Soil samples were collected from Zhangshi Wastewater Irrigation Area in the suburb of Shenyang City,China,an area with a 30-year irrigation history with heavy metal-containing wastewater.The chemical properties and mi...Soil samples were collected from Zhangshi Wastewater Irrigation Area in the suburb of Shenyang City,China,an area with a 30-year irrigation history with heavy metal-containing wastewater.The chemical properties and microbial characteristics of the soils were examined to evaluate the present situation of heavy metal pollution and to assess the soil microbial characteristics under long-term heavy metal stress.In light of the National Environmental Quality Standards of China,the soil in the test area was heavily polluted by Cd and to a lesser degree by Zn and Cu,even though wastewater irrigation ceased in 1993.Soil metabolic quotient (qCO_2) had a significant positive correlation,while soil microbial quotient (qM) had a negative correlation with content of soil heavy metals.Soil microbial biomass carbon (MBC) had significantly negative correlation with Cd,but soil substrate-induced respiration (SIR),dehydrogenase activity (DHA),cellulase activity, and culturable microbial populations had no persistent correlations with soil heavy metal content.Soil nutrients,except for phosphorous,showed positive effects on soil microbial characteristics,which to a certain degree obscured the adverse effects of soil heavy metals.Soil Cd contributed more to the soil microbial characteristics,but qM and qCO_2 were more sensitive and showed persistent responses to heavy metals stress.It could be concluded that qM and qCO_2 can be used as bioindicators of heavy metal pollution in soils.展开更多
Copper (Cu) mine tailings, because of their high content of heavy metals, are usually hostile to plant colonization. A pot experiment was conducted to determine the tolerance of four forage grasses to heavy metals i...Copper (Cu) mine tailings, because of their high content of heavy metals, are usually hostile to plant colonization. A pot experiment was conducted to determine the tolerance of four forage grasses to heavy metals in Cu mine tailings and to examine the variation in the microbial functional diversity of soils from the tailing sites in southern China. All the four grass species survived on Cu mine tailings and Cu mine tailing-soil mixture. However, on pure mine tailings, the growth was minimal, whereas the growth was maximum for the control without mine tailings. The tolerance of grasses to heavy metals followed the sequence: Paspalum notatum 〉 Festuea arundinaeea 〉 Lolium perenne 〉 Cynodon daetylon. The planting of forage grasses enhanced the soil microbial biomass. The Biolog data indicated that the soil microbial metabolic profile values (average well color development, community richness, and Shannon index) of the four forage grasses also followed the sequence: P. notatum 〉 F. arundinaeea 〉 L. perenne 〉 C. daetylon. Thus, P. notatum, under the experimental conditions of this study, may be considered as the preferred plant species for revegetation of Cu mine tailing areas.展开更多
Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent sus...Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent susceptibility (Xfd) showed the absence of superparamagnetic (SP) grains in the samples. The IRM20mT (isothermal remanent magnetization at 20 mT) being linearly proportional to SIRM (saturation isothermal remanent magnetization) (R^2=0.901), suggested that ferrimagnetic minerals were responsible for the magnetic properties of automobile emission particulates. The average contents of Cu, Cd, Pb and Fe in automobile emission particulates were 95.83, 22.14, 30.58 and 34727.31 mg/kg, respectively. Significant positive correlations exist between the magnetic parameters and the contents ofPb, Cu and Fe. The magnetic parameters of automobile emission particulates reflecting concentration of magnetic particles increased linearly with increase of Pb and Cu content, showed that the magnetic measurement could be used as a preliminary index for detection of Pb and Cu pollution.展开更多
Due to the paramagnetic property of liquid oxygen,the Kelvin force can be induced in liquid oxygen under non-uniform magnetic field.Based on the volume of fluid(VOF)model,the positioning effect of the force in liquid ...Due to the paramagnetic property of liquid oxygen,the Kelvin force can be induced in liquid oxygen under non-uniform magnetic field.Based on the volume of fluid(VOF)model,the positioning effect of the force in liquid oxygen tanks is analyzed under various Bond numbers(Bo)and magnetic Bond numbers(Bom).The results show that the magnetic field has the effect of repositioning the liquid oxygen in the tank when the gravity field is not enough or absent.Additionally,the gas-liquid interface has a periodic fluctuation during the process due to the inhomogeneous Kelvin force distribution,and more effective suppression of fluctuation can be achieved under the condition of a larger Bom.The new method of controlling gas-liquid interface of liquid oxygen tank under micro gravity condition is hoped to be developed in the future.展开更多
