以Bi(NO3)3.5H2O、NaVO3和Cu(NO3)2.3H2O为原料并以十六烷基三甲基溴化铵(CTAB)为结构导向剂通过水热法制备了Cu/BiVO4微米片晶体。采用XRD、XPS、SEM、HRTEM、UV-Vis、比表面积测试等对产品进行了表征。结果表明,2.0 g CTAB辅助水热法...以Bi(NO3)3.5H2O、NaVO3和Cu(NO3)2.3H2O为原料并以十六烷基三甲基溴化铵(CTAB)为结构导向剂通过水热法制备了Cu/BiVO4微米片晶体。采用XRD、XPS、SEM、HRTEM、UV-Vis、比表面积测试等对产品进行了表征。结果表明,2.0 g CTAB辅助水热法能够合成结晶度高且形貌规整的单斜白钨矿Cu/BiVO4微米片晶体,其长度为1.0～2.0μm,宽度为0.5～2.0μm,厚度在200～300 nm内。相比BiVO4颗粒,片状Cu/BiVO4样品的紫外–可见光吸收边发生了稍许红移,具有较小的能带隙。光催化结果说明,5.0wt%Cu/BiVO4微米片表现出最好的光催化活性,其速度常数k为5.89×10–2/min,可见光照射10 mg/L亚甲基蓝溶液60 min的光解率达100%。展开更多
FeSiAl 不规则颗粒在酒精溶剂中球磨，制备得到直径为10μm左右厚度为1μm左右的FeSiAl微米片，然后用硅烷偶联剂对微米片表面进行包裹处理。用电子显微镜和 X 射线光谱仪对包裹和未包裹样品做形貌观测和元素分析，并将样品制备成45%（...FeSiAl 不规则颗粒在酒精溶剂中球磨，制备得到直径为10μm左右厚度为1μm左右的FeSiAl微米片，然后用硅烷偶联剂对微米片表面进行包裹处理。用电子显微镜和 X 射线光谱仪对包裹和未包裹样品做形貌观测和元素分析，并将样品制备成45%（体积分数）的石蜡复合材料，通过矢量网络分析仪测试其在0.1-18 GHz范围内的电磁参数，发现包裹和未包裹样品的复数磁导率曲线基本重合，但包裹后样品的复数介电常数有很明显的下降。微波传输理论计算表明，包裹后样品在L-S波段具有更优越吸波性能。展开更多
Submicron scale temperature sensors are crucial for a range of applications,particularly in micro and na-noscale environments.One promising solution involves the use of active whispering gallery mode(WGM)microresonato...Submicron scale temperature sensors are crucial for a range of applications,particularly in micro and na-noscale environments.One promising solution involves the use of active whispering gallery mode(WGM)microresonators.These resonators can be remotely excited and read out using free-space structures,simplifying the process of sensing.In this study,we present a submicron-scale temperature sensor with a remarkable sensitivity up to 185 pm/℃based on a trian-gular MAPbI3 nanoplatelet(NPL)laser.Notably,as temperature changes,the peak wavelength of the laser line shifts lin-early.This unique characteristic allows for precise temperature sensing by tracking the peak wavelength of the NPL laser.The optical modes are confined within the perovskite NPL,which measures just 85 nm in height,due to total internal reflec-tion.Our NPL laser boasts several key features,including a high Q of~2610 and a low laser threshold of about 19.8μJ·cm^(−2).The combination of exceptional sensitivity and ultra-small size makes our WGM device an ideal candidate for integration into systems that demand compact temperature sensors.This advancement paves the way for significant prog-ress in the development of ultrasmall temperature sensors,opening new possibilities across various fields.展开更多
Low-dimensional Bi2Fe4O9 nanosheets and microrods have been selectively prepared by a solvothermal method, from which the growth of the Bi2Fe4O9 crystals can be controlled by the variation of reaction conditions. Stru...Low-dimensional Bi2Fe4O9 nanosheets and microrods have been selectively prepared by a solvothermal method, from which the growth of the Bi2Fe4O9 crystals can be controlled by the variation of reaction conditions. Structure determination showed that the nanosheets are mainly exposed by {001} facets while the microrods are exposed by {110} facets. Ab- sorption spectra revealed that there are two bandgaps observed for both nanosheets （at 1.9 and 1.55 eV） and microrods （1.7 and 1.45 eV）, and they both would be available for the sunlight photocatalysis e ciently due to the intensive absorption ability in a wide region. Photocatalytic investigation demonstrated that the overall photocatalytic performance of the microrods is prior to that of the nanosheets due to the variation of bandgaps and exposed facets. The present report provides a useful alternative strategy for the controlling growth of nanostructures and/or microcrystals besides the present demonstration of the Bi2Fe4O9 crystals with diflerent bandgaps and facets that would be able to tune the corresponding photocatalytic ability selectively.展开更多
