The initial efficiency is a very important criterion for carbon anode material of Li-ion battery.The relationship between initial efficiency and structure parameters of carbon anode material of Li-ion battery was inve...The initial efficiency is a very important criterion for carbon anode material of Li-ion battery.The relationship between initial efficiency and structure parameters of carbon anode material of Li-ion battery was investigated by an artificial intelligence approach called Random Forests using D10,D50,D90,BET specific surface area and TP density as inputs,initial efficiency as output.The results give good classification performance with 91%accuracy.The variable importance analysis results show the impact of 5 variables on the initial efficiency descends in the order of D90,TP density,BET specific surface area,D50 and D10;smaller D90 and larger TP density have positive impact on initial efficiency.The contribution of BET specific surface area on classification is only 18.74%,which indicates the shortcoming of BET specific surface area as a widely used parameter for initial efficiency evaluation.展开更多
The modern transportation system is increasingly developed during recent years.It is an effective solution to set the noise barriers to reduce the traffic noise pollution caused by different kinds of transportation sy...The modern transportation system is increasingly developed during recent years.It is an effective solution to set the noise barriers to reduce the traffic noise pollution caused by different kinds of transportation systems.Many deficiencies on concrete noise barriers and metal noise barriers with rivet structure can be eliminated by a new kind of noise barrier with no-riveted structure.The mechanical performance examination and acoustic performance test are conducted on the new-designed noise barrier with no-riveted structure.The results indicate that the maximum stress is 1.74 MPa and the maximum deformation is 1.04 mm with load acting on the unit plate.The noise reduction coefficient of this kind of no-riveted noise barrier unit plate is 0.75 and its noise insulation is 40 dB,which were conform to or superior to the standard requirements.Therefore,this new designed noise barrier meets the field application requirements of mechanical and acoustic performance,which demonstrates the noise barriers can be widely promoted.展开更多
Compared with ordinary commercial products, housing has many special characteristics including the multi-function characteristic. How to evaluate the multi-functional nature of housing is very useful in both theory an...Compared with ordinary commercial products, housing has many special characteristics including the multi-function characteristic. How to evaluate the multi-functional nature of housing is very useful in both theory and in application, yet it is often ignored in China. This paper introduces an approach to estimate the multicriteria function of housing using multiattribute utility theory (MAUT) based on consumers’ ordinal multicriteria preferences as determined via questionnaires. When compared with the classic framework in which MAUT is applied, this approach needs less prior information and subjective comparisons and thus can allay many of the operational difficulties involved in assessment. Some potential applications to the China housing market are also discussed.展开更多
In this paper the optimal model of the main energy absorbed structure in an auto-body “front rail”, based on structural crashworthiness is built. For an optimal design on structure crashworthiness, the new method is...In this paper the optimal model of the main energy absorbed structure in an auto-body “front rail”, based on structural crashworthiness is built. For an optimal design on structure crashworthiness, the new method is based on a response surface model and Pareto GA, which improves the efficiency and flexibility of an optimal design, that is brought forward. The traditional optimal method can not be applied in the design of an impact structure due to the high nonlinearity and large time cost of crashworthiness FE analysis. So the method of an optimal design based on crashworthiness is brought forward. After constructing the response surface model of auto-body crashworthiness, the Pareto GA can be applied to find the multi-objective globally. The optimal solution set can then be used to provide many scheme combinations for choice structural parameters.To acquire the optimized structure parameters on front rail crashworthiness, this simplified model of an original design is built. After studying various ways of reinforcing the cross-section to control the structural failure mode, a better method has been found. On the precondition of not increasing the mass of the structure, an optimal design of the front rail is performed further. Finally, the optimized scheme is implemented in the full-car impact analysis and crashworthiness is studied. With proper measures to control deformation of the front rail structure the crashworthiness can be improved with minor structural modifications.展开更多
