The morphologies, sizes, compositions and volume fractions of dendritic phases in in situ Ti-based metallic glass matrix composites (MGMCs) containing beryllium (Be) with the nominal composition of Tia7Zr19Cu5V12B...The morphologies, sizes, compositions and volume fractions of dendritic phases in in situ Ti-based metallic glass matrix composites (MGMCs) containing beryllium (Be) with the nominal composition of Tia7Zr19Cu5V12Be17 (mole fraction, %) were investigated using XRD, SEM, EBSD, TEM, EDS and three-dimensional reconstruction method. Moreover, visualized at the nanoscale, Be distribution is confirmed to be only present in the matrix using scanning transmission electron microscopy-electron energy loss spectroscopy (STEM-EELS). Based on these findings, it has been obtained that the accurate chemical compositions are Wi28.3Zr19.7Cu8V6.4Be37.6 (mole fraction, %) for glass matrix and Wi62.nZr18.aCu2.6V16.6 (mole fraction, %) for the dendritic phases, and the volume fractions are 38.5% and 61.5%, respectively. It is believed that the results are of particular importance for the designing of Be-containing MGMCs.展开更多
Concentrations of rare earth elements (REE) in Jurassic coal of YanAn Formation from Dongsheng coalfield located in the northeast of Ordos basin were determined by instrumental neutron activation analysis (INAA). Curv...Concentrations of rare earth elements (REE) in Jurassic coal of YanAn Formation from Dongsheng coalfield located in the northeast of Ordos basin were determined by instrumental neutron activation analysis (INAA). Curves of distribution pattern of REE were drawn, and many geochemical parameters were calculated. The result shows that 1) The contents of REE in Jurassic coal with low ash and sulfur are lower than those of Carboniferous and Permian coal from the Basin of North China; 2) Inside the Dongsheng coalfield, coal from the north has higher contents of REE than that form the south because the north is near the area of source rock which is the main supplier of REE, while the south is far away from the area of source rocks; 3) Although Jurassic coal in Dongsheng is the low ash coal with less than 10%, the contents of REE are still proportional to ash yield of ash and SiO 2 contents. 4) Although the Jurassic coal in Dongsheng were deposited in oxidative continental environment of river lake, Eu depletion of REE in coal commonly exists, and positive abnormity of Ce dose not exist. This reflects the REE distribution pattern of REE in source rock of continental area; and 5) Compared with other rocks, coal shows extremely complexity of distribution pattern of REE, which is the result of continuous alteration and redistribution of matter in coal occurred in open basin system.展开更多
A rhizobox system was used to determine the distribution of micronutrients (Fe, Mn, Cu and Zn) acrossthe rhmosphere of wheat (Triticum aestivum). The available contents of Fe and Mn in the rhizosphere wereraised by ad...A rhizobox system was used to determine the distribution of micronutrients (Fe, Mn, Cu and Zn) acrossthe rhmosphere of wheat (Triticum aestivum). The available contents of Fe and Mn in the rhizosphere wereraised by addition of manure or chemical fertilizer combined with manure, but those of Cu and Zn werehardly affected, which might be an important reason why manure addition could improve the Fe and Mnnutrition status of plants. Several possible mechanisms for the increase of the availabilities of Fe and Mn inthe rhizosphere due to manuring are discussed as well.展开更多
The concentration distribution of essential and non-essential micro-elements of the tissues of healthy organisms shows significant difference. This fact can be used for clarification of the biological role of hardly k...The concentration distribution of essential and non-essential micro-elements of the tissues of healthy organisms shows significant difference. This fact can be used for clarification of the biological role of hardly known trace elements, as well, proving the essential or non-essential character. In case of essential elements the concentration range is rather narrow, the distribution is normal. In case of non-essential elements the interval is wide, the concentration-distribution is log-normal. Measurements and mathematical calculations were carried out for determination of the concentrations and concentration-distributions of some micro-elements, trying to clarify the essentiality or non-essential character of the investigated elements from point of view of plant physiology. Based on the measurements for radish Li and Ni seem to be non-essential trace elements, however in case of Sr the distribution curve suggests an essential character, because the concentration range is not wide.展开更多
基金Project(11374028)supported by the National Natural Science Foundation of ChinaProject supported by the Cheung Kong Scholars Program of China
文摘The morphologies, sizes, compositions and volume fractions of dendritic phases in in situ Ti-based metallic glass matrix composites (MGMCs) containing beryllium (Be) with the nominal composition of Tia7Zr19Cu5V12Be17 (mole fraction, %) were investigated using XRD, SEM, EBSD, TEM, EDS and three-dimensional reconstruction method. Moreover, visualized at the nanoscale, Be distribution is confirmed to be only present in the matrix using scanning transmission electron microscopy-electron energy loss spectroscopy (STEM-EELS). Based on these findings, it has been obtained that the accurate chemical compositions are Wi28.3Zr19.7Cu8V6.4Be37.6 (mole fraction, %) for glass matrix and Wi62.nZr18.aCu2.6V16.6 (mole fraction, %) for the dendritic phases, and the volume fractions are 38.5% and 61.5%, respectively. It is believed that the results are of particular importance for the designing of Be-containing MGMCs.
文摘Concentrations of rare earth elements (REE) in Jurassic coal of YanAn Formation from Dongsheng coalfield located in the northeast of Ordos basin were determined by instrumental neutron activation analysis (INAA). Curves of distribution pattern of REE were drawn, and many geochemical parameters were calculated. The result shows that 1) The contents of REE in Jurassic coal with low ash and sulfur are lower than those of Carboniferous and Permian coal from the Basin of North China; 2) Inside the Dongsheng coalfield, coal from the north has higher contents of REE than that form the south because the north is near the area of source rock which is the main supplier of REE, while the south is far away from the area of source rocks; 3) Although Jurassic coal in Dongsheng is the low ash coal with less than 10%, the contents of REE are still proportional to ash yield of ash and SiO 2 contents. 4) Although the Jurassic coal in Dongsheng were deposited in oxidative continental environment of river lake, Eu depletion of REE in coal commonly exists, and positive abnormity of Ce dose not exist. This reflects the REE distribution pattern of REE in source rock of continental area; and 5) Compared with other rocks, coal shows extremely complexity of distribution pattern of REE, which is the result of continuous alteration and redistribution of matter in coal occurred in open basin system.
文摘A rhizobox system was used to determine the distribution of micronutrients (Fe, Mn, Cu and Zn) acrossthe rhmosphere of wheat (Triticum aestivum). The available contents of Fe and Mn in the rhizosphere wereraised by addition of manure or chemical fertilizer combined with manure, but those of Cu and Zn werehardly affected, which might be an important reason why manure addition could improve the Fe and Mnnutrition status of plants. Several possible mechanisms for the increase of the availabilities of Fe and Mn inthe rhizosphere due to manuring are discussed as well.
文摘The concentration distribution of essential and non-essential micro-elements of the tissues of healthy organisms shows significant difference. This fact can be used for clarification of the biological role of hardly known trace elements, as well, proving the essential or non-essential character. In case of essential elements the concentration range is rather narrow, the distribution is normal. In case of non-essential elements the interval is wide, the concentration-distribution is log-normal. Measurements and mathematical calculations were carried out for determination of the concentrations and concentration-distributions of some micro-elements, trying to clarify the essentiality or non-essential character of the investigated elements from point of view of plant physiology. Based on the measurements for radish Li and Ni seem to be non-essential trace elements, however in case of Sr the distribution curve suggests an essential character, because the concentration range is not wide.