A one-dimensional coupled pelagic-benthic box model for the Yellow Sea Cold Water Mass (YSCWM) is developed. The model is divided into three boxes vertically according to the depths of thermocline and euphotic layer. ...A one-dimensional coupled pelagic-benthic box model for the Yellow Sea Cold Water Mass (YSCWM) is developed. The model is divided into three boxes vertically according to the depths of thermocline and euphotic layer. It simulates well the oligotrophic shelf ecosystem of the YSCWM considering effects of nu- trients deposition and microbial loop. Main features of vertical structure of various variables in ecosystem of the YSCWM were captured and seasonal variability of the ecosystem was well reconstructed. Calculation shows that the contribution of microbial loop to the zooplankton can reach up to 60%. Besides, input of inorganic nutrients from atmospheric deposition is an important mechanism of production in upper layer of the YSCWM when stratified.展开更多
Multimodal cancer synergistic therapy exhibited remarkable advantages over monotherapy in producing an improved therapeutic efficacy. In this work, Janus-type γ-Fe2 O3/SiO2 nanoparticles(JFSNs) are conjugated with gl...Multimodal cancer synergistic therapy exhibited remarkable advantages over monotherapy in producing an improved therapeutic efficacy. In this work, Janus-type γ-Fe2 O3/SiO2 nanoparticles(JFSNs) are conjugated with glucose oxidase(GOx) for synergistic cancer starvation/chemodynamic therapy. The γ-Fe2O3 hemisphere of JFSNs can perform photoacoustic/T2 magnetic resonance dual-modal imaging of tumors.GOx on the surface of JFSNs catalyzes the decomposition of glucose and produces H2O2 for cancer starvation therapy. Subsequently, the γ-Fe2O3 hemisphere catalyzes the disproportionation of H2O2 to generate highly reactive hydroxyl radicals in an acidic tumor microenvironment. The close distance between GOx and JFSNs ensures adequate contact between the γ-Fe2O3 hemisphere and its substrate H2O2, thus enhancing the catalytic efficiency. This synergy of glucose depletion, biotoxic H2O2 and hydroxyl radicals significantly suppresses 4 T1 mammary tumor growth with minimal adverse effects.展开更多
An extremely effortless method was applied for successful synthesis of mesoporous carbonaceous materials(MCMs) using well-ordered mesoporous silica as template. Various characterizations(scanning electron microscopy(S...An extremely effortless method was applied for successful synthesis of mesoporous carbonaceous materials(MCMs) using well-ordered mesoporous silica as template. Various characterizations(scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FT-IR), Raman, X-ray photoelectron spectroscopy(XPS), Brunner-Emmet-Teller(BET) and Zeta potential) confirmed that MCMs had large surface area, uniform pore size distribution, and abundant oxygen-containing functional groups. The batch techniques were employed to study U(VI) adsorption on MCMs under a wide range of experiment conditions. The adsorption kinetics of U(VI) onto MCMs were well-fitted by pseudo-second-order kinetic model, indicating a chemisorption process. The excellent adsorption capacity of MCMs calculated from the Langmuir model was 293.95 mg g^(-1) at pH 4.0. The FT-IR and XPS analyses further evidenced that the binding of U(VI) onto MCMs was ascribed to the plentiful adsorption sites(–OH and –COOH groups) in the internal mesoporous structure, which could efficiently trap guest U(VI) ions. The results presented herein revealed that MCMs were ideal adsorbents in the efficient elimination of uranium or other lanthanides/actinides from aqueous solutions, which would play an important role in environmental pollution management application.展开更多
In the real world, the population systems are often subject to white noises and a system with such stochastic perturbations tends to be suitably modeled by stochastic differential equations. This paper is concerned wi...In the real world, the population systems are often subject to white noises and a system with such stochastic perturbations tends to be suitably modeled by stochastic differential equations. This paper is concerned with the dynamic behaviors of a delay stochastic competitive system. We first obtain the global existence of a unique positive solution of system. Later, we show that the solution of system will be stochastically ultimate boundedness. However, large noises may make the system extinct exponentially with probability one. Also, sufficient conditions for the global attractivity of system are established. FinMly, illustrated examples are given to show the effectiveness of the proposed criteria.展开更多
基金This work is supported by Major State Basic Research DevelopmentProgram of China (973 Program, G19990437), China International Co-operation Program (No. 2001CB711004) and NSFC (No. 40476045)
文摘A one-dimensional coupled pelagic-benthic box model for the Yellow Sea Cold Water Mass (YSCWM) is developed. The model is divided into three boxes vertically according to the depths of thermocline and euphotic layer. It simulates well the oligotrophic shelf ecosystem of the YSCWM considering effects of nu- trients deposition and microbial loop. Main features of vertical structure of various variables in ecosystem of the YSCWM were captured and seasonal variability of the ecosystem was well reconstructed. Calculation shows that the contribution of microbial loop to the zooplankton can reach up to 60%. Besides, input of inorganic nutrients from atmospheric deposition is an important mechanism of production in upper layer of the YSCWM when stratified.