This paper presents an analytical foundation for probability-based formats for seismic design and assessment of structures. These formats are designed to be suitable for code and guideline implementation. The framewor...This paper presents an analytical foundation for probability-based formats for seismic design and assessment of structures. These formats are designed to be suitable for code and guideline implementation. The framework rests on non-linear, static seismic analysis. The formats can be used to ensure that the structural seismic design can be expected to satisfy specified probabilistic performance objectives, and perhaps (more novel) that it does so with a desired, guaranteed degree of confidence. Performance objectives are presumed to be expressed as the annual probability of exceeding a structural performance level. Structural performance levels are in turn defined as specified structural parameters (e.g., ductility, strength, maximum drift ratio, etc.) reaching a structural limit state (e.g. onset of yield, collapse, etc.). The degree of confidence in meeting the specified performance objective may be quantified through the upper confidence bound on the (uncertain) probability. In order to make such statements, aleatory (random) uncertainty and epistemic (knowledge limited) uncertainty must be distinguished. The single seismic design foundation can be formatted into the alternative conventional design methods such as LRFD design and fragility-hazard design. Versions of the new developments reported here are already in place in recently completed seismic guidelines.展开更多
Intelligent structures like zero Poisson’s ratio(ZPR)cellular structures have been widely applied to the engineering fields such as morphing wings in recent decades,owing to their outstanding characteristics includin...Intelligent structures like zero Poisson’s ratio(ZPR)cellular structures have been widely applied to the engineering fields such as morphing wings in recent decades,owing to their outstanding characteristics including light weight and low effective modulus. In-plane and out-of-plane mechanical properties of ZPR cellular structures are investigated in this paper. A theoretical method for calculating in-plane tensile modulus,in-plane shear modulus and out-of-plane bending modulus of ZPR cellular structures is proposed,and the impacts of the unit cell geometrical configurations on in-plane tensile modulus,in-plane shear modulus and out-of-plane bending modulus are studied systematically based on finite element(FE)simulation. Experimental tests validate the feasibility and effectiveness of the theoretical and FE analysis. And the results show that the in-plane and out-of-plane mechanical properties of ZPR cellular structures can be manipulated by designing cell geometrical parameters.展开更多
It is known that the seismic response of a structural system is highly influenced, in addition to the earthquake input, by the dynamic characteristics of the system itself. This paper presents an approach for the iden...It is known that the seismic response of a structural system is highly influenced, in addition to the earthquake input, by the dynamic characteristics of the system itself. This paper presents an approach for the identification of the characteristics of the structural system resisting to horizontal loads which enables to satisfy given seismic performance objectives. This is achieved by considering a total conceptual separation between the structural systems resisting to vertical and horizontal loads. The proposed approach is first briefly developed in general within a Performance-Based Seismic Design (PBSD) framework and then fully applied to the case study of a five-storey steel building structure. It is composed of three basic steps: (1) identification of the fundamental characteristics which should be possessed by the horizontal resisting system to satisfy a multiplicity of performance objectives, (2) development of a peculiar horizontal resisting system composed of "crescent shaped braces" which are specifically calibrated to satisfy given performance objectives, (3) verification, by means of appropriate time-history analyses, of the seismic performances achieved. In detail, the horizontal resisting system is calibrated to satisfy a multiplicity of performance objectives through the identification of an "objectives curve", in the Force-Displacement diagram, of the mechanical characteristics of the structure. The calibration is obtained by methods/tools borrowed either from Direct Displacement-Based Design (DDBD) or Force-Based Design (FBD), depending on the specific performance objective to be imposed. The applicative example has been carried out with reference to three performance objectives and has led to the identification of a horizontal resisting system composed of special bracing elements capable of realizing a sort of properly-calibrated seismic isolation called crescent-shaped braces. The results obtained through non-linear dynamic analyses have shown that the proposed approach leads to the congruity between the imposed and the achieved seismic performances.展开更多
