Mean-square bond length, root-mean-square end-to-end distance and gyration radius in diblock copolymer films have been studied by dissipative particle dynamics simulations. Results show evident linear trends of any pr...Mean-square bond length, root-mean-square end-to-end distance and gyration radius in diblock copolymer films have been studied by dissipative particle dynamics simulations. Results show evident linear trends of any property separately with the thickness of film, the interaction between particles of different types, the repulsion between particle and boundary, except for the dependence of the variations of mean-square bond length on the thickness of film, which exhibits as a wave trend. What＇s more, the varying trends of mean-square bond length and root-mean-square end-to-end distance can correspond to each other. The density distribution of either component in diblock copolymer film can be controlled and adjusted effectively through its interaction with boundary.展开更多
Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent sus...Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent susceptibility （Xfd） showed the absence of superparamagnetic （SP） grains in the samples. The IRM20mT （isothermal remanent magnetization at 20 mT） being linearly proportional to SIRM （saturation isothermal remanent magnetization） （R^2=0.901）, suggested that ferrimagnetic minerals were responsible for the magnetic properties of automobile emission particulates. The average contents of Cu, Cd, Pb and Fe in automobile emission particulates were 95.83, 22.14, 30.58 and 34727.31 mg/kg, respectively. Significant positive correlations exist between the magnetic parameters and the contents ofPb, Cu and Fe. The magnetic parameters of automobile emission particulates reflecting concentration of magnetic particles increased linearly with increase of Pb and Cu content, showed that the magnetic measurement could be used as a preliminary index for detection of Pb and Cu pollution.展开更多
One dimensional periodic hopping model is useful to understand the motion of microscopic particles in thermal noise environment. In this research, by formal calculation and based on detailed balance, the explicit expr...One dimensional periodic hopping model is useful to understand the motion of microscopic particles in thermal noise environment. In this research, by formal calculation and based on detailed balance, the explicit expressions of the limits of mean velocity and diffusion constant of this model as the number of internal mechanochemical sates tend to infinity are obtained.These results will be helpful to understand the limit of the one dimensional hopping model.At the same time, the work can be used to get more useful results in continuous form from the corresponding ones obtained by discrete models.展开更多
Nanometer Ni0.5Zn0.5Fe2O4 powders with spinel phase were prepared by the hydrothermal method using purified FeSO4 solution from sodium jarosite＇s slag as materials. The results show that the spinel phase of Ni0.5Zn0....Nanometer Ni0.5Zn0.5Fe2O4 powders with spinel phase were prepared by the hydrothermal method using purified FeSO4 solution from sodium jarosite＇s slag as materials. The results show that the spinel phase of Ni0.5Zn0.5Fe2O4 powders begins to form at a relatively low temperature （130 ℃） and a shorter holding time （1 h） when pH=8. The crystallization kinetics equation at 200℃ is ln[-ln（1-x）] =-0.78＋0.951n t. The growth activation energy of Ni0.5Zn0.5Fe2O4 grains is 41.6 kJ/moL in hydrothermal synthesis process. With the increase of sintering temperature, the density and diameter shrinkage of ferrite circulus increase, whereas its pores decrease. The results of magnetic measurements show that saturation magnetic flux density Bs increases and the coercivity Hc decreases with the increase of their sintering temperature. Magnetic parameters of all the investigated samples satisfy the character demand of high Bs, low Br and low Hc of soft magnetic ferrite materials.展开更多
The goal of continuous ambient participate monitoring has been accomplished by the use of terahertz （THz） wave. The fre- quency-dependent spectrum and absorbance of the particulate matter （PM2.5） were measured in ...The goal of continuous ambient participate monitoring has been accomplished by the use of terahertz （THz） wave. The fre- quency-dependent spectrum and absorbance of the particulate matter （PM2.5） were measured in the range of 0-10 THz. The PM2.5 concentration ,o was calculated according to the sampling time and air flow. With the increase of ,o, the THz wave am- plitude gradually decreased and the absorbance A of PM2.5 increased. The relationship between p and A can be described mathematically through p∝ A0.5. Our results demonstrate that the terahertz wave could be a valuable tool to monitor and in- spect the PM2.5 concentration.展开更多
文摘Mean-square bond length, root-mean-square end-to-end distance and gyration radius in diblock copolymer films have been studied by dissipative particle dynamics simulations. Results show evident linear trends of any property separately with the thickness of film, the interaction between particles of different types, the repulsion between particle and boundary, except for the dependence of the variations of mean-square bond length on the thickness of film, which exhibits as a wave trend. What＇s more, the varying trends of mean-square bond length and root-mean-square end-to-end distance can correspond to each other. The density distribution of either component in diblock copolymer film can be controlled and adjusted effectively through its interaction with boundary.
