采用固相法制备NaNbO_(3)微米粉末,研究其压电催化特性。采用XRD检测Na Nb O_(3)微米粉末的相结构;利用PFM分析Na NbO_(3)粉末的压电响应;使用超声的方式施加应力,测试NaNbO3_粉末降解染料罗丹明B的压电催化能力。结果表明:NaNbO_(3)微...采用固相法制备NaNbO_(3)微米粉末,研究其压电催化特性。采用XRD检测Na Nb O_(3)微米粉末的相结构;利用PFM分析Na NbO_(3)粉末的压电响应;使用超声的方式施加应力,测试NaNbO3_粉末降解染料罗丹明B的压电催化能力。结果表明:NaNbO_(3)微米粉末的空间群结构为P2_(1)ma,属于铁电相,具有多畴结构和明显的极化反转行为;在200 W超声功率和40 kHz的超声频率下,随着时间的延长,罗丹明B溶液浓度逐渐降低,在120 min时降解度高达94.8%。展开更多
In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applicati...In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applications,the microwave sintering process and densification mechanism of Mo nanopowder were studied.In this experiment,Mo nanopowder and micropowder were used for conventional sintering and microwave sintering at different sintering temperatures and sintering time,respectively.The results showed that with the increase in the sintering temperature,the increase rates of the relative density and hardness increased rapidly at first and then slowed down.The relative density rapidly reached 95%,followed by a small change.Mo nanopowder with a relative density of 98.03% and average grain size of 3.6 μm was prepared by microwave sintering at 1873 K for30 min.According to the analysis of the sintering kinetics,its densification is attributed to the combination of volumetric diffusion and grain boundary diffusion mechanisms.The calculated sintering activation energy of Mo nanopowder was 203.65 kJ/mol,which was considerably lower than that in the conventional sintering,suggesting that the microwave sintering was beneficial to the enhancement in the atom diffusion and densification for the powder.The results confirm that the microwave sintering is a promising method to economically prepare molybdenum with high properties.展开更多
5.0 vol.% graphene nanoplatelets(GNPs) and aluminum powders were mixed to prepare GNPs/Al composites via high-energy ball milling(HEBM). The mixed powders were subjected to spark plasma sintering(SPS) and subsequent h...5.0 vol.% graphene nanoplatelets(GNPs) and aluminum powders were mixed to prepare GNPs/Al composites via high-energy ball milling(HEBM). The mixed powders were subjected to spark plasma sintering(SPS) and subsequent hot extrusion. The microstructure and mechanical properties of extruded composites were investigated by X-ray photoelectron spectroscopy(XPS), transmission electron microscopy(TEM) and tensile tests. In the extruded composites, 5.0 vol.% GNPs were dispersed homogeneously and no serious GNP-Al interfacial reaction occurred. As a result, the yield strength and ultimate tensile strength of the extruded GNPs/Al composites reached 462 and 479 MPa, which were 62% and 60% higher than those of the extruded Al matrix, respectively. The enhanced mechanical properties were attributed to the effective load transfer capacity of dispersed GNPs. This demonstrated that it may be promising to introduce dispersed high-content GNPs via HEBM, SPS and hot extrusion techniques and GNP-Al interfacial reaction can be controlled.展开更多
The explosive characteristics of aluminum powder have great significance in preventing and controlling aluminum-dust explosion accidents, especially the nano-aluminum powder. The explosion characteristics of 100 nm an...The explosive characteristics of aluminum powder have great significance in preventing and controlling aluminum-dust explosion accidents, especially the nano-aluminum powder. The explosion characteristics of 100 nm and 75 μm aluminum powders were investigated by using a 20 L spherical explosion cavity and a horizontal pipe whose cross-section area is 80 mm × 80 mm and length is 8 m. The results show that the maximum explosion pressure and its rising rate of 100 nm aluminum powder gradually increase with increasing concentration of aluminum-powder at the beginning. When aluminum-powder concentration is I kg/m3, the maximum explosion pressure reaches its maximum, and then gradually decreases. While when the concentration is 1.25 kg/m3, the maximum rate of pressure rise obtains its maximum, and then decreases. After 100 nm aluminum powder is exploded in pipes, the peak overpressure of blast wave first decreases and then increases to the maximum at a distance of 298 cm from the ignition source, and then gradually decreases. The most violent concentration is about 0.4 kg/m3 which is lower than 0.8 kg/m3 of 75 μm aluminum powder, so 100 nm aluminum powders are more easily exploded. The change laws of maximum explosion pressure, maximum rate of pressure rise and blast-wave peak overpressure of 100 nm aluminum powders with concentration are similar to those of 75 ktm aluminum powders, but these values are much higher than 75 Bm aluminum powders under the same concentration, so the aluminum-powders explosion of 100 nm will produce more harms. In the process of production, storage and transportation of aluminum powder, some relevant preventive measures can be taken to reduce the loss caused by aluminum-dust explosion according to nano-aluminum dust.展开更多