Drainage layers provide permanent relief of hydrostatic water pressure, while the waterproof liner prevents any ingress of water into the tunnel. The durability and aging resistance of drainage membranes are of primar...Drainage layers provide permanent relief of hydrostatic water pressure, while the waterproof liner prevents any ingress of water into the tunnel. The durability and aging resistance of drainage membranes are of primary concern. This paper describes advantages and concerns related to the usage of, and the design with, polymeric drainboards in tunnel construction. Common degradation mechanisms associated with HDPE (high density polyethylene) sheets are described. The stringent requirements for the Gotthard Alpine Railway Tunnel through the Swiss Alps, e.g., high ambient temperatures of up to 45 ℃ and an expected service life of up to 100 years require outstanding aging resistance of polymeric drainage materials. The paper describes the methods deployed to investigate the long-term performance of HDPE drainboards, focusing on aging mechanisms. Details associated with the test procedures developed to reflect the specific properties of drainboards, as well as the results obtained, are presented. A summary table shows recommended product specifications needed to confine the aging properties of drainboards and to design a system performing adequately during the entire lifetime of the structure.展开更多
Ground motion intensity measure (IM) is an important part in performance-based seismic design. A reasonable and efficient IM can make the prediction of the structural seismic responses more accurate. Therefore, a more...Ground motion intensity measure (IM) is an important part in performance-based seismic design. A reasonable and efficient IM can make the prediction of the structural seismic responses more accurate. Therefore, a more reasonable IM for super high-rise buildings is proposed in this paper. This IM takes into account the significant characteristic that higher-order vibration modes play important roles in the seismic response of super high-rise buildings, as well as the advantages of some existing IMs. The key parameter of the proposed IM is calibrated using a series of time-history analyses. The collapse simulations of two super high-rise buildings are used to discuss the suitability of the proposed IM and some other existing IMs. The results indicate that the proposed IM yields a smaller coefficient of variation for the critical collapse status than other existing IMs and performs well in reflecting the contribution of higher-order vibration modes to the structural response. Hence, the proposed IM is more applicable to seismic design for super high-rise buildings than other IMs.展开更多
Both of planar and mesoporous architectures prevail for perovskite solar cells(PSCs).However,it is still an open question how the architecture affects the performance of PSCs.The inconsistent results in the references...Both of planar and mesoporous architectures prevail for perovskite solar cells(PSCs).However,it is still an open question how the architecture affects the performance of PSCs.The inconsistent results in the references often create confusion.In particular,the specific roles of mesoporous frameworks are yet to be well elaborated and require further clarification.In this study,we carefully compared the properties of perovskite films and the device performances for both architectures to unravel the roles of mesoporous TiO2 framworks in CH3NH3PbI3 PSCs.The detailed characterizations of structural,microscopic,optical and electrical properties revealed that the presence of mesoporous TiO2 framework contributed to enlarged perovskite crystal sizes,enhanced light harvesting,efficient electron extration and suppressed charge recombination.As a result,compared with the planar device,the mesoporous device yielded an improved power conversion efficiency of 18.18%,coupled with a reduced hystersis.This study reveals the benefits of mesoporous TiO2 framework in PSCs and provides the guidance for the design and optimization of architectures for high-performance devices.展开更多
As an im portant branch of fiber-shaped energy storage devices, the fiber-shaped supercapacitor has been widely studied recently. However, it remains challenging to simultaneously achieve fast electron transport and e...As an im portant branch of fiber-shaped energy storage devices, the fiber-shaped supercapacitor has been widely studied recently. However, it remains challenging to simultaneously achieve fast electron transport and excellent ion accessibility in one single fiber electrode of the fibershaped supercapacitor. Herein, a novel family of amphiphilic core-sheath structured carbon nanotube composite fibers has been developed and applied to the fiber-shaped supercapacitor to address the above challenge. The polyaniline-modified hydrophilic sheath of the composite fiber electrode effectively enhanced the electrochemical property via advancing ion accessibility, while Au-deposited hydrophobic core demonstrated improved electrical conductivity by fast electron supply. On the basis of a synergistic effect, a remarkable specific capacitance of 324 F cm^-3 at 0.5 A cm^-3 and greatly enhanced rate performance were achieved, i.e” a 79% retention (256 F cm 3) at 50 A cm^-3. The obtained fiber-shaped supercapacitor finally displayed remarkable energy and power densities of 7.2 mW h cm 3 and 10 W cm^-3, respectively. The strategy developed herein also presents a general pathway towards novel fiber electrodes for high-performance wearable devices.展开更多
