Studies of its photocatalytic performance in the deco...Cube-like Ag-Ag2MoO4 composite has been successfully prepared in the presence of PVP （potyvinylpyrrolidone） via a facile microwave-assisted hydrothermal process. Studies of its photocatalytic performance in the decomposition of RhB indicate that the cube-like Ag-Ag2MoO4 composite exhibits good catalytic activities under visible-light irradiation. The face that Ag pro- motes the absorption of visible light may be attributed to the surface plasmon resonance. Further XRD characterization after recycle photocatalytic tests confirms that partial Ag~ ions in Ag2MoO4 have been reduced to metallic Ag. Reaction temperature, reaction time and the amount of PVP have also been studied and found to play crucial roles in the formation of the cube-like microstructures.展开更多
基金the National Natural Science Foundation of China (No. 51774323)the Natural Science Foundation of Hunan Province, China (No. 2020JJ4704)+1 种基金the Fundamental Research Funds for the Central Universities of Central South University, China (No. 2018zzts216) the financial support from the China Scholarship Councilthe support of the high-performance computer from Compute Canada
文摘Microwave precondition has been highlighted as a promising technology for softening the rock mass prior to rock breakage by machine to reduce drill bit/cutter wear as well as inverse production rate.To numerically explore the effect of numerical parameters on rock static strength simulation,and determine the numerical mechanical parameters of microwave-treated basalts for future drilling and cutting simulations,numerical models of uniaxial compression strength(UCS)and Brazilian tensile strength(BTS)were established with the coupling of smoothed particle hydrodynamics and finite element method(SPH-FEM).To eliminate the large rock strength errors caused by microwave-induced damage,the cohesion and internal friction angle of microwave-treated basalt specimens with the same microwave treatment parameters were calibrated based on a linear Mohr-Coulomb theory.Based on parametric sensitivity analysis of SPH simulation of UCS and BTS,experimental UCS and BTS values were simultaneously captured according to the same set of calibrated cohesion and internal friction angle data,and the UCS modeling results are in good agreement with experimental tests.Furthermore,the effect of microwave irradiation parameter on the basalt mechanical behaviors was evaluated.
基金Project(50804055) supported by the National Natural Science Foundation of China
文摘Microwave irradiation was employed to assist the synthesis of poly（amino-quinone） （PAQ） from p-benzoquinone and diamines in solid state. The effects of power, time, and pattern （continuously or intermittently） of microwave irradiation on yield and intrinsic viscosity of PAQs were studied. It is shown that the continuous microwave irradiation at a high power leads to rapid increase of yield and a sudden halt in polymerization afterwards, due to the subsequent loss of volatile reactants at a high reaction temperature. Alternatively, the high-power microwave irradiation is applicable to raising the yield if used intermittently. In contras4 the low-power microwave irradiation favours the way of continuous exposure to ensure sufficient heat for polymerization. In both cases of high and low power, the yield and intrinsic viscosity can be further promoted by prolonging the exposure time. It is found that under a preliminarily optimized condition of intermittent irradiation at 490 W with six sequences of 5 min irradiation followed by 5 rain interval, the yield and intrinsic viscosity of PAQ from p-benzoquinone and p-phenylene diamine can reach as high as 83% and 41.9 mL/g, respectively.
基金supported by the National Basic Research Program of China (2013CB922102)the National Natural Science Foundation of China(21021062)the US National Science Foundation (CHE-1012173)
文摘Cube-like Ag-Ag2MoO4 composite has been successfully prepared in the presence of PVP （potyvinylpyrrolidone） via a facile microwave-assisted hydrothermal process. Studies of its photocatalytic performance in the decomposition of RhB indicate that the cube-like Ag-Ag2MoO4 composite exhibits good catalytic activities under visible-light irradiation. The face that Ag pro- motes the absorption of visible light may be attributed to the surface plasmon resonance. Further XRD characterization after recycle photocatalytic tests confirms that partial Ag~ ions in Ag2MoO4 have been reduced to metallic Ag. Reaction temperature, reaction time and the amount of PVP have also been studied and found to play crucial roles in the formation of the cube-like microstructures.
