动态载荷下剪切变形局部化、微结构演化与剪切断裂研究进展

总结和评述了近年来金属与合金变形局部化的形成、微结构演化与剪切断裂方面作者和相关的研究工作成果.材料包括低碳钢,SS304不锈钢,Fe-15%Ni-15%Cr单晶,Al-Li合金,α-Ti和Ti-6Al-4V,Al/SiCp复合材料等.综述内容主要包括:采用改进的Hopkinson扭杆装置,对剪切变形局部化形成、发展和演化过程进行了实验观察与数值模拟;采用"侧剖"与"对接"等定点方法制备电子显微镜薄膜试样,对剪切带内相变与再结晶、非晶转变、旋涡结构等动态变形现象,以及与宏观动态力学行为对应的位错胞的形成、发展和坍塌等微结构特征进行了观测;提出了应变和应变率同时作为剪切带形成的两个必要条件的直接实验证据;在剪切带内发现了α′-马氏体相变现象,以及相变产物与母体之间的晶体学关系;通过位错单滑移或交滑移等微观剪切最后发展成为宏观剪切的机制;对剪切带内再结晶结构的观测和对再结晶动力学本构关系的定量描述;对剪切带特别是"白色"腐蚀带(或相变带)的形成机制的分析和新的解释,指出"白色"是带内亚结构取向趋于一致,其在光学或扫描显微镜下很难辨认这些亚结构的取向差所致,并非表明剪切带内一定发生了相变;通过截断实验和实时跟踪观测发现,剪切带内微裂纹的萌生与聚合是材料承载能力骤然下降并导致最后断裂的主控因素.此外,本文对近年来在准静态和循环加载下材料的局部化形变与剪切断裂的实验结果予以简要评述,指出其微观机制与动态载荷下的截然不同,是由位错的平面滑移所控制的,与热效应无关的等温变形.

Performance of grouts for post-tensioned prestressed structures

New high performance grouts with high volume stability and good fluidity were prepared with Portland cement and a multifunctional admixture (MFA). The theological characteristics and mechanical performance of the grouts were investigated. The addition of MFA effectively improves the pseudo-plasticity of the grout. The Ma cone flow time decreases obviously, and the bleeding rate tends to be zero. The deformation behaviors of fresh mixture and hardened grout are systematically studied. Mercury injection method (MIP), scanning electron microscopy (SEM) and X-ray diffractory analysis experiments are used to analyze the microstructure evolution of the grouts, which manifests that the co-action of the early bubble reaction and the latter ettringite crystallization ensure the volume stability throughout the whole hydration process and result in refined pore structure of the grout.

Failure mechanism of as-cast Mg-6Zn-2Er alloy during tensile test at room temperature

Tensile test of the as-cast Mg-6Zn-2Er alloy was conducted at room temperature. The results indicate that the alloy is inclined to failure when the strain reaches 5.6%. The coarse secondary phases are responsible for the failure, especially for the Mg3Zn3Er2 phase （W-phase）. It is indicated that the existence of the W-phase activates the stress concentrations due to the incapacity of W-phase for the load transfer, which results in the void at the inner of the W-phase. In comparison, the interface between the matrix and the secondary phase is stable. In conclusion, the characters of the secondary phases with respect to size, distribution, morphology and type, play an important role in the plastic deformation behavior of the alloy.

Numerical and physical simulation of new SPD method combining extrusion and equal channel angular pressing for AZ31 magnesium alloy

A new serve plastic deformation(SPD) including initial forward extrusion and subsequent shearing process(ES) was proposed.The influence of the ES forming on the grain refinement of the microstructure was researched.The components of ES forming die were manufactured and installed to Gleeble1500D thermo-mechanical simulator.The microstructure observations were carried out on the as-extruded rods(as-received) and ES formed rods.From the simulation results,ES forming can increase the cumulative strain enormously and the volume fraction of dynamic recrystallization.From the physical modeling results,the microstructures can be refined.

Physical simulation of hot deformation of TiAl based alloy

In order to establish a model between the grain size and the process parameters, the hot deformation behaviors of Ti 49.5Al alloy was investigated by isothermal compressive tests at temperatures ranging from 800 to 1?100 ℃ with strain rates of 10 -3 10 -1 s -1 . Within this range, the deformation behavior obeys the power law relationship, which can be described using the kinetic rate equation. The stress exponent, n , has a value of about 5.0, and the apparent activation energy is about 320 J/mol, which fits well with the value estimated in previous investigations. The results show that, the dependence of flow stress on the recrystallized grain size can be expressed by the equation: σ=K 1d rex -0 56 . The relationship between the deformed microstructure and the process control parameter can be expressed by the formula: lg d rex =-0 281?1gZ +3 908?1.

