An effective method was proposed to establish the continuous cooling transformation(CCT) diagrams of aluminum alloys using in situ voltage measurement.The voltage change of samples with predefined dimension was reco...An effective method was proposed to establish the continuous cooling transformation(CCT) diagrams of aluminum alloys using in situ voltage measurement.The voltage change of samples with predefined dimension was recorded under the constant current state during continuous cooling.Solutionizing time,together with starting and finishing temperatures of phase transformation of the alloy can be obtained from relationships of voltage vs time and temperature.A critical cooling rate without detectable phase transition during continuous cooling can be determined.Continuous cooling transformation diagrams of tested samples can be established conveniently based on these results.Microstructure observation and differential scanning calorimetry(DSC) testing were applied to verify the reliability of continuous cooling transformation diagram.展开更多
A finite-element model of the thermosetting epoxy asphalt mixture(EAM) microstructure is developed to simulate the indirect tension test(IDT).Image techniques are used to capture the EAM microstructure which is di...A finite-element model of the thermosetting epoxy asphalt mixture(EAM) microstructure is developed to simulate the indirect tension test(IDT).Image techniques are used to capture the EAM microstructure which is divided into two phases:aggregates and mastic.A viscoelastic constitutive relationship,which is obtained from the results of a creep test,is used to represent the mastic phase at intermittent temperatures.Model simulation results of the stiffness modulus in IDT compare favorably with experimental data.Different loading directions and velocities are employed in order to account for their influence on the modulus and the localized stress of the microstructure model.It is pointed out that the modulus is not consistent when the loading direction changes since the heterogeneous distribution of the mixture internal structure,and the loading velocity affects the localized stress as a result of the viscoelasticity of the mastic.The study results can provide a theoretical basis for the finite-element method,which can be extended to the numerical simulations of asphalt mixture micromechanical behavior.展开更多
Isothermal compression experiments were conducted to study the hot deformation behaviors of a Sr-modified Al-Si-Mg alloy in the temperature range of 300-420°C and strain rate range of 0.01-10 s-1.A physically-bas...Isothermal compression experiments were conducted to study the hot deformation behaviors of a Sr-modified Al-Si-Mg alloy in the temperature range of 300-420°C and strain rate range of 0.01-10 s-1.A physically-based model was developed to accurately predict the flow stress.Meanwhile,processing maps were established to optimize hot working parameters.It is found that decreasing the strain rate or increasing the deformation temperature reduces the flow stress.The high activation energy is closely related to the pinning of dislocations from Si-containing dispersoids.Moreover,the deformed grains and the Si-containing dispersoids in the matrix are elongated perpendicular to the compression direction,and incomplete dynamic recrystallization(DRX)is discovered on the elongated boundaries in domain with peak efficiency.The flow instability is mainly attributed to the flow localization,brittle fracture of eutectic Si phase,and formation of adiabatic shear band.The optimum hot working window is 380-420°C and 0.03-0.28 s-1.展开更多
The microstructure and mechanical properties of extruded Mg-Zn alloy containing Y element were investigated in temperature range of 300-450°C and strain rate range of 0.001-1 s-1 through hot compression tests.Pro...The microstructure and mechanical properties of extruded Mg-Zn alloy containing Y element were investigated in temperature range of 300-450°C and strain rate range of 0.001-1 s-1 through hot compression tests.Processing maps were used to indicate optimum conditions and instability zones for hot deformation of alloys.For Mg-Zn and Mg-Zn-Y alloys,peak stress,temperature and strain rate were related by hyperbolic sine function,and activation energies were obtained to be 177 and 236 kJ/mol,respectively.Flow curves showed that the addition of Y element led to increase in peak stress and decrease in peak strain,and indicated that DRX started at lower strains in Mg-Zn-Y alloy than in Mg-Zn alloy.The stability domains of Mg-Zn-Y alloy were indicated in two domains as 1)300°C,0.001 s-1;350°C,0.01-0.1 s-1 and 400°C,0.01 s-1 and 2)450°C,0.01-0.1 s-1.Microstructural observations showed that DRX was the main restoration mechanism for alloys,and fully dynamic recrystallization of Mg-Zn-Y alloy was observed at 450°C.The instability domain in Mg-Zn-Y alloy was located significantly at high strain rates.In addition,the instability zone width of Mg-Zn and Mg-Zn-Y alloys increased with increasing strain,and cracks,twins and severe deformation were considered in these regions.展开更多