文摘FeSiAl 不规则颗粒在酒精溶剂中球磨，制备得到直径为10μm左右厚度为1μm左右的FeSiAl微米片，然后用硅烷偶联剂对微米片表面进行包裹处理。用电子显微镜和 X 射线光谱仪对包裹和未包裹样品做形貌观测和元素分析，并将样品制备成45%（体积分数）的石蜡复合材料，通过矢量网络分析仪测试其在0.1-18 GHz范围内的电磁参数，发现包裹和未包裹样品的复数磁导率曲线基本重合，但包裹后样品的复数介电常数有很明显的下降。微波传输理论计算表明，包裹后样品在L-S波段具有更优越吸波性能。
文摘Submicron scale temperature sensors are crucial for a range of applications,particularly in micro and na-noscale environments.One promising solution involves the use of active whispering gallery mode(WGM)microresonators.These resonators can be remotely excited and read out using free-space structures,simplifying the process of sensing.In this study,we present a submicron-scale temperature sensor with a remarkable sensitivity up to 185 pm/℃based on a trian-gular MAPbI3 nanoplatelet(NPL)laser.Notably,as temperature changes,the peak wavelength of the laser line shifts lin-early.This unique characteristic allows for precise temperature sensing by tracking the peak wavelength of the NPL laser.The optical modes are confined within the perovskite NPL,which measures just 85 nm in height,due to total internal reflec-tion.Our NPL laser boasts several key features,including a high Q of~2610 and a low laser threshold of about 19.8μJ·cm^(−2).The combination of exceptional sensitivity and ultra-small size makes our WGM device an ideal candidate for integration into systems that demand compact temperature sensors.This advancement paves the way for significant prog-ress in the development of ultrasmall temperature sensors,opening new possibilities across various fields.
基金This work was supported by the National Natu-ral Science Foundation of China （No.21571166 and No.51271173） and the National Basic Research Pro- gram of China （No.2012CB922001）.
文摘Low-dimensional Bi2Fe4O9 nanosheets and microrods have been selectively prepared by a solvothermal method, from which the growth of the Bi2Fe4O9 crystals can be controlled by the variation of reaction conditions. Structure determination showed that the nanosheets are mainly exposed by {001} facets while the microrods are exposed by {110} facets. Ab- sorption spectra revealed that there are two bandgaps observed for both nanosheets （at 1.9 and 1.55 eV） and microrods （1.7 and 1.45 eV）, and they both would be available for the sunlight photocatalysis e ciently due to the intensive absorption ability in a wide region. Photocatalytic investigation demonstrated that the overall photocatalytic performance of the microrods is prior to that of the nanosheets due to the variation of bandgaps and exposed facets. The present report provides a useful alternative strategy for the controlling growth of nanostructures and/or microcrystals besides the present demonstration of the Bi2Fe4O9 crystals with diflerent bandgaps and facets that would be able to tune the corresponding photocatalytic ability selectively.