基金Project(2017YFB0305601) supported by the National Key R&D Program of ChinaProjects(51874368,51274246) supported by the National Natural Science Foundation of China
文摘In order to prepare high-performance Mo with fine and homogeneous microstructure to meet the demand of high-technology applications such as metallurgical,mechanical,national defense,aerospace and electronics applications,the microwave sintering process and densification mechanism of Mo nanopowder were studied.In this experiment,Mo nanopowder and micropowder were used for conventional sintering and microwave sintering at different sintering temperatures and sintering time,respectively.The results showed that with the increase in the sintering temperature,the increase rates of the relative density and hardness increased rapidly at first and then slowed down.The relative density rapidly reached 95%,followed by a small change.Mo nanopowder with a relative density of 98.03% and average grain size of 3.6 μm was prepared by microwave sintering at 1873 K for30 min.According to the analysis of the sintering kinetics,its densification is attributed to the combination of volumetric diffusion and grain boundary diffusion mechanisms.The calculated sintering activation energy of Mo nanopowder was 203.65 kJ/mol,which was considerably lower than that in the conventional sintering,suggesting that the microwave sintering was beneficial to the enhancement in the atom diffusion and densification for the powder.The results confirm that the microwave sintering is a promising method to economically prepare molybdenum with high properties.
基金financial supports from National Key R&D Program of China (2017YFB0703103)Key Area R&D Program of Guangdong Province,China (2019B010942001)。
文摘5.0 vol.% graphene nanoplatelets(GNPs) and aluminum powders were mixed to prepare GNPs/Al composites via high-energy ball milling(HEBM). The mixed powders were subjected to spark plasma sintering(SPS) and subsequent hot extrusion. The microstructure and mechanical properties of extruded composites were investigated by X-ray photoelectron spectroscopy(XPS), transmission electron microscopy(TEM) and tensile tests. In the extruded composites, 5.0 vol.% GNPs were dispersed homogeneously and no serious GNP-Al interfacial reaction occurred. As a result, the yield strength and ultimate tensile strength of the extruded GNPs/Al composites reached 462 and 479 MPa, which were 62% and 60% higher than those of the extruded Al matrix, respectively. The enhanced mechanical properties were attributed to the effective load transfer capacity of dispersed GNPs. This demonstrated that it may be promising to introduce dispersed high-content GNPs via HEBM, SPS and hot extrusion techniques and GNP-Al interfacial reaction can be controlled.
基金supported by the Major State Basic Research Development Program of China (No. 2011CB201205)the Open Fund Program of the State Key Laboratory of Explosion Science and Technology (No. KFJJ10-19M)
文摘The explosive characteristics of aluminum powder have great significance in preventing and controlling aluminum-dust explosion accidents, especially the nano-aluminum powder. The explosion characteristics of 100 nm and 75 μm aluminum powders were investigated by using a 20 L spherical explosion cavity and a horizontal pipe whose cross-section area is 80 mm × 80 mm and length is 8 m. The results show that the maximum explosion pressure and its rising rate of 100 nm aluminum powder gradually increase with increasing concentration of aluminum-powder at the beginning. When aluminum-powder concentration is I kg/m3, the maximum explosion pressure reaches its maximum, and then gradually decreases. While when the concentration is 1.25 kg/m3, the maximum rate of pressure rise obtains its maximum, and then decreases. After 100 nm aluminum powder is exploded in pipes, the peak overpressure of blast wave first decreases and then increases to the maximum at a distance of 298 cm from the ignition source, and then gradually decreases. The most violent concentration is about 0.4 kg/m3 which is lower than 0.8 kg/m3 of 75 μm aluminum powder, so 100 nm aluminum powders are more easily exploded. The change laws of maximum explosion pressure, maximum rate of pressure rise and blast-wave peak overpressure of 100 nm aluminum powders with concentration are similar to those of 75 ktm aluminum powders, but these values are much higher than 75 Bm aluminum powders under the same concentration, so the aluminum-powders explosion of 100 nm will produce more harms. In the process of production, storage and transportation of aluminum powder, some relevant preventive measures can be taken to reduce the loss caused by aluminum-dust explosion according to nano-aluminum dust.