π-Conjugated polymers(CPs)represent one of the quite important and rapidly growing branches of flexible electrochromic materials.Electrosynthesized hybrid CPs employing dibenzo pentacycles(fluorenes,carbazoles,dibenz...π-Conjugated polymers(CPs)represent one of the quite important and rapidly growing branches of flexible electrochromic materials.Electrosynthesized hybrid CPs employing dibenzo pentacycles(fluorenes,carbazoles,dibenzothiophenes,and dibenzofuran)as the backbones have received considerable attention owing to their special structures and interesting electrochromic performances.Recent studies show that polymers from these structures exhibit decent contrast ratios,favorable coloration efficiencies,low switching voltages,fast response time,excellent stability,and color persistence.Intrinsically,their electrochromic properties significantly depend on fine-tailoring of precursor monomer structures,and polymerization techniques and conditions.This review devotes to showing a clear picture of the research progress of dibenzo pentacycle-centered CPs via electrochemical polymerization,including fluorenes,carbazoles,dibenzothiophenes,and dibenzofuran-based hybrid electrochromic polymers.Critical influences of the tailored precursor structures on their electropolymerization and resultant polymer performances are highlighted,aiming at providing an insight for the development of novel fused ring-based polymer electrochromic materials.展开更多
A static and dynamic collaborative optimization method for materials and structure with uniform periodic microstructure is presented.The sensitivity formulae of hierarchical optimization,i.e.,material design,structure...A static and dynamic collaborative optimization method for materials and structure with uniform periodic microstructure is presented.The sensitivity formulae of hierarchical optimization,i.e.,material design,structure design and integrated design for porous metals,are given.On the base of the hierarchical optimization model,numerical experiments of an MBB beam and a cantilever one were carried out.Based on porous metals bearing multi-functionality,the differences and applicability of hierarchical optimization are discussed in the structure loading field.It is concluded that structure design is mainly oriented to structure efficiency,material design is mainly oriented to multi-functionality,and integrated design is oriented to structure efficiency and multi-functionality.This work provides some useful ideas for the selection of porous metals design method.展开更多
基金Project(2001AA501433)supported by the National High-Tech Research and Development Program of China
文摘The initial efficiency is a very important criterion for carbon anode material of Li-ion battery.The relationship between initial efficiency and structure parameters of carbon anode material of Li-ion battery was investigated by an artificial intelligence approach called Random Forests using D10,D50,D90,BET specific surface area and TP density as inputs,initial efficiency as output.The results give good classification performance with 91%accuracy.The variable importance analysis results show the impact of 5 variables on the initial efficiency descends in the order of D90,TP density,BET specific surface area,D50 and D10;smaller D90 and larger TP density have positive impact on initial efficiency.The contribution of BET specific surface area on classification is only 18.74%,which indicates the shortcoming of BET specific surface area as a widely used parameter for initial efficiency evaluation.
基金supported by the National Natural Science Foundation of China (No. 51768014).
文摘The modern transportation system is increasingly developed during recent years.It is an effective solution to set the noise barriers to reduce the traffic noise pollution caused by different kinds of transportation systems.Many deficiencies on concrete noise barriers and metal noise barriers with rivet structure can be eliminated by a new kind of noise barrier with no-riveted structure.The mechanical performance examination and acoustic performance test are conducted on the new-designed noise barrier with no-riveted structure.The results indicate that the maximum stress is 1.74 MPa and the maximum deformation is 1.04 mm with load acting on the unit plate.The noise reduction coefficient of this kind of no-riveted noise barrier unit plate is 0.75 and its noise insulation is 40 dB,which were conform to or superior to the standard requirements.Therefore,this new designed noise barrier meets the field application requirements of mechanical and acoustic performance,which demonstrates the noise barriers can be widely promoted.