The deformation behavior and microstructure of the Zr50Ti50 alloy in β phase field were investigated by isothermal compression tests at temperatures ranging from 700 to 850 °C and strain rates ranging from 0.001...The deformation behavior and microstructure of the Zr50Ti50 alloy in β phase field were investigated by isothermal compression tests at temperatures ranging from 700 to 850 °C and strain rates ranging from 0.001 to 1 s?1. The flow curves exhibited typical flow softening. The initial discontinuous yielding behavior was observed at higher strain rates, which was not found in other traditional Zr alloys. The apparent deformation activation energy was calculated to be 103 kJ/mol and constitutive equationdescribing the flow stress as a function of the strain rate and deformation temperature was proposed. The analysis indicated that the hot deformation mechanism was mainly dominated by dynamic recovery. However, dynamic recrystallization was delayed by dynamic recovery. Thereafter, the processing map was calculated to evaluate the efficiency of the forging process at the temperatures and strain rates investigated and to optimize processing parameters of hot deformation. The optimum processing parameters were found to be 830?850 °C and 0.56?1 s?1 for hot the deformation of Zr50Ti50 alloy in the β phase region.展开更多
A methodology was presented relating the microstructure of asphalt mixtures to their damage behavior. Digital image techniques were used to capture the asphalt mixture microstructure, and the finite element method was...A methodology was presented relating the microstructure of asphalt mixtures to their damage behavior. Digital image techniques were used to capture the asphalt mixture microstructure, and the finite element method was used to simulate the damage evolution of asphalt mixture through splitting test. Aggregates were modeled to be linearly elastic, and the mastics were modeled to be plastically damaged. The splitting test simulation results show that the material heterogeneity, the properties of aggregates and air voids have significant effects on the damage evolution approach. The damage behavior of asphalt mixture considering material heterogeneity is quite different from that of the conventional hypothesis of homogeneous material. The results indicate that the proposed method can be extended to the numerical analysis for the other micromechanical behaviors of asphalt concrete.展开更多
This paper reports the extraction of aloe-emodin from aloe by microwave-assisted extraction. The effects of various factors, including the solvent, the ratio (mL/g) of the solvent to the sample, microwave irradiatio...This paper reports the extraction of aloe-emodin from aloe by microwave-assisted extraction. The effects of various factors, including the solvent, the ratio (mL/g) of the solvent to the sample, microwave irradiation time and microwave power, were discussed in the experiments. The yield of aloe-emodin was determined by HPLC. The optimized conditions for micro- wave-assisted extraction of aloe-emodin were concluded as follows: the solvent is 80% ethanol (V/V) solution, microwave ir- radiation time is 3 rain and microwave power is 340 W. Additionally, HPLC fingerprint was developed for consistency evalua- tion of aloe. The similarities of 3 aloe samples obtained by microwave-assisted extraction, ultrasound-assisted extraction and Soxhlet extraction were more than 0.9, indicating that 3 aloe samples were consistent. Compared with Soxhlet extraction and ultrasound-assisted extraction, microwave extraction is a rapid method with higher yield and less solvent consumption. Aloe samples treated by microwave-assisted extraction, ultrasound-assisted extraction and Soxhlet extraction were observed using transmission electronic microscopy. The micrographs provide evidence of more breakage of chloroplasts treated by micro- wave-assisted extraction as compared to Soxhlet extraction and ultrasound-assisted extraction.展开更多
In this paper, evacuation experiments are carried out to study pedestrian movement behaviors in building bottleneck. An image processing method based on mean-shift algorithm is used to extract pedestrian movement traj...In this paper, evacuation experiments are carried out to study pedestrian movement behaviors in building bottleneck. An image processing method based on mean-shift algorithm is used to extract pedestrian movement trajectory. Based on the extracted trajectory, we analyze the microscopic movement characteristics of pedestrians such as lane formation, change of velocity and distance between two sequential pedestrians. A pedestrian lane is a group of pedestrians moving in a column. The lane formation is verified by the pedestrian trajectory and distribution of pedestrian’s lateral positions (x direction in the paper): lane number changes from one to two, three or even more with the increasing bottleneck width when pedestrians pass through the bottleneck. By analyzing the pedestrian movement behaviors in the same pedestrian lane, we find three typical movement modes in the bottleneck: time-lag acceleration, synchronous acceleration, and avoiding deceleration. Through analyzing the time intervals when successive pedestrians pass through the bottleneck, we find that most pedestrians adjust their velocities according to the distance to the forward pedestrians. Results also indicate that due to different cultures, pedestrians flux in China and Germany may have some differences besides their similarities.展开更多
