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电动汽车锂离子电池碳负极扩散应力与微观结构失效机理研究 被引量:4
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作者 刘良 李超 +3 位作者 顾延光 王丽梅 裴磊 王瑞帅 《中国公路学报》 EI CAS CSCD 北大核心 2022年第8期79-88,共10页
扩散应力易引起电极体积变化、电极颗粒破裂和脱落,导致电极材料失效,从而引起锂离子电池容量的衰减。为探究不同材料厚度和放电倍率下的扩散应力规律以及扩散应力与微观结构破坏间的关联性,采用试验与仿真相结合的方法进行相关研究。首... 扩散应力易引起电极体积变化、电极颗粒破裂和脱落,导致电极材料失效,从而引起锂离子电池容量的衰减。为探究不同材料厚度和放电倍率下的扩散应力规律以及扩散应力与微观结构破坏间的关联性,采用试验与仿真相结合的方法进行相关研究。首先,制备3种不同厚度(25、36、48μm)的石墨负极,与三元正极组装成纽扣全电池;其次,以相同充电倍率(0.2C)、不同放电倍率(1C、2C、5C)在25℃下进行循环测试,为模型验证及微观测试提供样本;随后,根据电化学及扩散力学原理建立电化学-力耦合模型,并通过不同倍率放电工况对模型进行验证;进一步,利用控制变量法,基于所建模型研究不同材料厚度与放电倍率下扩散应力的规律;最后,基于电镜扫描和X射线衍射测试,对循环后的负极形貌及微观结构进行表征,结合模型仿真研究扩散应力与负极微观结构的破坏关联性。研究结果表明:随着放电倍率增大或材料厚度减小,扩散应力增大、负极损坏程度加深,可根据拉伸屈服强度将扩散应力与微观结构变化关系分为2个阶段;进一步,引入剥落指数定量描述微观结构失效,发现剥落指数与扩散应力之间存在幂函数关系。研究结果可为揭示扩散应力与容量损失之间的关联性提供思路。 展开更多
关键词 汽车工程 微观结构失效 试验与仿真联合 锂离子电池 碳负极 扩散应力 电动汽车
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Scatter of fatigue data owing to material microscopic effects 被引量:10
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作者 TANG XueSong 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2014年第1期90-97,共8页
A common phenomenon of fatigue test data reported in the open literature such as S-N curves exhibits the scatter of points for a group of same specimens under the same loading condition.The reason is well known that t... A common phenomenon of fatigue test data reported in the open literature such as S-N curves exhibits the scatter of points for a group of same specimens under the same loading condition.The reason is well known that the microstructure is different from specimen to specimen even in the same group.Specifically,a fatigue failure process is a multi-scale problem so that a fatigue failure model should have the ability to take the microscopic effect into account.A physically-based trans-scale crack model is established and the analytical solution is obtained by coupling the micro-and macro-scale.Obtained is the trans-scale stress intensity factor as well as the trans-scale strain energy density(SED)factor.By taking this trans-scale SEDF as a key controlling parameter for the fatigue crack propagation from micro-to macro-scale,a trans-scale fatigue crack growth model is proposed in this work which can reflect the microscopic effect and scale transition in a fatigue process.The fatigue test data of aluminum alloy LY12 plate specimens is chosen to check the model.Two S-N experimental curves for cyclic stress ratio R=0.02 and R=0.6 are selected.The scattering test data points and two S-N curves for both R=0.02 and R=0.6 are exactly re-produced by application of the proposed model.It is demonstrated that the proposed model is able to reflect the multiscaling effect in a fatigue process.The result also shows that the microscopic effect has a pronounced influence on the fatigue life of specimens. 展开更多
关键词 fracture mechanics fatigue crack growth multiscaling effect S-N curve microscopic effect trans-scale
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