文摘Compared with ordinary commercial products, housing has many special characteristics including the multi-function characteristic. How to evaluate the multi-functional nature of housing is very useful in both theory and in application, yet it is often ignored in China. This paper introduces an approach to estimate the multicriteria function of housing using multiattribute utility theory (MAUT) based on consumers’ ordinal multicriteria preferences as determined via questionnaires. When compared with the classic framework in which MAUT is applied, this approach needs less prior information and subjective comparisons and thus can allay many of the operational difficulties involved in assessment. Some potential applications to the China housing market are also discussed.
文摘In this paper the optimal model of the main energy absorbed structure in an auto-body “front rail”, based on structural crashworthiness is built. For an optimal design on structure crashworthiness, the new method is based on a response surface model and Pareto GA, which improves the efficiency and flexibility of an optimal design, that is brought forward. The traditional optimal method can not be applied in the design of an impact structure due to the high nonlinearity and large time cost of crashworthiness FE analysis. So the method of an optimal design based on crashworthiness is brought forward. After constructing the response surface model of auto-body crashworthiness, the Pareto GA can be applied to find the multi-objective globally. The optimal solution set can then be used to provide many scheme combinations for choice structural parameters.To acquire the optimized structure parameters on front rail crashworthiness, this simplified model of an original design is built. After studying various ways of reinforcing the cross-section to control the structural failure mode, a better method has been found. On the precondition of not increasing the mass of the structure, an optimal design of the front rail is performed further. Finally, the optimized scheme is implemented in the full-car impact analysis and crashworthiness is studied. With proper measures to control deformation of the front rail structure the crashworthiness can be improved with minor structural modifications.
文摘This paper presents an analytical foundation for probability-based formats for seismic design and assessment of structures. These formats are designed to be suitable for code and guideline implementation. The framework rests on non-linear, static seismic analysis. The formats can be used to ensure that the structural seismic design can be expected to satisfy specified probabilistic performance objectives, and perhaps (more novel) that it does so with a desired, guaranteed degree of confidence. Performance objectives are presumed to be expressed as the annual probability of exceeding a structural performance level. Structural performance levels are in turn defined as specified structural parameters (e.g., ductility, strength, maximum drift ratio, etc.) reaching a structural limit state (e.g. onset of yield, collapse, etc.). The degree of confidence in meeting the specified performance objective may be quantified through the upper confidence bound on the (uncertain) probability. In order to make such statements, aleatory (random) uncertainty and epistemic (knowledge limited) uncertainty must be distinguished. The single seismic design foundation can be formatted into the alternative conventional design methods such as LRFD design and fragility-hazard design. Versions of the new developments reported here are already in place in recently completed seismic guidelines.
基金supported by the National Natural Science Foundation of China(No.11872207)the Aeronautical Science Foundation of China (No. 20180952007)+1 种基金the Foundation of National Key Laboratory on Ship Vibration and Noise(No.614220400307)the National Key Research and Development Program of China (No.2019YFA708904)。
文摘Intelligent structures like zero Poisson’s ratio(ZPR)cellular structures have been widely applied to the engineering fields such as morphing wings in recent decades,owing to their outstanding characteristics including light weight and low effective modulus. In-plane and out-of-plane mechanical properties of ZPR cellular structures are investigated in this paper. A theoretical method for calculating in-plane tensile modulus,in-plane shear modulus and out-of-plane bending modulus of ZPR cellular structures is proposed,and the impacts of the unit cell geometrical configurations on in-plane tensile modulus,in-plane shear modulus and out-of-plane bending modulus are studied systematically based on finite element(FE)simulation. Experimental tests validate the feasibility and effectiveness of the theoretical and FE analysis. And the results show that the in-plane and out-of-plane mechanical properties of ZPR cellular structures can be manipulated by designing cell geometrical parameters.
