The velocity, phase fraction and fluctuation velocity of dense clusters are obtained by analysis of transient velocity signals from laser Doppler velocimeter The local velocity of dense clusters increased linearly wit...The velocity, phase fraction and fluctuation velocity of dense clusters are obtained by analysis of transient velocity signals from laser Doppler velocimeter The local velocity of dense clusters increased linearly with superficial gas velocity, while the cross sectional average solids fraction influence the velocity of dense clusters insignificantly A Boltzmann function is used to describe the velocity radial distribution of dense clusters The radial distribution of the phase fraction for dense clusters is described by using an exponential function With the increase of cross sectional average solids fraction, the local phase fraction of dense clusters increases and the area controlled by dense clusters is enlarged The turbulence intensity of dense clusters is highest in the center of the bed while decreases towards the展开更多
The flow behavior of pressure-driven water infiltration through graphene-based slit nanopores has been studied by molecular simulation.The simulated flow rate is close to the experimental values,which demonstrates the...The flow behavior of pressure-driven water infiltration through graphene-based slit nanopores has been studied by molecular simulation.The simulated flow rate is close to the experimental values,which demonstrates the reasonability of simulation results.Water molecules can spontaneously infiltrate into the nanopores,but an external driving force is generally required to pass through the whole pores.The exit of nanopore has a large obstruction on the water effusion.The flow velocity within the graphene nanochannels does not display monotonous dependence upon the pore width,indicating that the flow is related to the microscopic structures of water confined in the nanopores.Extensive structures of confined water are characterized in order to understand the flow behavior.This simulation improves the understanding of graphene-based nanofluidics,which helps in developing a new type of membrane separation technique.展开更多
Microstructure profiling measurements taken on a shallow Black Sea shelf and in Lake Banyoles and Boadella reservoir (Both in Spain) are analyzed to investigate the influence of boundary-layer-induced turbulence of ...Microstructure profiling measurements taken on a shallow Black Sea shelf and in Lake Banyoles and Boadella reservoir (Both in Spain) are analyzed to investigate the influence of boundary-layer-induced turbulence of various sources on mixing in the water interior. The state of turbulence in shallow waters is examined and details of microstructure data processing and error analysis are discussed. The dependence between averaged activity parameter A6 and buoyancy Reynolds number Reb for the shelf turbulence indicates that for Reb 〈 1 the state of turbulence can be described by the fossil turbulence model, which postulates AG - Re b^1/2. For Reb 〉 1, however, the influence of Reb on Ao is weak, signifying that the buoyancy Reynolds number can no longer serve as the governing parameter for active turbulent mixing. The generation of turbulence by a one-minute long wind bursts (the Boadella reservoir) increases the averaged dissipation rate (ε) of the surface mixed layer by more than 5 times (up to 3 × 10^-6 W kg^-1). The influence of the wind bursts was also traced below the thermocline, where turbulent patches with (ε) = (10^-7 - 10^-6) W kg^-1 were generated. It is shown that the geothermal convection in Lake Banyoles produces intermittent turbulent patches with characteristic dissipation rate (ε) = (2 × 10^-8- 3 × 10^-7) W kg^-1, which influences the overall vertical mixing in the basin.展开更多
The AI-AIN-Si composites were prepared in the gas-in-liquid in situ synthesized flow-reaction-system, which was implemented by a powder metallurgy and reaction sin- tering route. The experimental results showed that A...The AI-AIN-Si composites were prepared in the gas-in-liquid in situ synthesized flow-reaction-system, which was implemented by a powder metallurgy and reaction sin- tering route. The experimental results showed that A1-AIN- 50SiB material (prepared by ball-milling powders) and AI- AIN-50SiM material (prepared by mixing powders) exhibited the semi-continuous Si structures and the isolated Si islands, respectively. Subsequently, the AI-AIN-50Si materials were selected as the model materials by phase identification and microstructure analysis. The dynamic microstructural evolu- tion of AI-AIN-50Si materials was investigated using the computational fluid dynamics (CFD) method. Mathematical models and simulation results showed that the in situ synthesis of AIN was strongly influenced by the structure and the flow- path ((Cg,N2/lg,N2)+(Cs,AlN/ls,AiN)). The flow paths of AI-AIN-50Si^B material were restricted by the semi-continuous Si. These Si structures can promote the formation of the strong turbulence with gradually weakened fluctuation, so that the in situ synthesis of AIN was interconnected and surrounded by an interpenetrating Si network. In contrast, the flow paths of AI- AIN-50Si^B material can easily pass through the isolated Si due to its mild turbulence with linear relationship. As a result, AIN was separated by the isolated Si and agglomerated in the matrix. Overall, the present work provides new insights into dynamic microstructural evolution in in situ reaction sinter- ing systems.展开更多
