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元素分析-同位素质谱联用测定微量氮元素同位素方法研究 被引量:3
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作者 尹希杰 刘维维 +2 位作者 王永涛 苏静 李廷伟 《质谱学报》 EI CAS CSCD 北大核心 2021年第3期346-352,I0006,共8页
在保证仪器正常出峰的情况下,缩小元素分析仪氧化管、还原管的管径,优化色谱柱条件,降低载气流速,进而减小载气对进入质谱仪的N 2稀释比,降低元素分析-同位素质谱(EA-IRMS)测试固体样品中氮同位素的检出限。结果表明,优化前元素分析仪... 在保证仪器正常出峰的情况下,缩小元素分析仪氧化管、还原管的管径,优化色谱柱条件,降低载气流速,进而减小载气对进入质谱仪的N 2稀释比,降低元素分析-同位素质谱(EA-IRMS)测试固体样品中氮同位素的检出限。结果表明,优化前元素分析仪载气流速为80 mL/min,大约20μg氮元素在质谱检测器产生的峰面积约3×10^(-8),δ^(15) N值标准偏差为0.13‰(n=6);优化后载气流速降至20 mL/min,大约4μg氮元素产生的峰面积达到约2×10^(-8),其δ^(15) N值标准偏差为0.18‰(n=6),满足仪器测试氮同位素的标准偏差须小于0.2‰的要求。 展开更多
关键词 元素分析-同位素质谱(EA-IRMS) 微量氮元素 优化
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The rhizosphere pH change of Pinus koraiensis seedlings as affected by N sources of different levels and its effect on the availability and uptake of Fe, Mn, Cu and Zn
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作者 陈永亮 韩士杰 +1 位作者 周玉梅 程国玲 《Journal of Forestry Research》 SCIE CAS CSCD 2002年第1期37-40,83,共4页
Dark brown forest soil was collected from the upper 20 cm soil layer in Changbai Mountain Research Station of Ecosystem, Chinese Academy of Sciences. The soil was amended with two different forms of nitrogen fertilize... Dark brown forest soil was collected from the upper 20 cm soil layer in Changbai Mountain Research Station of Ecosystem, Chinese Academy of Sciences. The soil was amended with two different forms of nitrogen fertilizers: NO3- as Ca(NO3)2, NH4+ as NH4Cl at the concentrations of 50, 100, 200 and 400 mgkg-1 respectively. The experiment was carried out with 2-yr-old Pinus koraiensis seedlings in pot. The pH change of rhizosphere soil and the contents of available Fe, Mn, Cu, and Zn in soil and leaves were analyzed. The result indicated that the addition of NH4--N decreased the rhizosphere pH value, while the addition of NO3--N increased the rhizosphere pH value in contrast with the control treatment. The direction and extent of the pH change mainly depended on N source and its concentrations applied. The rhizosphere pH change had a remarkable influence on the availability of the micronutrients in the rhizosphere, and thereafter affected the nutrient uptake by the seedlings. The contents of available mineral nutrients had a negative correlation with the pH value in the rhizosphere soil. The contents of available mineral nutrients in leaves were positively correlated to the levels of the available nutrients in the rhizosphere soils. 展开更多
关键词 Rhizosphere pH N sources MICRONUTRIENT AVAILABILITY UPTAKE
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Impact of Silicon,Zinc,Boron Combined with Reduced Nitrogen Fertilization on Rice Growth 被引量:2
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作者 庄光泉 郭红艳 +3 位作者 杨利 袁迎春 赵妍 童军 《Agricultural Science & Technology》 CAS 2016年第7期1618-1620,共3页
Under the condition of reduced application of nitrogen fertilizer, the impact of silicor), zinc and boron on rice growth was investigated by field experiment. The results showed that when the application amount of ni... Under the condition of reduced application of nitrogen fertilizer, the impact of silicor), zinc and boron on rice growth was investigated by field experiment. The results showed that when the application amount of nitrogen fertilizer was reduced by 20%, the application of silicon, zinc and boron did not reduce the yield of rice, but reduced the incidence of panicle blast in rice and optimized the structure of rice production. 展开更多
关键词 Rice Reducing nitrogen fertilization Secondary and trace elements Jianghan Plain
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Soil Inorganic Nitrogen and Microbial Biomass Carbon and Nitrogen Under Pine Plantations in Zhanggutai Sandy Soil 被引量:7
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作者 YU Zhan-Yuan CHEN Fu-Sheng +2 位作者 ZENG De-Hui ZHAO Qiong CHEN Guang-Sheng 《Pedosphere》 SCIE CAS CSCD 2008年第6期775-784,共10页
The dynamics of soil inorganic nitrogen (NH4^+ -N and NO3^- -N) and microbial biomass carbon (Cmic) and nitrogen (Nmic) under 30-year-old fenced Pinus sylvestris L. var. mongolica Litvin (SF), unfenced P. syl... The dynamics of soil inorganic nitrogen (NH4^+ -N and NO3^- -N) and microbial biomass carbon (Cmic) and nitrogen (Nmic) under 30-year-old fenced Pinus sylvestris L. var. mongolica Litvin (SF), unfenced P. sylvestris L. var. mongolica Litvin (SUF), and unfenced Pinus densiflora Siebold et Zucc. (DUF) plantations in the Zhanggutai sandy soil of China were studied during Apr. to Oct. 2004 by the in situ closed-top core incubation method. All mentioned C and N indices in each stand type fluctuated over time. The ranges of inorganic N, Cmic, and Nmic contents in the three stand types were 0.7-2.6, 40.0-128.9, and 5.4-15.2 μg g^-1, respectively. The average contents of soil NH4^+ -N and Cmic under the three 30-year-old pine plantations were not different. However, soil NO3^ -N and total inorganic N contents decreased in the order of SUF ≥ SF ≥ DUF, the Nmic content was in the order of SF = SUF 〉 DUF, and the Cmic:Nmic ratio was in the order of SUF = DUF 〉 SF. Seasonal variations were observed in soil inorganic N, microbial biomass, and plant growth. These seasonal variations had certain correlations with microbe and plant N use in the soil, and their competition for NH4^+ -N was mostly regulated by soil N availability. The influence of tree species on inorganic N and Nmic were mainly because of differences in litter quality. Lack of gazing decreased the Cmic:Nmic ratio owing to decreased carbon output and increased the ability of soil to supply N. The soil N supply under the P. sylvestris var. mongolica plantation was lower than under the P. densiflora plantation. 展开更多
关键词 ecosystem management Horqin sandy land soil nitrogen availability Pinus densiflora Pinus sylvestris vat. mongoliea
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新型无机磷源的发展趋势
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作者 李霞 万荣 《饲料广角》 2014年第4期25-26,共2页
本文综述了磷酸氢钙Ⅲ型、磷酸一铵和多组分复合磷酸盐等新型无机磷源产品的特点以及在畜禽上的使用效果,为饲料中无机磷源的开发和高效利用提供参考依据。
关键词 磷酸氢钙Ⅲ型 磷酸一铵 复合磷酸盐 鸡目前 降低养殖业污染物排放和非再生资源的使用是当今畜禽营养和养殖的发展方向.在过去的几十年间 已采取多种方法来降低环境中、磷和微量元素等的养殖污染 以降低土地和地表水污染.改善空气质量等.对于磷等非再生资源 储量有限 因此更应该提高其利用效率 降低排放.
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