Microstructure evolution of 7050 aluminum alloy during hot deformation

Hot compression of 7050 aluminum alloy was performed on Gleeble 1500D thermo-mechanical simulator at 350 ℃ and 450 ℃ with a constant strain rate of 0.1 s-1 to different nominal strains of 0.1, 0.3 and 0.7. Microstructures of 7050 alloy under various compression conditions were observed by TEM to investigate the microstructure evolution process of the alloy deformed at various temperatures. The microstructure evolves from dislocation tangles to cell structure and subgrain structure when being deformed at 350 ℃, of which dynamic recovery is the softening mechanism. However, continuous dynamic recrystallization (DRX) occurs during hot deformation at 450 ℃, in which the main nucleation mechanisms of DRX are subgrain growth and subgrain coalescence rather than particle-simulated nucleation (PSN).

Effect of heat treatment on microstructures and mechanical properties of extruded-rolled AZ31 Mg alloys

The deformation behaviors of extruded-rolled(ER)AZ31 Mg alloys with different rolling reduction and heat treatment were investigated.The results show that the accumulation of rolling reduction increases the density of twins,and refines the grain structures,which are in accordance with the enhanced strength and degraded plasticity.Tensile strength and plasticity of the alloy depend mainly on rolling reduction,while heat treatment temperature plays a more important role than heat treatment time at the same rolling reduction.With the increase of rolling reduction,the plasticity becomes more sensitive than strength on heat treatment. Recrystallization of extruded-rolled alloys will occur easily with deformation increasing,which is induced by addition of distortion energy.

A unified constitutive model for multiphase precipitation and multi-stage creep ageing behavior of Al−Li−S4 alloy

A unified constitutive model is presented to predict the recently observed“multi-stage”creep behavior of Al−Li−S4 alloy.The corresponding microstructural variables related to the yield strength and creep deformation of the alloy during the creep ageing process,including dislocations and multiple precipitates,have been characterized in detail by X-ray diffraction(XRD)and transmission electron microscopy(TEM).For the yield strength,the model considers the multiphase strengthening behavior of the alloy based on strengthening mechanisms,which includes shearable T1 precipitate strengthening,non-shearable T1 precipitate strengthening andθ′precipitate strengthening.Based on creep deformation mechanism,the“multi-stage”creep behavior of the alloy is predicted by introducing the effects of interacting microstructural variables,including the radius of multiple precipitates,dislocation density and solute concentration,into the creep stress−strain model.It is concluded that the results calculated by the model are in a good agreement with the experimental data,which validates the proposed model.

Microstructure and texture characteristics of ZK60 Mg alloy processed by cyclic extrusion and compression

The microstructure and crystallographic texture characteristics of an extruded ZK60 Mg alloy subjected to cyclic extrusion and compression(CEC) up to 8 passes at 503 K were investigated.The local crystallographic texture,grain size and distribution,and grain boundary character distributions were analyzed using high-resolution electron backscatter diffraction(EBSD).The results indicate that the microstructure is refined significantly by the CEC processing and the distributions of grain size tend to be more uniform with increasing CEC pass number.The fraction of low angle grain boundaries(LAGBs) decreases after CEC deformation,and a high fraction of high angle grain boundaries(HAGBs) is revealed after 8 passes of CEC.Moreover,the initial fiber texture becomes random during CEC processing and develops a new texture.

Characteristics of hot tensile deformation and microstructure evolution of twin-roll cast AZ31B magnesium alloys

High temperature tensile properties and microstructure evolutions of twin-roll-cast AZ31B magnesium alloy were investigated over a strain rate range from 10-3 to 1 s-1.It is suggested that the dominant deformation mechanism in the lower strain rate regimes is dislocation creep controlled by grain boundary diffusion at lower temperature and by lattice diffusion at higher temperatures,respectively.Furthermore,dislocation glide and twinning are dominant deformation mechanisms at higher strain-rate.The processing map,the effective diffusion coefficient and activation energy map of the alloy were established.The relations of microstructure evolutions to the transition temperature of dominant diffusion process,the activation energy platform and the occurrence of the full dynamic recrystallization with the maximum peak efficiency were analyzed.It is revealed that the optimum conditions for thermo-mechanical processing of the alloy are at a temperature range from 553 to 593 K,and a strain rate range from 7×10-3 to 2×10-3 s-1.

Effect of initial microstructure on superplastic deformation of AZ70 magnesium alloy

The mechanical properties and deformation mechanism of semi-continuously casting and as-extruded AZ70 magnesium alloys in a wide range of grain sizes(from 14 to 103μm)were investigated at 653 K and 1×10-3s -1.It is discovered that with reducing grain size,flow stress is weakened and plasticity is improved and even superplasticity exhibits.SEM and OM were used to clarify the deformation mechanism.It is suggested that dynamic recrystallization(DRX)is the coordination deformation mechanism of grain boundary sliding(GBS)for coarse grain,and cavity and intracrystalline slip are the coordination deformation mechanisms of GBS for fine grain.