Nowadays, oil spills have led to a serious environmental crisis of the world. To deal with this problem, inspired from super-hydrophobic lotus leaf, this study fabricated super-hydrophobic and super-lipophilic functio...Nowadays, oil spills have led to a serious environmental crisis of the world. To deal with this problem, inspired from super-hydrophobic lotus leaf, this study fabricated super-hydrophobic and super-lipophilic functionalized graphene oxide/polyurethane (FGP) sponge by a simple and inexpensive dip coating method. The resulting FGP sponge was characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy and water contact angle. The results expressed that FGP sponge exhibited a similar surface structure to that of a lotus leaf, and possessed the super-hydrophobic characteristic with the water contact angle (WAC) of 152°± 1 °. The absorption capacity and reusability were also investigated. It can be seen that, the FGP sponge can remove a wide range of oils and organic solvents from water with good absorption capacities (up to 35 times of its own mass). Significantly, after 10 cycles the absorption capacity of the oils and organic solvents was higher than 90°; for the reused FGP sponge, demonstrating the good reusability of the FGP sponge. Therefore, this study probably provided a simole way to remove the pollutions ofoil spills and toxic organism from water.展开更多
In order to fulfil the microgravity requirements for space experiments, improved technology for the microgravity environment is proposed, including that for raising the orbital altitude, optimizing the layout of the d...In order to fulfil the microgravity requirements for space experiments, improved technology for the microgravity environment is proposed, including that for raising the orbital altitude, optimizing the layout of the disturbance source, using IN-thrusters instead of 5 N-thrusters, etc. In addition, evaluation of the microgravity environment of the recoverable satellite was also conducted using on-orbit micro-vibration measurement, on-orbit experiment and data analysis technologies. The microgravity level of the SJ-l0 recoverable satellite in China is compared with the spacecraft used for carrying out space science experiments internationally. This paper describes the microgravity environment of the SJ- 10 recoverable satellite, and its importance for analysing space experimental results.展开更多
Glycerol dialkyl glycerol tetraethers(GDGTs) in lake sediments are useful biomarkers for the continental paleoclimatic reconstruction. However, the environmental controls on the distribution of these compounds, in par...Glycerol dialkyl glycerol tetraethers(GDGTs) in lake sediments are useful biomarkers for the continental paleoclimatic reconstruction. However, the environmental controls on the distribution of these compounds, in particular the 6-methyl isomers of bacterial branched GDGTs(bGDGTs), in the lakes with contrasting pH, are still unknown, hindering their application for paleo-reconstructions. Here, we investigated the environmental impacts on the distribution of GDGTs in 17 alkaline lakes and 1 acid lake in China. It was found that the dissolved oxygen content in water column may have an impact on the distribution of archaeal isoprenoid GDGTs(iGDGTs) by causing the change in archaeal communities. The ratio of GDGT-0/crenarchaeol increases with decreasing oxygen content, indicating that the relative abundance of anaerobic methanogenic archaea or Miscellaneous Crenarchaeotic Group(MCG) vs. aerobic Thaumarchaeota is controlled by the oxygen content dissolved in water of these lakes. Thaumarchaeota are likely to contribute only a small proportion of iGDGTs in the relatively oxygen-depleted lakes, and thus TEX_(86) is not suitable for the reconstruction of the surface temperature of these lakes. The abundance ratio of iGDGTs to bGDGTs(R_(i/b)) appears to show no relationship with water pH in all the lakes, but exhibits a significant positive correlation with the water depth of the acid Lake Qinghai in Tengchong. As expected, the methylation degree of bGDGTs(MBT′) was found to correlate with both mean annual air temperature(MAT) and water pH, and the cyclization degree of bGDGTs(CBT) correlates only with water pH in these lakes. However, the MBT′_(5ME), an index to measure the methylation degree of 5-methyl bGDGTs, exhibits no relationship with MAT, whereas MBT′_(6ME), the methylation degree of 6-methyl bGDGTs, was found to correlate significantly with MAT. This is opposite to the situation observed in the global soils, pointing to a different adaptation of b GDGT-producing bacteria to environmental variables or different microbial sources of bGDGTs in these lakes. The relative abundance of 6- vs. 5-methyl bGDGTs is controlled by pH in these lakes, similar to that observed in worldwide soils. Hence, the isomer ratio(IR) of 6-methyl bGDGTs or CBT′ can be used as a proxy for water pH, although they might be influenced by other environmental factors including temperature in the lakes with a narrow range of pH.展开更多
基金Project supported by the National Key Basic Research Support Foundation of China (No.2004CB418503).