The dynamic wetting characteristics of water droplets on silicon wafers with microscale regular pillars structures and fresh lotus leaves are investigated experimentally.We measured the static contact angle,contact an...The dynamic wetting characteristics of water droplets on silicon wafers with microscale regular pillars structures and fresh lotus leaves are investigated experimentally.We measured the static contact angle,contact angle hysteresis,and roll-off angle of water droplets on both of these superhydrophobic surfaces with a high speed contact angle meter.The dynamic contact angles and internal velocity distribution of water droplets on superhydrophobic surfaces were studied with a high-speed camera system and a particle image velocimetry (PIV) system,respectively.We found that the acceleration of water droplets when they slide off lotus leaves is greater than that of water droplets sliding off the silicon wafers with microscale pillar structures although the static contact angles of water droplets on lotus leaves are slightly smaller than those on the silicon wafers.The reason is that water droplets sliding off lotus leaves have smaller contact angle hysteresis and larger slip velocities.These results indicate that the dynamic contact angle hysteresis and sliding acceleration of liquid droplets are more suitable for reflecting the hydrophobicity of material surfaces compared with static contact angles.Our experiments also show that lotus leaves with multiscale micro/nanostructures have stronger hydrophobicity and self-cleaning properties compared with the micro-structured superhydrophobic surfaces.展开更多
We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substr...We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substrate is patterned with a rectangular array of nanoscale holes. Because of the high quality of the pattern, using neutron reflectometry, we are able to map the surface-normal density distribution of the patterned silicon, the penetration of water into the pattern, and the distribution of a deposited film inside and outside of the etched holes. In this stud; 1,2-dilauroyl-sn-glycero-3-phosphocholine (DLPC) single bilayers were deposited on the hydrophilic patterned surface. For bilayers deposited either by vesicle fusion (VF) or by the Langmuir-Schaefer (L-S) technique, the most consistent model found to fit the data shows that the lipids form bilayer coatings on top of the substrate as well as the bottoms of the holes in an essentially conformal fashion. However, while there is a single bilayer on the unetched silicon surface, the lipids coating the bottoms of the holes form a complex bimodal structure consistent with a rough surface produced by the etching process. This study provides insight into film transfer both outside and inside regular nanopatterned features.展开更多
文摘An effective method was proposed to establish the continuous cooling transformation(CCT) diagrams of aluminum alloys using in situ voltage measurement.The voltage change of samples with predefined dimension was recorded under the constant current state during continuous cooling.Solutionizing time,together with starting and finishing temperatures of phase transformation of the alloy can be obtained from relationships of voltage vs time and temperature.A critical cooling rate without detectable phase transition during continuous cooling can be determined.Continuous cooling transformation diagrams of tested samples can be established conveniently based on these results.Microstructure observation and differential scanning calorimetry(DSC) testing were applied to verify the reliability of continuous cooling transformation diagram.
基金Program for New Century Excellent Talents in University(No. NCET-08-0118)Specialized Research Fund for the Doctoral Program of Higher Education (No. 20090092110049)
文摘A finite-element model of the thermosetting epoxy asphalt mixture(EAM) microstructure is developed to simulate the indirect tension test(IDT).Image techniques are used to capture the EAM microstructure which is divided into two phases:aggregates and mastic.A viscoelastic constitutive relationship,which is obtained from the results of a creep test,is used to represent the mastic phase at intermittent temperatures.Model simulation results of the stiffness modulus in IDT compare favorably with experimental data.Different loading directions and velocities are employed in order to account for their influence on the modulus and the localized stress of the microstructure model.It is pointed out that the modulus is not consistent when the loading direction changes since the heterogeneous distribution of the mixture internal structure,and the loading velocity affects the localized stress as a result of the viscoelasticity of the mastic.The study results can provide a theoretical basis for the finite-element method,which can be extended to the numerical simulations of asphalt mixture micromechanical behavior.
