Based on the location of bromine substituents and conjugation matrix, a new substituent po- sition index ~X not only was defined, but also molecular shape indexes Km and electronega- tivity distance vectors Mm of diph...Based on the location of bromine substituents and conjugation matrix, a new substituent po- sition index ~X not only was defined, but also molecular shape indexes Km and electronega- tivity distance vectors Mm of diphenylamine and 209 kinds of polybrominated diphenylamine （PBDPA） molecules were calculated. Then the quantitative structure-property relationships （QSPR） among the thermodynamic properties of 210 organic pollutants and 0X, K3, M29, M36 were founded by Leaps-and-Bounds regression. Using the four structural parameters as input neurons of the artificial neural network, three satisfactory QSPR models with network structures of 4：21：1, 4：24：1, and 4：24：1 respectively, were achieved by the back-propagation algorithm. The total correlation coefficients R were 0.9999, 0.9997, and 0.9995 respectively and the standard errors S were 1.036, 1.469, and 1.510 respectively. The relative mean deviation between the predicted value and the experimental value of Sθ, AfHe and △fGθ- were 0.11%, 0.34% and 0.24% respectively, which indicated that the QSPR models had good stability and superior predictive ability. The results showed that there were good nonlinear correlations between the thermodynamic properties of PBDPAs and the four structural pa- rameters. Thus, it was concluded that the ANN models established by the new substituent position index were fully applicable to predict properties of PBDPAs.展开更多
Wireless mesh network （WMN） is a new multi-hop network for broadband accessing to intemet. However, there exists a server unfairness problem based on different hop distances in WMN. To solve this problem, the unfair...Wireless mesh network （WMN） is a new multi-hop network for broadband accessing to intemet. However, there exists a server unfairness problem based on different hop distances in WMN. To solve this problem, the unfairness issue was analyzed in test-bed experiment and NS2 simulation. A dynamic queue management scheme E-QMMN was proposed, which allocates the queue buffer according to the hop distance of every flow. The experimental results show that the proposed scheme can not only increase the hop distance fairness of the legacy scheme at most 50%, but also reduce the average round trip time at least 29% in congested WMN environments.展开更多
Whereas a rich literature exists for estimating population genetic divergence, metrics of phenotypic trait divergence are lacking, particularly for comparing multiple traits among three or more populations. Here, we r...Whereas a rich literature exists for estimating population genetic divergence, metrics of phenotypic trait divergence are lacking, particularly for comparing multiple traits among three or more populations. Here, we review and analyze via simula- tion Hedges＇ g, a widely used parametric estimate of effect size. Our analyses indicate that g is sensitive to a combination of unequal trait variances and unequal sample sizes among populations and to changes in the scale of measurement. We then go on to derive and explain a new, non-parametric distance measure, ＇Aft＇, which is caiculated based upon a joint cumulative distribution function （CDF） from all populations under study. More precisely, distances are measured in terms of the percentiles in this CDF at which each population＇s median lies. Ap combines many desirable features of other distance metrics into a single metric; namely, compared to other metrics, p is relatively insensitive to unequal variances and sample sizes among the populations sam- pied. Furthermore, a key feature of Ap--and our main motivation for developing it--is that it easily accommodates simultaneous comparisons of any number of traits across any number of populations. To exemplify its utility, we employ Ap to address a ques- tion related to the role of sexual selection in speciation： are sexual signals more divergent than ecological traits in closely related taxa？ Using traits of known function in closely related populations, we show that traits predictive of reproductive performance are indeed, more divergent and more sexually dimorphic than traits related to ecological adaptation [Current Zoology 58 （3）： 426-439 2012].展开更多
文摘Based on the location of bromine substituents and conjugation matrix, a new substituent po- sition index ~X not only was defined, but also molecular shape indexes Km and electronega- tivity distance vectors Mm of diphenylamine and 209 kinds of polybrominated diphenylamine （PBDPA） molecules were calculated. Then the quantitative structure-property relationships （QSPR） among the thermodynamic properties of 210 organic pollutants and 0X, K3, M29, M36 were founded by Leaps-and-Bounds regression. Using the four structural parameters as input neurons of the artificial neural network, three satisfactory QSPR models with network structures of 4：21：1, 4：24：1, and 4：24：1 respectively, were achieved by the back-propagation algorithm. The total correlation coefficients R were 0.9999, 0.9997, and 0.9995 respectively and the standard errors S were 1.036, 1.469, and 1.510 respectively. The relative mean deviation between the predicted value and the experimental value of Sθ, AfHe and △fGθ- were 0.11%, 0.34% and 0.24% respectively, which indicated that the QSPR models had good stability and superior predictive ability. The results showed that there were good nonlinear correlations between the thermodynamic properties of PBDPAs and the four structural pa- rameters. Thus, it was concluded that the ANN models established by the new substituent position index were fully applicable to predict properties of PBDPAs.
