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微陶材料对铀的吸附特性 被引量:2
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作者 朱锐之 李力力 +2 位作者 朱留超 赵立飞 赵永刚 《核化学与放射化学》 CSCD 北大核心 2017年第5期377-384,共8页
采用多种方法对微陶材料进行了表征,分别采用静态法和动态法研究了溶液pH、吸附时间、铀初始浓度、吸附剂用量、解吸流速、吸附剂粒度等因素对微陶材料吸附铀的影响;探究了微陶材料对模拟放射性废水的处理能力。实验结果表明,扫描电镜... 采用多种方法对微陶材料进行了表征,分别采用静态法和动态法研究了溶液pH、吸附时间、铀初始浓度、吸附剂用量、解吸流速、吸附剂粒度等因素对微陶材料吸附铀的影响;探究了微陶材料对模拟放射性废水的处理能力。实验结果表明,扫描电镜显示微陶材料底部为层状结构,能谱显示其表面主要成分为铝元素,还有少量(质量分数6.00%)的铁元素;XRD结果显示微陶材料表面无明显Fe的衍射峰;红外光谱显示微陶材料对铀进行了吸附;当pH=5、吸附时间为1h、铀初始质量浓度为100μg/L、微陶材料用量为50mg时,微陶材料对铀的吸附率达到95%以上;动态法中流速和粒度对吸附影响较小;微陶材料对铀的吸附等温线符合Freundlich吸附等温模型;采用准二级反应动力学模型描述微陶材料对铀的吸附,吸附过程主要为化学吸附;微陶材料对模拟放射性废水中铀的吸附率均在90%以上,对锶、铯也有一定的吸附能力。 展开更多
关键词 微陶材料 吸附性能 放射性废水
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Antibacterial activities and corrosion behavior of novel PEO/nanostructured ZrO_2 coating on Mg alloy 被引量:13
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作者 Mohammadreza DAROONPARVAR Muhamad Azizi MAT YAJID +4 位作者 Rajeev KUMAR GUPTA Noordin MOHD YUSOF Hamid Reza BAKHSHESHI-RAD Hamidreza GHANDVAR Ehsan GHASEMI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第8期1571-1581,共11页
Plasma electrolytic oxidation(PEO) was developed as a bond coat for air plasma sprayed(APS) nanostructure ZrO2 as top coat to enhance the corrosion resistance and antibacterial activity of Mg alloy. Corrosion beha... Plasma electrolytic oxidation(PEO) was developed as a bond coat for air plasma sprayed(APS) nanostructure ZrO2 as top coat to enhance the corrosion resistance and antibacterial activity of Mg alloy. Corrosion behavior and antibacterial activities of coated and uncoated samples were assessed by electrochemical tests and agar diffusion method toward Escherichia coli(E. coli) bacterial pathogens, respectively. The lowest corrosion current density and the highest charge transfer resistance, phase angle and impedance modulus were observed for PEO/nano-ZrO2 coated sample compared with those of PEO coated and bare Mg alloys. Nano-ZrO2 top coat which has completely sealed PEO bond coat is able to considerably delay aggressive ions transportation towards Mg alloy surface and significantly enhances corrosion resistance of Mg alloy in simulated body fluid(SBF) solution. Moreover, higher antibacterial activity was also observed in PEO/nano-ZrO2 coating against bacterial strains than that of the PEO coated and bare Mg alloys. This observation was attributed to the presence of ZrO2 nanoparticles which decelerate E. coli growth as a result of E. coli membranes. 展开更多
关键词 Mg alloy CERAMICS coating materials microstructure scanning electron microscopy (SEM)
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Microstructure and frictional properties of 3D needled C/SiC brake materials modified with graphite 被引量:3
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作者 张建新 范尚武 +3 位作者 张立同 成来飞 杨尚杰 田广来 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第12期2289-2293,共5页
The 3D needled C/SiC brake materials modified with graphite were prepared by a combined process of the chemical vapor infiltration,slurry infiltration and liquid silicon infiltration process.The microstructure and fri... The 3D needled C/SiC brake materials modified with graphite were prepared by a combined process of the chemical vapor infiltration,slurry infiltration and liquid silicon infiltration process.The microstructure and frictional properties of the brake materials were investigated.The density and open porosity of the materials as-received were about(2.1±0.1)g/cm3and(5±1)%,respectively.The brake materials were composed of 59%C,39%SiC,and 2%Si(mass fraction).The content of Si in the C/SiC brake materials modified with graphite was far less than that in the C/SiC brake materials without being modified with graphite,and the Si was dispersed.The braking curve of the 3D needled C/SiC modified with graphite was smooth,which can ensure the smooth and comfortable braking.The frictional properties under wet condition of the 3D needled C/SiC modified with graphite showed no fading.And the linear wear rate of the C/SiC modified with graphite was lower than that of the C/SiC unmodified. 展开更多
关键词 3D needled C/SiC brake material MICROSTRUCTURE frictional properties
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Structural characteristics and dielectric properties of glass-ceramic nanocomposites of(Pb,Sr)Nb_2O_6-NaNbO_3-SiO_2 被引量:3
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作者 王磊 张庆猛 杜军 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第8期1434-1438,共5页
The structure and dielectric properties of (Pb,Sr)Nb2O6-NaNbO3-SiO2 glass-ceramics with different Pb and Sr contents were investigated. The XRD pattern of glass-ceramics without Sr substitution is different from tha... The structure and dielectric properties of (Pb,Sr)Nb2O6-NaNbO3-SiO2 glass-ceramics with different Pb and Sr contents were investigated. The XRD pattern of glass-ceramics without Sr substitution is different from that with Sr substitution, which indicates the existence of orthorhombic phase in the latter ones. TEM bright field observation shows nanosized microstructures, while for samples with Sr, typical eutectic microstrncture with separated crystallized bands is found in the glass matrix. Dielectric properties measurement of the samples indicates an obvious improvement of dielectric constant, dielectric loss, DC field and temperature dependence of dielectric constant when the molar ratio of Sr to Pb is 4:6. 展开更多
关键词 dielectric properties NANOCOMPOSITE (Pb Sr)Nb2O6 NaNbO3 GLASS-CERAMICS
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