Impact polypropylene copolymer (IPC), named polypropylene catalloy, not only possesses excellent impact property, but also presents good rigidity. Its superior performances result from the complicated composition and ...Impact polypropylene copolymer (IPC), named polypropylene catalloy, not only possesses excellent impact property, but also presents good rigidity. Its superior performances result from the complicated composition and microstructure. In the present article, recent progress in the studies on microstructure, morphology, crystallization and rheological behavior of IPC is summarized, and findings of the authors and their collaborators are reported. In general, IPC is divided into three components, i.e., ethylene-propylene random copolymer (EPR), a series of different segment lengths ethylene-propylene copolymer (EbP) and propylene homopolymer. The reasonable macromolecular structures of EbP and a multilayered core-shell model of dispersed phase structure in IPC were proposed, in which the dispersed phase consists of an outer EbP shell, an inner EPR layer and an EbP core. It is found that the annealing at melt-state may lead to an abnormal phase inversion, and the phase inversion disappears when temperature cools down to room temperature. The cause of phase inversion is ascribed to the existence of EbP component, which results in the stronger activity of the dispersed phase. The crystalline structure and morphologic results confirm the formation of β-iPP in IPC. Furthermore, it is found that the ethylene content in IPC and cooling rate of the samples have an important influence on the formation of β-iPP. Based on the crystallization kinetics analyzed by Lauritzen-Hoffman theory, crystallization behavior of different IPC samples is discussed and it is proposed that the dilution effect of ethylene propylene copolymer has a more remarkable influence on surface nucleation than on crystal growth. In addition, annealing at high temperature can result in the changes of chain structure for IPC, and this instability is ascribed to the oxidative degradation and crosslink reaction mainly in iPP component.展开更多
文摘The velocity, phase fraction and fluctuation velocity of dense clusters are obtained by analysis of transient velocity signals from laser Doppler velocimeter The local velocity of dense clusters increased linearly with superficial gas velocity, while the cross sectional average solids fraction influence the velocity of dense clusters insignificantly A Boltzmann function is used to describe the velocity radial distribution of dense clusters The radial distribution of the phase fraction for dense clusters is described by using an exponential function With the increase of cross sectional average solids fraction, the local phase fraction of dense clusters increases and the area controlled by dense clusters is enlarged The turbulence intensity of dense clusters is highest in the center of the bed while decreases towards the
基金Supported by the National Natural Science Foundation of China(21376116)A PAPD Project of Jiangsu Higher Education Institution
文摘The flow behavior of pressure-driven water infiltration through graphene-based slit nanopores has been studied by molecular simulation.The simulated flow rate is close to the experimental values,which demonstrates the reasonability of simulation results.Water molecules can spontaneously infiltrate into the nanopores,but an external driving force is generally required to pass through the whole pores.The exit of nanopore has a large obstruction on the water effusion.The flow velocity within the graphene nanochannels does not display monotonous dependence upon the pore width,indicating that the flow is related to the microscopic structures of water confined in the nanopores.Extensive structures of confined water are characterized in order to understand the flow behavior.This simulation improves the understanding of graphene-based nanofluidics,which helps in developing a new type of membrane separation technique.
基金The work was supported by the US Office of Naval Research(N00014-97-1-0140 and N00014-05-l-0245)by the Spanish Government(GL2004-02027/HID).
