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微量反应系统化学动力学教学实验的设计与应用 被引量:2
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作者 周丹娜 袁亚男 《化学教育》 CAS 北大核心 2016年第12期18-21,共4页
利用光纤光谱仪构建微量反应系统,并通过偶氮染料橙黄II在铁-亚硫酸钠-溶解氧体系中的脱色反应,分别用特征动力学方程法及初始速率法进行了脱色反应动力学分析。该实验体系能够实现简单、快速的均相溶液反应动力学实验,其数据处理方法... 利用光纤光谱仪构建微量反应系统,并通过偶氮染料橙黄II在铁-亚硫酸钠-溶解氧体系中的脱色反应,分别用特征动力学方程法及初始速率法进行了脱色反应动力学分析。该实验体系能够实现简单、快速的均相溶液反应动力学实验,其数据处理方法较好地巩固和提升了对反应动力学理论课教学内容的学习。整个实验体系的设计与应用能够满足物理化学、大学化学、环境化学等相关课程中有关反应动力学的实验教学需求。 展开更多
关键词 反应动力学 初始速率法 积分法 微量反应系统 特征动力学方程
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Optimal design for split-and-recombine-type flow distributors of microreactors based on blockage detection 被引量:2
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作者 Lin Wang Xianzuo Kong Yongsheng Qi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第7期897-903,共7页
In order to increase the productivity of microreactors, the parallelization of the microreactors is required. The performances of flow distributors can affect the product yield and fault detection ability when blockag... In order to increase the productivity of microreactors, the parallelization of the microreactors is required. The performances of flow distributors can affect the product yield and fault detection ability when blockage happens.In this research, an optimal design method to calculate the channel diameters and to determine the flow sensor location is derived based on mass balance and pressure balance models of split-and-recombine-type flow distributors(SRFDs). The model accuracy is verified by experiment data. The proposed method is applied to optimal design of SRFDs under constant flow rate operation conditions. The maximum angle difference between normal and blockage conditions at one sensor to those at the other sensors is set to be the objective function and the uniformity of flow distribution in microreactors under normal condition is also required. The diameters of each pipe in SRFDs are selected as the design variables. Simulated annealing algorithm is used to solve the optimization problem. The effectiveness of the optimal design results is demonstrated by fluid dynamics simulations. The results show that using the optimal channel diameters of SRFDs, the pressure drop in SRFD section is lower than that of the microreactor section. Meanwhile, in the case studies, only a few sensors that are located inside the SRFDs can easily detect the blockage abnormal condition in the parallelized microreactor system. 展开更多
关键词 Optimal designSplit-and-recombine-type flow distributorsMicroreactorsMicrochannelsBlockage
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