文摘Soil samples were collected from Zhangshi Wastewater Irrigation Area in the suburb of Shenyang City,China,an area with a 30-year irrigation history with heavy metal-containing wastewater.The chemical properties and microbial characteristics of the soils were examined to evaluate the present situation of heavy metal pollution and to assess the soil microbial characteristics under long-term heavy metal stress.In light of the National Environmental Quality Standards of China,the soil in the test area was heavily polluted by Cd and to a lesser degree by Zn and Cu,even though wastewater irrigation ceased in 1993.Soil metabolic quotient (qCO_2) had a significant positive correlation,while soil microbial quotient (qM) had a negative correlation with content of soil heavy metals.Soil microbial biomass carbon (MBC) had significantly negative correlation with Cd,but soil substrate-induced respiration (SIR),dehydrogenase activity (DHA),cellulase activity, and culturable microbial populations had no persistent correlations with soil heavy metal content.Soil nutrients,except for phosphorous,showed positive effects on soil microbial characteristics,which to a certain degree obscured the adverse effects of soil heavy metals.Soil Cd contributed more to the soil microbial characteristics,but qM and qCO_2 were more sensitive and showed persistent responses to heavy metals stress.It could be concluded that qM and qCO_2 can be used as bioindicators of heavy metal pollution in soils.
基金the National Natural Sciences Foundation of China (Nos40171054 and 40125005)the National Key Basic Research Support Foundation of China (No2002CB410809/10)
文摘Copper (Cu) mine tailings, because of their high content of heavy metals, are usually hostile to plant colonization. A pot experiment was conducted to determine the tolerance of four forage grasses to heavy metals in Cu mine tailings and to examine the variation in the microbial functional diversity of soils from the tailing sites in southern China. All the four grass species survived on Cu mine tailings and Cu mine tailing-soil mixture. However, on pure mine tailings, the growth was minimal, whereas the growth was maximum for the control without mine tailings. The tolerance of grasses to heavy metals followed the sequence: Paspalum notatum 〉 Festuea arundinaeea 〉 Lolium perenne 〉 Cynodon daetylon. The planting of forage grasses enhanced the soil microbial biomass. The Biolog data indicated that the soil microbial metabolic profile values (average well color development, community richness, and Shannon index) of the four forage grasses also followed the sequence: P. notatum 〉 F. arundinaeea 〉 L. perenne 〉 C. daetylon. Thus, P. notatum, under the experimental conditions of this study, may be considered as the preferred plant species for revegetation of Cu mine tailing areas.
基金Project supported by the National Natural Science Foundation of China (No. 40371056)the Foundation for the Author of NationalExcellent Doctoral Dissertation of China (No. 200149)
文摘Measurements of the magnetic properties and total contents of Cu, Cd, Pb and Fe in 30 automobile emission particulate samples indicated the presence of magnetic particles in them. The values of frequency dependent susceptibility (Xfd) showed the absence of superparamagnetic (SP) grains in the samples. The IRM20mT (isothermal remanent magnetization at 20 mT) being linearly proportional to SIRM (saturation isothermal remanent magnetization) (R^2=0.901), suggested that ferrimagnetic minerals were responsible for the magnetic properties of automobile emission particulates. The average contents of Cu, Cd, Pb and Fe in automobile emission particulates were 95.83, 22.14, 30.58 and 34727.31 mg/kg, respectively. Significant positive correlations exist between the magnetic parameters and the contents ofPb, Cu and Fe. The magnetic parameters of automobile emission particulates reflecting concentration of magnetic particles increased linearly with increase of Pb and Cu content, showed that the magnetic measurement could be used as a preliminary index for detection of Pb and Cu pollution.
基金supported by the Natural Science Foundation of China(No.51706190)the State Scholarship Fund of China Scholarship Council。
文摘Due to the paramagnetic property of liquid oxygen,the Kelvin force can be induced in liquid oxygen under non-uniform magnetic field.Based on the volume of fluid(VOF)model,the positioning effect of the force in liquid oxygen tanks is analyzed under various Bond numbers(Bo)and magnetic Bond numbers(Bom).The results show that the magnetic field has the effect of repositioning the liquid oxygen in the tank when the gravity field is not enough or absent.Additionally,the gas-liquid interface has a periodic fluctuation during the process due to the inhomogeneous Kelvin force distribution,and more effective suppression of fluctuation can be achieved under the condition of a larger Bom.The new method of controlling gas-liquid interface of liquid oxygen tank under micro gravity condition is hoped to be developed in the future.