基金Project supported by the National Natural Science Foundation of China (No. 40371056)the Foundation for the Author of NationalExcellent Doctoral Dissertation of China (No. 200149)
文摘Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent susceptibility （Xfd） showed the absence of superparamagnetic （SP） grains in the samples. The IRM20mT （isothermal remanent magnetization at 20 mT） being linearly proportional to SIRM （saturation isothermal remanent magnetization） （R^2=0.901）, suggested that ferrimagnetic minerals were responsible for the magnetic properties of automobile emission particulates. The average contents of Cu, Cd, Pb and Fe in automobile emission particulates were 95.83, 22.14, 30.58 and 34727.31 mg/kg, respectively. Significant positive correlations exist between the magnetic parameters and the contents ofPb, Cu and Fe. The magnetic parameters of automobile emission particulates reflecting concentration of magnetic particles increased linearly with increase of Pb and Cu content, showed that the magnetic measurement could be used as a preliminary index for detection of Pb and Cu pollution.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.10701029） and the Shanghai Key Laboratory for Contemporary Applied Mathematics （No.SGST09DZ2272900）.
文摘One dimensional periodic hopping model is useful to understand the motion of microscopic particles in thermal noise environment. In this research, by formal calculation and based on detailed balance, the explicit expressions of the limits of mean velocity and diffusion constant of this model as the number of internal mechanochemical sates tend to infinity are obtained.These results will be helpful to understand the limit of the one dimensional hopping model.At the same time, the work can be used to get more useful results in continuous form from the corresponding ones obtained by discrete models.
基金Project(50204001) supported by the National Natural Science Foundation of China
文摘Nanometer Ni0.5Zn0.5Fe2O4 powders with spinel phase were prepared by the hydrothermal method using purified FeSO4 solution from sodium jarosite＇s slag as materials. The results show that the spinel phase of Ni0.5Zn0.5Fe2O4 powders begins to form at a relatively low temperature （130 ℃） and a shorter holding time （1 h） when pH=8. The crystallization kinetics equation at 200℃ is ln[-ln（1-x）] =-0.78＋0.951n t. The growth activation energy of Ni0.5Zn0.5Fe2O4 grains is 41.6 kJ/moL in hydrothermal synthesis process. With the increase of sintering temperature, the density and diameter shrinkage of ferrite circulus increase, whereas its pores decrease. The results of magnetic measurements show that saturation magnetic flux density Bs increases and the coercivity Hc decreases with the increase of their sintering temperature. Magnetic parameters of all the investigated samples satisfy the character demand of high Bs, low Br and low Hc of soft magnetic ferrite materials.
基金supported by the Specially Funded Program on National Key Scientific Instruments and Equipment Development(Grant No.2012YQ140005)the National Key Basic Research Program of China(Grant No.2014CB744302)the Beijing National Science Foundation(Grant No.4122064)
文摘The goal of continuous ambient participate monitoring has been accomplished by the use of terahertz （THz） wave. The fre- quency-dependent spectrum and absorbance of the particulate matter （PM2.5） were measured in the range of 0-10 THz. The PM2.5 concentration ,o was calculated according to the sampling time and air flow. With the increase of ,o, the THz wave am- plitude gradually decreased and the absorbance A of PM2.5 increased. The relationship between p and A can be described mathematically through p∝ A0.5. Our results demonstrate that the terahertz wave could be a valuable tool to monitor and in- spect the PM2.5 concentration.