文摘Microstructure profiling measurements taken on a shallow Black Sea shelf and in Lake Banyoles and Boadella reservoir (Both in Spain) are analyzed to investigate the influence of boundary-layer-induced turbulence of various sources on mixing in the water interior. The state of turbulence in shallow waters is examined and details of microstructure data processing and error analysis are discussed. The dependence between averaged activity parameter A6 and buoyancy Reynolds number Reb for the shelf turbulence indicates that for Reb 〈 1 the state of turbulence can be described by the fossil turbulence model, which postulates AG - Re b^1/2. For Reb 〉 1, however, the influence of Reb on Ao is weak, signifying that the buoyancy Reynolds number can no longer serve as the governing parameter for active turbulent mixing. The generation of turbulence by a one-minute long wind bursts (the Boadella reservoir) increases the averaged dissipation rate (ε) of the surface mixed layer by more than 5 times (up to 3 × 10^-6 W kg^-1). The influence of the wind bursts was also traced below the thermocline, where turbulent patches with (ε) = (10^-7 - 10^-6) W kg^-1 were generated. It is shown that the geothermal convection in Lake Banyoles produces intermittent turbulent patches with characteristic dissipation rate (ε) = (2 × 10^-8- 3 × 10^-7) W kg^-1, which influences the overall vertical mixing in the basin.
基金supported by the financial support of the National Natural Science Foundation of China (51171146 and 51101177)the Program for Key Science and Technology Innovative Research Team of Shaanxi Province (2013KCT-05)
文摘The AI-AIN-Si composites were prepared in the gas-in-liquid in situ synthesized flow-reaction-system, which was implemented by a powder metallurgy and reaction sin- tering route. The experimental results showed that A1-AIN- 50SiB material (prepared by ball-milling powders) and AI- AIN-50SiM material (prepared by mixing powders) exhibited the semi-continuous Si structures and the isolated Si islands, respectively. Subsequently, the AI-AIN-50Si materials were selected as the model materials by phase identification and microstructure analysis. The dynamic microstructural evolu- tion of AI-AIN-50Si materials was investigated using the computational fluid dynamics (CFD) method. Mathematical models and simulation results showed that the in situ synthesis of AIN was strongly influenced by the structure and the flow- path ((Cg,N2/lg,N2)+(Cs,AlN/ls,AiN)). The flow paths of AI-AIN-50Si^B material were restricted by the semi-continuous Si. These Si structures can promote the formation of the strong turbulence with gradually weakened fluctuation, so that the in situ synthesis of AIN was interconnected and surrounded by an interpenetrating Si network. In contrast, the flow paths of AI- AIN-50Si^B material can easily pass through the isolated Si due to its mild turbulence with linear relationship. As a result, AIN was separated by the isolated Si and agglomerated in the matrix. Overall, the present work provides new insights into dynamic microstructural evolution in in situ reaction sinter- ing systems.
基金supported by the National Basic Research Program of China (2005CB623800)National Natural Science Foundation of China (51173157)Natural Science Foundation of Zhejiang Province (Y4100314)
文摘Impact polypropylene copolymer (IPC), named polypropylene catalloy, not only possesses excellent impact property, but also presents good rigidity. Its superior performances result from the complicated composition and microstructure. In the present article, recent progress in the studies on microstructure, morphology, crystallization and rheological behavior of IPC is summarized, and findings of the authors and their collaborators are reported. In general, IPC is divided into three components, i.e., ethylene-propylene random copolymer (EPR), a series of different segment lengths ethylene-propylene copolymer (EbP) and propylene homopolymer. The reasonable macromolecular structures of EbP and a multilayered core-shell model of dispersed phase structure in IPC were proposed, in which the dispersed phase consists of an outer EbP shell, an inner EPR layer and an EbP core. It is found that the annealing at melt-state may lead to an abnormal phase inversion, and the phase inversion disappears when temperature cools down to room temperature. The cause of phase inversion is ascribed to the existence of EbP component, which results in the stronger activity of the dispersed phase. The crystalline structure and morphologic results confirm the formation of β-iPP in IPC. Furthermore, it is found that the ethylene content in IPC and cooling rate of the samples have an important influence on the formation of β-iPP. Based on the crystallization kinetics analyzed by Lauritzen-Hoffman theory, crystallization behavior of different IPC samples is discussed and it is proposed that the dilution effect of ethylene propylene copolymer has a more remarkable influence on surface nucleation than on crystal growth. In addition, annealing at high temperature can result in the changes of chain structure for IPC, and this instability is ascribed to the oxidative degradation and crosslink reaction mainly in iPP component.