Corrosion properties of plastically deformed AZ80 magnesium alloy

AZ80 magnesium alloys were deformed at 200,250,300,350 and 400℃ with different deformation degree of 50%,75%, 83%,87%and 90%,respectively.The corrosion properties of different deformed AZ80 samples were studied by galvanic test in 3.5%NaCl solution.The results show that plastic deformation could improve the corrosion resistance of AZ80 alloy;and the corrosion rate of AZ80 deformed at 250℃ with the deformation degree of 83%was the lowest,which was 33%of the as-cast AZ80 alloy.Further studies of the microstructure show that the refined grain size and continuously distribution ofβphase around the grain boundary did have a positive effect on the improvement of corrosion resistance of AZ80 alloys.For AZ80 alloys,the smaller the grain size is,the more homogeneous the structure is,and the better the corrosion resistance is.

New Activity of the Tanlu Fault Zone in the South of Huaihe to the Nvshanhu Segment since the Late Quaternary

Taking the Huaihe to the Nvshanhu segment of the Tanlu( Tancheng-Lujiang) fault zone as the main research target to explore whether there has been new activity since the late Quaternary,and based on the interpretation of remote sensing images and repeated surface investigations,we excavated trenches at the sections where the tectonic landform is significant,identified and recorded the deformation patterns of the fault and analyzed the activity behavior. Samples of new activity and deformation were collected and oriented slices were ground based on the samples ' original state to make the micro structural analysis and demonstration. All of the above research shows very clear linear tectonic geomorphology along the fault,three trenches across the fault zone all revealed new deformation traces since late Quaternary. The latest stratum dislocated by the fault is the late Quaternary and Holocene. The main slip mode is stick slip,as represented typically by fault scarps,wedge accumulation,the faults and the filled cracks and so on. In general,it shows the characteristics of brittle high-speed deformation and belongs to the prehistoric earthquake ruins. The above understanding was confirmed partially by microscopic analysis. In addition,the similarities and differences and the possible reasons for the characteristics of the latest activities of the Tancheng-Lujiang fault zone in the north and south of the Huaihe River regions are also discussed in this paper.

浮空器蒙皮力学行为分析及本构建模

为了满足承载及特殊的环境适应性需求,在临近空间服役的浮空器囊体蒙皮由高性能纤维织物、阻氦层、耐候层、粘接层等构成。由于囊体充压水平直接决定了浮空器的承载能力,因此有必要建立能够对蒙皮等效力学行为进行准确预测的本构模型,为浮空器强度和寿命设计奠定基础。考虑到蒙皮由多组分材料构成,通过试验分析了纤维织物和功能层对蒙皮等效力学性能的协同影响。根据试验研究结果,发展了能够描述蒙皮各向异性、非线性力学行为的等效本构模型,预测了蒙皮在正轴和偏轴拉伸过程中其宏观应力、纱线剪切角、试样截面收缩率的变化规律。浮空器蒙皮的本构模拟与试验结果取得了较好的吻合,二者相结合揭示了蒙皮宏观力学响应与微结构变形之间的联系。

Effects of alkaline earth oxides on precipitation behavior of metallic iron under CO atmosphere

In gaseous reduction of iron ore fines, alkaline earth oxides have profound effects on the precipitation behavior of fresh metal- lic iron on the particle surface. In this work, in situ observation was performed to reveal the influence of alkaline earth oxides on the precipitation morphology and micro-structure variation of fresh metallic iron from microscopic level by simulation of the gas-solid reaction condition on the surface of ore particles. Experimental results indicate that doping MgO in the particle surface can inhibit the reduction of iron oxide and however doping CaO, SrO and BaO promote; all alkaline earth oxides tested in this study can change the precipitation morphology of fresh metallic iron; minimum doping mole fraction of one oxide to inhibit iron whiskers growth （ NAO ） is related to its cation radius （ r：＋ ） and its extranuclear electronic layers（nAD ）, which can be expressed as NAO = 1.3 × 10^-5r^2AD,√nA^2.

Simulation and Analysis of Microstructure Evolution of IN718 in Rotary Forgings by FEM

A numerical analysis was performed to study the influence of process parameters on the microstructure evolution of IN718 alloy in rotary forging using the finite element method （FEM）. For this purpose, a constitutive equation considering the effects of strain hardening and dynamic softening of IN718 alloy was built. The constitutive equation and microstructure models were implemented into the finite element code to investigate the microstructure evolution during rotary forging subject to large deformations. The simulations were carried out in the ratio of initial height to diameter range 0.2-0.8, the angle of the rocker 3°-7° and the relative feed per revolution range 0.01-0.1 r^-1. The research results revealed the deformation mechanism and the correlation of process parameters with the grain size evolution of IN718 alloy during rotary forging. These provide evidence for the selection of rotary forging parameters.