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利用快分子离子与固体的相互作用对H_2^+,HD^+和D_2^+结构的研究 被引量:1
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作者 朱洲森 缪竟威 师勉恭 《原子与分子物理学报》 CAS CSCD 北大核心 2005年第3期563-567,共5页
利用快分子离子与固体的相互作用,依靠一套高分辨装置,测量了H2+,HD+和D2+的结构,得到其核间距分别为1·19±0·003nm、1·25±0·003nm和1·32±0·003nm。通过对比,证实了分子离子结构中同位素... 利用快分子离子与固体的相互作用,依靠一套高分辨装置,测量了H2+,HD+和D2+的结构,得到其核间距分别为1·19±0·003nm、1·25±0·003nm和1·32±0·003nm。通过对比,证实了分子离子结构中同位素效应的存在,分析了实验值和理论值存在差别的原因,讨论了实验结果中同位素效应产生的缘由。 展开更多
关键词 快分子离子 同住素效应 尾流效应 库仑爆炸
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Probing Molecular Dynamics with Ultrafast Electron Diffraction
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作者 Zhuo-ran Ma Feng-feng Qi Dao Xiang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2021年第1期15-29,I0011,共16页
Recent progress in ultrafast lasers,ultrafast X-rays and ultrafast electron beams has made it possible to watch the motion of atoms in real time through pumpprobe technique.In this review,we focus on how the molecular... Recent progress in ultrafast lasers,ultrafast X-rays and ultrafast electron beams has made it possible to watch the motion of atoms in real time through pumpprobe technique.In this review,we focus on how the molecular dynamics can be studied with ultrafast electron diffraction where the dynamics is initiated by a pumping laser and then probed by pulsed electron beams.This technique allows one to track the molecular dynamics with femtosecond time resolution and Angstr6m spatial resolution.We present the basic physics and latest development of this technique.Representative applications of ultrafast electron diffraction in studies of laser-induced molecular dynamics are also discussed.This table-top technique is complementary to X-ray free-electron laser and we expect it to have a strong impact in studies of chemical dynamics. 展开更多
关键词 Ultrafast electron diffraction Gas phase PHOTOCHEMISTRY Molecular dynamics PUMP-PROBE
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