基金Project(51375502)supported by the National Natural Science Foundation of ChinaProject(2015CX002)supported by the Innovation-driven Plan in Central South University,China+2 种基金Project(2016RS2006)supported by the Science and Technology Leading Talent in Hunan Province,ChinaProject(Q2015140)supported by the Program of Chang Jiang Scholars of Ministry of Education,ChinaProject(2016JJ1017)supported by the Natural Science Foundation for Distinguished Young Scholars of Hunan Province,China
文摘Isothermal compression experiments were conducted to study the hot deformation behaviors of a Sr-modified Al-Si-Mg alloy in the temperature range of 300-420°C and strain rate range of 0.01-10 s-1.A physically-based model was developed to accurately predict the flow stress.Meanwhile,processing maps were established to optimize hot working parameters.It is found that decreasing the strain rate or increasing the deformation temperature reduces the flow stress.The high activation energy is closely related to the pinning of dislocations from Si-containing dispersoids.Moreover,the deformed grains and the Si-containing dispersoids in the matrix are elongated perpendicular to the compression direction,and incomplete dynamic recrystallization(DRX)is discovered on the elongated boundaries in domain with peak efficiency.The flow instability is mainly attributed to the flow localization,brittle fracture of eutectic Si phase,and formation of adiabatic shear band.The optimum hot working window is 380-420°C and 0.03-0.28 s-1.
文摘The microstructure and mechanical properties of extruded Mg-Zn alloy containing Y element were investigated in temperature range of 300-450°C and strain rate range of 0.001-1 s-1 through hot compression tests.Processing maps were used to indicate optimum conditions and instability zones for hot deformation of alloys.For Mg-Zn and Mg-Zn-Y alloys,peak stress,temperature and strain rate were related by hyperbolic sine function,and activation energies were obtained to be 177 and 236 kJ/mol,respectively.Flow curves showed that the addition of Y element led to increase in peak stress and decrease in peak strain,and indicated that DRX started at lower strains in Mg-Zn-Y alloy than in Mg-Zn alloy.The stability domains of Mg-Zn-Y alloy were indicated in two domains as 1)300°C,0.001 s-1;350°C,0.01-0.1 s-1 and 400°C,0.01 s-1 and 2)450°C,0.01-0.1 s-1.Microstructural observations showed that DRX was the main restoration mechanism for alloys,and fully dynamic recrystallization of Mg-Zn-Y alloy was observed at 450°C.The instability domain in Mg-Zn-Y alloy was located significantly at high strain rates.In addition,the instability zone width of Mg-Zn and Mg-Zn-Y alloys increased with increasing strain,and cracks,twins and severe deformation were considered in these regions.
基金Project(2013CB73300)supported by the National Basic Research Program of ChinaProjects(51531005,51434008,51571174)supported by the National Natural Science Foundation of China
文摘The deformation behavior and microstructure of the Zr50Ti50 alloy in β phase field were investigated by isothermal compression tests at temperatures ranging from 700 to 850 °C and strain rates ranging from 0.001 to 1 s?1. The flow curves exhibited typical flow softening. The initial discontinuous yielding behavior was observed at higher strain rates, which was not found in other traditional Zr alloys. The apparent deformation activation energy was calculated to be 103 kJ/mol and constitutive equationdescribing the flow stress as a function of the strain rate and deformation temperature was proposed. The analysis indicated that the hot deformation mechanism was mainly dominated by dynamic recovery. However, dynamic recrystallization was delayed by dynamic recovery. Thereafter, the processing map was calculated to evaluate the efficiency of the forging process at the temperatures and strain rates investigated and to optimize processing parameters of hot deformation. The optimum processing parameters were found to be 830?850 °C and 0.56?1 s?1 for hot the deformation of Zr50Ti50 alloy in the β phase region.
基金Project(50808086) supported by the National Natural Science Foundation of China
文摘A methodology was presented relating the microstructure of asphalt mixtures to their damage behavior. Digital image techniques were used to capture the asphalt mixture microstructure, and the finite element method was used to simulate the damage evolution of asphalt mixture through splitting test. Aggregates were modeled to be linearly elastic, and the mastics were modeled to be plastically damaged. The splitting test simulation results show that the material heterogeneity, the properties of aggregates and air voids have significant effects on the damage evolution approach. The damage behavior of asphalt mixture considering material heterogeneity is quite different from that of the conventional hypothesis of homogeneous material. The results indicate that the proposed method can be extended to the numerical analysis for the other micromechanical behaviors of asphalt concrete.
