A novel solid support adsorbent for CO2capture was developed by loading pentaethylenehexamine(PEHA)on commercially available mesoporous molecular sieve MCM-41 using wet impregnation method.MCM-41 samples before and af...A novel solid support adsorbent for CO2capture was developed by loading pentaethylenehexamine(PEHA)on commercially available mesoporous molecular sieve MCM-41 using wet impregnation method.MCM-41 samples before and after PEHA loading were characterized by X-ray powder diffraction,N2adsorption/desorption,thermal gravimetric analysis and scanning electron microscope to investigate the textural and thermo-physical properties.CO2adsorption performance was evaluated in a fixed bed adsorption system.Results indicated that the structure of MCM-41 was preserved after loading PEHA.Surface area and total pore volume of PEHA loaded MCM-41 decreased with the increase of loading.The working adsorption capacity of CO2could be significantly improved at 60%of PEHA loading and 75°C.The effect of the height of adsorbent bed was investigated and the best working adsorption capacity for MCM-41-PEHA-60 reached 165 mg·(g adsorbent)-1at 75°C.Adsorption/desorption circle showed that the CO2working adsorption capacity of MCM-41-PEHA kept stable.展开更多
Based on a sample of some real earthquakes,we have suggested in previous papers that there is a density-tectonic stress wave with ultra-low frequency which is emitted from the epicenter region for months before earthq...Based on a sample of some real earthquakes,we have suggested in previous papers that there is a density-tectonic stress wave with ultra-low frequency which is emitted from the epicenter region for months before earthquakes,and a micro-fracture wave 1 ～ 10 days before earthquakes. The former has been observed by different kinds of measurements and the latter has been observed by a few chance observations which consists of electromagnetic,gravitational and sonic fluctuations. We show real observational results that depict the two waves and they have very different frequencies,which are not difficult to discriminate. The classical elastic-rebound model is one of the most influential theories on earthquakes,and the thermodynamic elastic-rebound model has amended the classical framework. Considering the two waves above,we attempt to further modify the elasticrebound model,and the new framework could be called the "micro-fracture elasticrebound model". We infer that tectonic earthquakes could have three special phases: the accumulation of tectonic stress,micro-fracture,and main-fracture. Accordingly,there would be three waves which come from the epicenter of a tectonic earthquake,i. e. ,the tectonic stress wave with ultra-low frequency a few months before the earthquake,the micro-fracture wave about 1 ～ 10 days before the earthquake and the main-fracture wave (common earthquake wave).展开更多
基金Supported by the National Natural Science Foundation of China(20836008,21176132)the Special Research Fund for the Doctoral Program of the Ministry of Education of China(20101012174)
文摘A novel solid support adsorbent for CO2capture was developed by loading pentaethylenehexamine(PEHA)on commercially available mesoporous molecular sieve MCM-41 using wet impregnation method.MCM-41 samples before and after PEHA loading were characterized by X-ray powder diffraction,N2adsorption/desorption,thermal gravimetric analysis and scanning electron microscope to investigate the textural and thermo-physical properties.CO2adsorption performance was evaluated in a fixed bed adsorption system.Results indicated that the structure of MCM-41 was preserved after loading PEHA.Surface area and total pore volume of PEHA loaded MCM-41 decreased with the increase of loading.The working adsorption capacity of CO2could be significantly improved at 60%of PEHA loading and 75°C.The effect of the height of adsorbent bed was investigated and the best working adsorption capacity for MCM-41-PEHA-60 reached 165 mg·(g adsorbent)-1at 75°C.Adsorption/desorption circle showed that the CO2working adsorption capacity of MCM-41-PEHA kept stable.
文摘Based on a sample of some real earthquakes,we have suggested in previous papers that there is a density-tectonic stress wave with ultra-low frequency which is emitted from the epicenter region for months before earthquakes,and a micro-fracture wave 1 ～ 10 days before earthquakes. The former has been observed by different kinds of measurements and the latter has been observed by a few chance observations which consists of electromagnetic,gravitational and sonic fluctuations. We show real observational results that depict the two waves and they have very different frequencies,which are not difficult to discriminate. The classical elastic-rebound model is one of the most influential theories on earthquakes,and the thermodynamic elastic-rebound model has amended the classical framework. Considering the two waves above,we attempt to further modify the elasticrebound model,and the new framework could be called the "micro-fracture elasticrebound model". We infer that tectonic earthquakes could have three special phases: the accumulation of tectonic stress,micro-fracture,and main-fracture. Accordingly,there would be three waves which come from the epicenter of a tectonic earthquake,i. e. ,the tectonic stress wave with ultra-low frequency a few months before the earthquake,the micro-fracture wave about 1 ～ 10 days before the earthquake and the main-fracture wave (common earthquake wave).