基金Supported by the National Natural Science Foundation of China(21776319)
文摘Nowadays, oil spills have led to a serious environmental crisis of the world. To deal with this problem, inspired from super-hydrophobic lotus leaf, this study fabricated super-hydrophobic and super-lipophilic functionalized graphene oxide/polyurethane (FGP) sponge by a simple and inexpensive dip coating method. The resulting FGP sponge was characterized by infrared spectroscopy, X-ray diffraction, scanning electron microscopy and water contact angle. The results expressed that FGP sponge exhibited a similar surface structure to that of a lotus leaf, and possessed the super-hydrophobic characteristic with the water contact angle (WAC) of 152°± 1 °. The absorption capacity and reusability were also investigated. It can be seen that, the FGP sponge can remove a wide range of oils and organic solvents from water with good absorption capacities (up to 35 times of its own mass). Significantly, after 10 cycles the absorption capacity of the oils and organic solvents was higher than 90°; for the reused FGP sponge, demonstrating the good reusability of the FGP sponge. Therefore, this study probably provided a simole way to remove the pollutions ofoil spills and toxic organism from water.
文摘In order to fulfil the microgravity requirements for space experiments, improved technology for the microgravity environment is proposed, including that for raising the orbital altitude, optimizing the layout of the disturbance source, using IN-thrusters instead of 5 N-thrusters, etc. In addition, evaluation of the microgravity environment of the recoverable satellite was also conducted using on-orbit micro-vibration measurement, on-orbit experiment and data analysis technologies. The microgravity level of the SJ-l0 recoverable satellite in China is compared with the spacecraft used for carrying out space science experiments internationally. This paper describes the microgravity environment of the SJ- 10 recoverable satellite, and its importance for analysing space experimental results.
基金supported by the Fundamental Research Funds for the Central Universities (Grant No. CUGL150812)the National Natural Science Foundation of China (Grant No. 41330103)the Programme of Introducing Talents of Discipline to Universities Project (Grant No. B08030)
文摘Glycerol dialkyl glycerol tetraethers(GDGTs) in lake sediments are useful biomarkers for the continental paleoclimatic reconstruction. However, the environmental controls on the distribution of these compounds, in particular the 6-methyl isomers of bacterial branched GDGTs(bGDGTs), in the lakes with contrasting pH, are still unknown, hindering their application for paleo-reconstructions. Here, we investigated the environmental impacts on the distribution of GDGTs in 17 alkaline lakes and 1 acid lake in China. It was found that the dissolved oxygen content in water column may have an impact on the distribution of archaeal isoprenoid GDGTs(iGDGTs) by causing the change in archaeal communities. The ratio of GDGT-0/crenarchaeol increases with decreasing oxygen content, indicating that the relative abundance of anaerobic methanogenic archaea or Miscellaneous Crenarchaeotic Group(MCG) vs. aerobic Thaumarchaeota is controlled by the oxygen content dissolved in water of these lakes. Thaumarchaeota are likely to contribute only a small proportion of iGDGTs in the relatively oxygen-depleted lakes, and thus TEX_(86) is not suitable for the reconstruction of the surface temperature of these lakes. The abundance ratio of iGDGTs to bGDGTs(R_(i/b)) appears to show no relationship with water pH in all the lakes, but exhibits a significant positive correlation with the water depth of the acid Lake Qinghai in Tengchong. As expected, the methylation degree of bGDGTs(MBT′) was found to correlate with both mean annual air temperature(MAT) and water pH, and the cyclization degree of bGDGTs(CBT) correlates only with water pH in these lakes. However, the MBT′_(5ME), an index to measure the methylation degree of 5-methyl bGDGTs, exhibits no relationship with MAT, whereas MBT′_(6ME), the methylation degree of 6-methyl bGDGTs, was found to correlate significantly with MAT. This is opposite to the situation observed in the global soils, pointing to a different adaptation of b GDGT-producing bacteria to environmental variables or different microbial sources of bGDGTs in these lakes. The relative abundance of 6- vs. 5-methyl bGDGTs is controlled by pH in these lakes, similar to that observed in worldwide soils. Hence, the isomer ratio(IR) of 6-methyl bGDGTs or CBT′ can be used as a proxy for water pH, although they might be influenced by other environmental factors including temperature in the lakes with a narrow range of pH.