The microstructure, dielectric properties and chemical state of Ti element on BaTi_4O_9 (f)/(0.64 BaTi_4O_9-0.36BaPr_2Ti_4O_(12)) composites sample surface were characterized by X-ray diffraction (XRD), Transmission e...The microstructure, dielectric properties and chemical state of Ti element on BaTi_4O_9 (f)/(0.64 BaTi_4O_9-0.36BaPr_2Ti_4O_(12)) composites sample surface were characterized by X-ray diffraction (XRD), Transmission electron microscopy (TEM), LCR meter method and X-ray photoelectron spectroscopy (XPS). The results show that the system is composed of BaTi_4O_9 and BaPr_2Ti_4O_(12) two phases. Pr ions are distributed in the BaWi_4O_9 grains and the segregation of Pr ions was observed on the grain boundaries of BaTi_4O_9/BaTi_4O_9. The content of Ti^(3+) and Ti^(2+) decrease in the BPT system composites due to the addition of BaTi_4O_9 fibers, which improved the dielectric properties of the system. BPT10 sample with 10% BaTi_4O_9 fibers, has the best dielectric properties in the system, its ε_r = 64, tan δ= 1×10^(-4)(at 1 MHz) , and it may be a potential candidate for microwave dielectric ceramics.展开更多
It is economically advantageous to cast wrought aluminum alloys directly into near-net-shape components.The objective of the present work is to take advantage of the rheoforming with 7075 alloy to improve the competit...It is economically advantageous to cast wrought aluminum alloys directly into near-net-shape components.The objective of the present work is to take advantage of the rheoforming with 7075 alloy to improve the competitiveness of this emerging technology in the manufacture of wrought aluminum alloy.High quality semi-solid slurry was produced,in which primary α(Al) presents in diameter of 62 μm and shape factor of 0.78 and features no eutectics entrapped.Higher forming pressure results in small grain size,improved shape factor and higher density.Especially,rheoforming can effectively reduce the occurrence of hot tearing.The average yield strength and elongation of the rheoformed samples in the T6 condition are 483 MPa and 8%,respectively.展开更多
The microstructure and surface state of three kinds of polyacrylonitrile-based carbon fibers (T700, T300 and M40) before and after high temperature treatment were investigated. Also, the pyrocarbon and thermal condu...The microstructure and surface state of three kinds of polyacrylonitrile-based carbon fibers (T700, T300 and M40) before and after high temperature treatment were investigated. Also, the pyrocarbon and thermal conductivity of carbon/carbon composites with different carbon fibers as preform were studied. The results show that M40 carbon fiber has the largest crystallite size and the least d002, T300 follows, and TT00 the third. With the increase of heat treatment temperature, the surface state and crystal size of carbon fibers change correspondingly. M40 carbon fiber exhibits the best graphitization property, followed by T300 and then T700. The different microstructure and surface state of different carbon fibers lead to the different microstructures of pyrocarbon and then result in the different thermal conductivities of carbon/carbon composites. The carbon/carbon composite with M40 as preform has the best microstructure in pyrocarbon and the highest thermal conductivity.展开更多
Inelastic electron scattering form factors has been calculated for different parity for the two (C3) transitions of 14^N for (5.83MeV) (f^π, T = 20) level and, (5.106MeV) (f^π, T = 30) level in the frame w...Inelastic electron scattering form factors has been calculated for different parity for the two (C3) transitions of 14^N for (5.83MeV) (f^π, T = 20) level and, (5.106MeV) (f^π, T = 30) level in the frame work of shell model. The model space wave functions are generated by using the Cohen-Kurath (CK) interaction, where 4He is assumed as a core and ten nucleons are distributed over the lp-shell which forms the model space. Core-polarization effects (CP) (the effects from outside lp-shell model space) are included through the first order perturbation theory. The core-polarization effects increase the form factor to be up near the experimental data which are not sufficient to give a good comparison with the calculating data.展开更多
In seasonal frozen soil region,the engineering geological properties of loess-like soil will be deteriorated after freeze-thaw cycles.Through the freeze-thaw cycle experiment of remolded loess-like soil,under differen...In seasonal frozen soil region,the engineering geological properties of loess-like soil will be deteriorated after freeze-thaw cycles.Through the freeze-thaw cycle experiment of remolded loess-like soil,under different freezing temperatures,the authors carried out freeze-thaw cycle tests for 3 times and 20 times,respectively.With mercury intrusion porosimetry and granulometric analysis,from the micro-structure,the authors studied the law that freeze-thaw cycle times and frozen temperature effect on the variation of microscopic pore of loesslike soil.This result can provide theoretical basis for comprehensive treatment of problems in the construction of the project in seasonal frozen loess-like soil region.展开更多