基金supported by the National Key Technology R&D Program (2006BAI09B07-02)
文摘This paper reports the extraction of aloe-emodin from aloe by microwave-assisted extraction. The effects of various factors, including the solvent, the ratio (mL/g) of the solvent to the sample, microwave irradiation time and microwave power, were discussed in the experiments. The yield of aloe-emodin was determined by HPLC. The optimized conditions for micro- wave-assisted extraction of aloe-emodin were concluded as follows: the solvent is 80% ethanol (V/V) solution, microwave ir- radiation time is 3 rain and microwave power is 340 W. Additionally, HPLC fingerprint was developed for consistency evalua- tion of aloe. The similarities of 3 aloe samples obtained by microwave-assisted extraction, ultrasound-assisted extraction and Soxhlet extraction were more than 0.9, indicating that 3 aloe samples were consistent. Compared with Soxhlet extraction and ultrasound-assisted extraction, microwave extraction is a rapid method with higher yield and less solvent consumption. Aloe samples treated by microwave-assisted extraction, ultrasound-assisted extraction and Soxhlet extraction were observed using transmission electronic microscopy. The micrographs provide evidence of more breakage of chloroplasts treated by micro- wave-assisted extraction as compared to Soxhlet extraction and ultrasound-assisted extraction.
基金supported by the National Natural Science Foundation of China (Grant No. 91024025)the NCET Project (Grant No. 08-0518)
文摘In this paper, evacuation experiments are carried out to study pedestrian movement behaviors in building bottleneck. An image processing method based on mean-shift algorithm is used to extract pedestrian movement trajectory. Based on the extracted trajectory, we analyze the microscopic movement characteristics of pedestrians such as lane formation, change of velocity and distance between two sequential pedestrians. A pedestrian lane is a group of pedestrians moving in a column. The lane formation is verified by the pedestrian trajectory and distribution of pedestrian’s lateral positions (x direction in the paper): lane number changes from one to two, three or even more with the increasing bottleneck width when pedestrians pass through the bottleneck. By analyzing the pedestrian movement behaviors in the same pedestrian lane, we find three typical movement modes in the bottleneck: time-lag acceleration, synchronous acceleration, and avoiding deceleration. Through analyzing the time intervals when successive pedestrians pass through the bottleneck, we find that most pedestrians adjust their velocities according to the distance to the forward pedestrians. Results also indicate that due to different cultures, pedestrians flux in China and Germany may have some differences besides their similarities.
基金supported by the National Natural Science Foundation of China(Grant Nos. 11072126 and 10872106)
文摘The dynamic wetting characteristics of water droplets on silicon wafers with microscale regular pillars structures and fresh lotus leaves are investigated experimentally.We measured the static contact angle,contact angle hysteresis,and roll-off angle of water droplets on both of these superhydrophobic surfaces with a high speed contact angle meter.The dynamic contact angles and internal velocity distribution of water droplets on superhydrophobic surfaces were studied with a high-speed camera system and a particle image velocimetry (PIV) system,respectively.We found that the acceleration of water droplets when they slide off lotus leaves is greater than that of water droplets sliding off the silicon wafers with microscale pillar structures although the static contact angles of water droplets on lotus leaves are slightly smaller than those on the silicon wafers.The reason is that water droplets sliding off lotus leaves have smaller contact angle hysteresis and larger slip velocities.These results indicate that the dynamic contact angle hysteresis and sliding acceleration of liquid droplets are more suitable for reflecting the hydrophobicity of material surfaces compared with static contact angles.Our experiments also show that lotus leaves with multiscale micro/nanostructures have stronger hydrophobicity and self-cleaning properties compared with the micro-structured superhydrophobic surfaces.
文摘We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substrate is patterned with a rectangular array of nanoscale holes. Because of the high quality of the pattern, using neutron reflectometry, we are able to map the surface-normal density distribution of the patterned silicon, the penetration of water into the pattern, and the distribution of a deposited film inside and outside of the etched holes. In this stud; 1,2-dilauroyl-sn-glycero-3-phosphocholine (DLPC) single bilayers were deposited on the hydrophilic patterned surface. For bilayers deposited either by vesicle fusion (VF) or by the Langmuir-Schaefer (L-S) technique, the most consistent model found to fit the data shows that the lipids form bilayer coatings on top of the substrate as well as the bottoms of the holes in an essentially conformal fashion. However, while there is a single bilayer on the unetched silicon surface, the lipids coating the bottoms of the holes form a complex bimodal structure consistent with a rough surface produced by the etching process. This study provides insight into film transfer both outside and inside regular nanopatterned features.