文摘It is known that the seismic response of a structural system is highly influenced, in addition to the earthquake input, by the dynamic characteristics of the system itself. This paper presents an approach for the identification of the characteristics of the structural system resisting to horizontal loads which enables to satisfy given seismic performance objectives. This is achieved by considering a total conceptual separation between the structural systems resisting to vertical and horizontal loads. The proposed approach is first briefly developed in general within a Performance-Based Seismic Design (PBSD) framework and then fully applied to the case study of a five-storey steel building structure. It is composed of three basic steps: (1) identification of the fundamental characteristics which should be possessed by the horizontal resisting system to satisfy a multiplicity of performance objectives, (2) development of a peculiar horizontal resisting system composed of "crescent shaped braces" which are specifically calibrated to satisfy given performance objectives, (3) verification, by means of appropriate time-history analyses, of the seismic performances achieved. In detail, the horizontal resisting system is calibrated to satisfy a multiplicity of performance objectives through the identification of an "objectives curve", in the Force-Displacement diagram, of the mechanical characteristics of the structure. The calibration is obtained by methods/tools borrowed either from Direct Displacement-Based Design (DDBD) or Force-Based Design (FBD), depending on the specific performance objective to be imposed. The applicative example has been carried out with reference to three performance objectives and has led to the identification of a horizontal resisting system composed of special bracing elements capable of realizing a sort of properly-calibrated seismic isolation called crescent-shaped braces. The results obtained through non-linear dynamic analyses have shown that the proposed approach leads to the congruity between the imposed and the achieved seismic performances.
文摘Drainage layers provide permanent relief of hydrostatic water pressure, while the waterproof liner prevents any ingress of water into the tunnel. The durability and aging resistance of drainage membranes are of primary concern. This paper describes advantages and concerns related to the usage of, and the design with, polymeric drainboards in tunnel construction. Common degradation mechanisms associated with HDPE (high density polyethylene) sheets are described. The stringent requirements for the Gotthard Alpine Railway Tunnel through the Swiss Alps, e.g., high ambient temperatures of up to 45 ℃ and an expected service life of up to 100 years require outstanding aging resistance of polymeric drainage materials. The paper describes the methods deployed to investigate the long-term performance of HDPE drainboards, focusing on aging mechanisms. Details associated with the test procedures developed to reflect the specific properties of drainboards, as well as the results obtained, are presented. A summary table shows recommended product specifications needed to confine the aging properties of drainboards and to design a system performing adequately during the entire lifetime of the structure.
基金supported by "Twelfth Five-Year" plan major projects supported by National Science and Technology (Grant No.2011BAJ09B01)the National Nature Science Foundation of China (Grant Nos. 51222804, 51261120377)+1 种基金the Tsinghua University Initiative Scientific Research Program (Grant Nos. 2012THZ02-2, 2011THZ03) the Fok Ying Dong Education Foundation (Grant No. 131071)
文摘Ground motion intensity measure (IM) is an important part in performance-based seismic design. A reasonable and efficient IM can make the prediction of the structural seismic responses more accurate. Therefore, a more reasonable IM for super high-rise buildings is proposed in this paper. This IM takes into account the significant characteristic that higher-order vibration modes play important roles in the seismic response of super high-rise buildings, as well as the advantages of some existing IMs. The key parameter of the proposed IM is calibrated using a series of time-history analyses. The collapse simulations of two super high-rise buildings are used to discuss the suitability of the proposed IM and some other existing IMs. The results indicate that the proposed IM yields a smaller coefficient of variation for the critical collapse status than other existing IMs and performs well in reflecting the contribution of higher-order vibration modes to the structural response. Hence, the proposed IM is more applicable to seismic design for super high-rise buildings than other IMs.