文摘The microstructure, dielectric properties and chemical state of Ti element on BaTi_4O_9 (f)/(0.64 BaTi_4O_9-0.36BaPr_2Ti_4O_(12)) composites sample surface were characterized by X-ray diffraction (XRD), Transmission electron microscopy (TEM), LCR meter method and X-ray photoelectron spectroscopy (XPS). The results show that the system is composed of BaTi_4O_9 and BaPr_2Ti_4O_(12) two phases. Pr ions are distributed in the BaWi_4O_9 grains and the segregation of Pr ions was observed on the grain boundaries of BaTi_4O_9/BaTi_4O_9. The content of Ti^(3+) and Ti^(2+) decrease in the BPT system composites due to the addition of BaTi_4O_9 fibers, which improved the dielectric properties of the system. BPT10 sample with 10% BaTi_4O_9 fibers, has the best dielectric properties in the system, its ε_r = 64, tan δ= 1×10^(-4)(at 1 MHz) , and it may be a potential candidate for microwave dielectric ceramics.
基金Projects(50804023,50474007) supported by the National Natural Science Foundation of ChinaProject(GJJ08006) supported by the Jiangxi Provincial Education Department,China
文摘It is economically advantageous to cast wrought aluminum alloys directly into near-net-shape components.The objective of the present work is to take advantage of the rheoforming with 7075 alloy to improve the competitiveness of this emerging technology in the manufacture of wrought aluminum alloy.High quality semi-solid slurry was produced,in which primary α(Al) presents in diameter of 62 μm and shape factor of 0.78 and features no eutectics entrapped.Higher forming pressure results in small grain size,improved shape factor and higher density.Especially,rheoforming can effectively reduce the occurrence of hot tearing.The average yield strength and elongation of the rheoformed samples in the T6 condition are 483 MPa and 8%,respectively.
基金Project(201012200233)supported by the Freedom Explore Program of Central South University,China
文摘The microstructure and surface state of three kinds of polyacrylonitrile-based carbon fibers (T700, T300 and M40) before and after high temperature treatment were investigated. Also, the pyrocarbon and thermal conductivity of carbon/carbon composites with different carbon fibers as preform were studied. The results show that M40 carbon fiber has the largest crystallite size and the least d002, T300 follows, and TT00 the third. With the increase of heat treatment temperature, the surface state and crystal size of carbon fibers change correspondingly. M40 carbon fiber exhibits the best graphitization property, followed by T300 and then T700. The different microstructure and surface state of different carbon fibers lead to the different microstructures of pyrocarbon and then result in the different thermal conductivities of carbon/carbon composites. The carbon/carbon composite with M40 as preform has the best microstructure in pyrocarbon and the highest thermal conductivity.
文摘Inelastic electron scattering form factors has been calculated for different parity for the two (C3) transitions of 14^N for (5.83MeV) (f^π, T = 20) level and, (5.106MeV) (f^π, T = 30) level in the frame work of shell model. The model space wave functions are generated by using the Cohen-Kurath (CK) interaction, where 4He is assumed as a core and ten nucleons are distributed over the lp-shell which forms the model space. Core-polarization effects (CP) (the effects from outside lp-shell model space) are included through the first order perturbation theory. The core-polarization effects increase the form factor to be up near the experimental data which are not sufficient to give a good comparison with the calculating data.
文摘In seasonal frozen soil region,the engineering geological properties of loess-like soil will be deteriorated after freeze-thaw cycles.Through the freeze-thaw cycle experiment of remolded loess-like soil,under different freezing temperatures,the authors carried out freeze-thaw cycle tests for 3 times and 20 times,respectively.With mercury intrusion porosimetry and granulometric analysis,from the micro-structure,the authors studied the law that freeze-thaw cycle times and frozen temperature effect on the variation of microscopic pore of loesslike soil.This result can provide theoretical basis for comprehensive treatment of problems in the construction of the project in seasonal frozen loess-like soil region.