基金Projects(61163060,61103204,60963022) supported by the National Natural Science Foundation of ChinaProject(D018023) supported by the Natural Science Foundation of Guangxi Province,ChinaPostdoctoral Funding of Central South University,China
文摘Wireless mesh network （WMN） is a new multi-hop network for broadband accessing to intemet. However, there exists a server unfairness problem based on different hop distances in WMN. To solve this problem, the unfairness issue was analyzed in test-bed experiment and NS2 simulation. A dynamic queue management scheme E-QMMN was proposed, which allocates the queue buffer according to the hop distance of every flow. The experimental results show that the proposed scheme can not only increase the hop distance fairness of the legacy scheme at most 50%, but also reduce the average round trip time at least 29% in congested WMN environments.
基金Acknowlegements We thank Matthew Arnegard, Carlos Botero, Tamra Mendelson, Rafael Rodriqu6z and Sander van Doom for excellent discussions about the need for a new phenotypic distance metric and Maria Servedio for the invitation and encouragement to formalize our ideas. This research was supported as part of the Sexual Selection and Speciation working group by the National Evolutionary Synthesis Center （NESCent）, NSF #EF-0905606. RJS and SMF were supported by the University of Colorado and National Science Founda- tion grant IOS-0717421to RJS. MK was supported by a grant from the Vienna Science and Technology Fund （WWTF） to the Mathematics and Biosciences Group at the University of Vienna. EAH thanks Mitch Bern for use of his Master＇s thesis data and was supported by the National Science Foundation grant lOS - 0643179. DEI and DPLT were supported by the Natural Sciences and Engineering Research Council of Can- ada （Discovery Grants 311931-2005 and 311931-2010 to DEI, CGS-D to DPLT）. NS and JAT were supported by the Royal Society, British Ecological Society and John Fell Fund （Ox- ford University）. ES supported by NSF-DDIG the American Ornithologists Union, the University of Chicago, and the American Philosophical Society Lewis and Clark award. JACU was funded by National Science Foundation grant lOS 0306175.
文摘Whereas a rich literature exists for estimating population genetic divergence, metrics of phenotypic trait divergence are lacking, particularly for comparing multiple traits among three or more populations. Here, we review and analyze via simula- tion Hedges＇ g, a widely used parametric estimate of effect size. Our analyses indicate that g is sensitive to a combination of unequal trait variances and unequal sample sizes among populations and to changes in the scale of measurement. We then go on to derive and explain a new, non-parametric distance measure, ＇Aft＇, which is caiculated based upon a joint cumulative distribution function （CDF） from all populations under study. More precisely, distances are measured in terms of the percentiles in this CDF at which each population＇s median lies. Ap combines many desirable features of other distance metrics into a single metric; namely, compared to other metrics, p is relatively insensitive to unequal variances and sample sizes among the populations sam- pied. Furthermore, a key feature of Ap--and our main motivation for developing it--is that it easily accommodates simultaneous comparisons of any number of traits across any number of populations. To exemplify its utility, we employ Ap to address a ques- tion related to the role of sexual selection in speciation： are sexual signals more divergent than ecological traits in closely related taxa？ Using traits of known function in closely related populations, we show that traits predictive of reproductive performance are indeed, more divergent and more sexually dimorphic than traits related to ecological adaptation [Current Zoology 58 （3）： 426-439 2012].