基金This work was supported by the National Key Research and Development Program of China(2018YFA0704003)the Basic Research Program of Shenzhen(JCYJ20180305163452667,JCYJ20180507182413022,and JCYJ20170412111100742)+3 种基金the National Natural Science Foundation of China(81903564,31771036,51703132,and 21874119)the Guangdong Provincial Natural Science Foundation of Major Basic Research and Cultivation Project(2018B030308003)the Fok Ying-Tong Education Foundation for Young Teachers in the Higher Education Institutions of China(161032)We thank Instrumental Analysis Center of Shenzhen University(Lihu Campus).
文摘Multimodal cancer synergistic therapy exhibited remarkable advantages over monotherapy in producing an improved therapeutic efficacy. In this work, Janus-type γ-Fe2 O3/SiO2 nanoparticles(JFSNs) are conjugated with glucose oxidase(GOx) for synergistic cancer starvation/chemodynamic therapy. The γ-Fe2O3 hemisphere of JFSNs can perform photoacoustic/T2 magnetic resonance dual-modal imaging of tumors.GOx on the surface of JFSNs catalyzes the decomposition of glucose and produces H2O2 for cancer starvation therapy. Subsequently, the γ-Fe2O3 hemisphere catalyzes the disproportionation of H2O2 to generate highly reactive hydroxyl radicals in an acidic tumor microenvironment. The close distance between GOx and JFSNs ensures adequate contact between the γ-Fe2O3 hemisphere and its substrate H2O2, thus enhancing the catalytic efficiency. This synergy of glucose depletion, biotoxic H2O2 and hydroxyl radicals significantly suppresses 4 T1 mammary tumor growth with minimal adverse effects.
基金supported by the National Natural Science Foundation of China(91326202,21577032)the Fundamental Research Funds for the Central Universities(JB2015001,JB2017057)the Jiangsu Provincial Key Laboratory of Radiation Medicine and Protection and the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘An extremely effortless method was applied for successful synthesis of mesoporous carbonaceous materials(MCMs) using well-ordered mesoporous silica as template. Various characterizations(scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FT-IR), Raman, X-ray photoelectron spectroscopy(XPS), Brunner-Emmet-Teller(BET) and Zeta potential) confirmed that MCMs had large surface area, uniform pore size distribution, and abundant oxygen-containing functional groups. The batch techniques were employed to study U(VI) adsorption on MCMs under a wide range of experiment conditions. The adsorption kinetics of U(VI) onto MCMs were well-fitted by pseudo-second-order kinetic model, indicating a chemisorption process. The excellent adsorption capacity of MCMs calculated from the Langmuir model was 293.95 mg g^(-1) at pH 4.0. The FT-IR and XPS analyses further evidenced that the binding of U(VI) onto MCMs was ascribed to the plentiful adsorption sites(–OH and –COOH groups) in the internal mesoporous structure, which could efficiently trap guest U(VI) ions. The results presented herein revealed that MCMs were ideal adsorbents in the efficient elimination of uranium or other lanthanides/actinides from aqueous solutions, which would play an important role in environmental pollution management application.
基金Acknowledgments The authors thank the referees for their reports and many valuable comments and suggestions that greatly improved the presentation of this paper. The work is supported by the National Natural Science Foundation of China （No. 11261017）, the Key Laboratory of Biological Resources Protection and Utilization of Hubei Province （No. PKLHB1323） and the Key Project of Chinese Ministry of Education （No. 212111）.
文摘In the real world, the population systems are often subject to white noises and a system with such stochastic perturbations tends to be suitably modeled by stochastic differential equations. This paper is concerned with the dynamic behaviors of a delay stochastic competitive system. We first obtain the global existence of a unique positive solution of system. Later, we show that the solution of system will be stochastically ultimate boundedness. However, large noises may make the system extinct exponentially with probability one. Also, sufficient conditions for the global attractivity of system are established. FinMly, illustrated examples are given to show the effectiveness of the proposed criteria.