基金financially supported by the National Natural Science Foundation of China(51602088)the Open Fund of the Key Laboratory of Photovoltaic and Energy Conservation Materials,Chinese Academy of Sciences(PECL2019KF007)and China Postdoctoral Science Foundation(2017T100313)。
文摘Both of planar and mesoporous architectures prevail for perovskite solar cells(PSCs).However,it is still an open question how the architecture affects the performance of PSCs.The inconsistent results in the references often create confusion.In particular,the specific roles of mesoporous frameworks are yet to be well elaborated and require further clarification.In this study,we carefully compared the properties of perovskite films and the device performances for both architectures to unravel the roles of mesoporous TiO2 framworks in CH3NH3PbI3 PSCs.The detailed characterizations of structural,microscopic,optical and electrical properties revealed that the presence of mesoporous TiO2 framework contributed to enlarged perovskite crystal sizes,enhanced light harvesting,efficient electron extration and suppressed charge recombination.As a result,compared with the planar device,the mesoporous device yielded an improved power conversion efficiency of 18.18%,coupled with a reduced hystersis.This study reveals the benefits of mesoporous TiO2 framework in PSCs and provides the guidance for the design and optimization of architectures for high-performance devices.
基金supported by the Ministry of Science and Technology (2016YFA0203302)the National Natural Science Foundation of China (21634003, 51573027, 51673043, 21604012, 21805044 and 21875042)+1 种基金Shanghai Science and Technology Committee (16JC1400702, 17QA1400400, 18QA1400700 and 18QA1400800)SHMEC (2017-01-07-00-07-E00062)
文摘As an im portant branch of fiber-shaped energy storage devices, the fiber-shaped supercapacitor has been widely studied recently. However, it remains challenging to simultaneously achieve fast electron transport and excellent ion accessibility in one single fiber electrode of the fibershaped supercapacitor. Herein, a novel family of amphiphilic core-sheath structured carbon nanotube composite fibers has been developed and applied to the fiber-shaped supercapacitor to address the above challenge. The polyaniline-modified hydrophilic sheath of the composite fiber electrode effectively enhanced the electrochemical property via advancing ion accessibility, while Au-deposited hydrophobic core demonstrated improved electrical conductivity by fast electron supply. On the basis of a synergistic effect, a remarkable specific capacitance of 324 F cm^-3 at 0.5 A cm^-3 and greatly enhanced rate performance were achieved, i.e” a 79% retention (256 F cm 3) at 50 A cm^-3. The obtained fiber-shaped supercapacitor finally displayed remarkable energy and power densities of 7.2 mW h cm 3 and 10 W cm^-3, respectively. The strategy developed herein also presents a general pathway towards novel fiber electrodes for high-performance wearable devices.
基金the National Natural Science Foundationof China(51303073,51463008,51572117)the Ganpo Outstanding Talents 555 projects(2013)+4 种基金the National Science Fund for Distinguished Young Scholars in Jiangxi Province,Key Project of Jiangxi Educational Committee(GJJ150795)the Natural Science Foundation of Jiangxi Province(20161BAB216130)Scientific Fund of Jiangxi Science & Technology Normal University(2014QNBJRC003)Jiangxi Science & Technology Normal University Program for Scientific Research Innovation Team (2015CXTD001)Scientific Research Foundation for Doctors in Jiangxi Science & Technology
文摘π-Conjugated polymers(CPs)represent one of the quite important and rapidly growing branches of flexible electrochromic materials.Electrosynthesized hybrid CPs employing dibenzo pentacycles(fluorenes,carbazoles,dibenzothiophenes,and dibenzofuran)as the backbones have received considerable attention owing to their special structures and interesting electrochromic performances.Recent studies show that polymers from these structures exhibit decent contrast ratios,favorable coloration efficiencies,low switching voltages,fast response time,excellent stability,and color persistence.Intrinsically,their electrochromic properties significantly depend on fine-tailoring of precursor monomer structures,and polymerization techniques and conditions.This review devotes to showing a clear picture of the research progress of dibenzo pentacycle-centered CPs via electrochemical polymerization,including fluorenes,carbazoles,dibenzothiophenes,and dibenzofuran-based hybrid electrochromic polymers.Critical influences of the tailored precursor structures on their electropolymerization and resultant polymer performances are highlighted,aiming at providing an insight for the development of novel fused ring-based polymer electrochromic materials.
基金supported by the National Basic Research Program of China ("973" Project) (Grant No. 2010CB832700)the Science and Technology Development Fundation of Academy of Engineering Physics(Grant No. 2008A0302011)
文摘A static and dynamic collaborative optimization method for materials and structure with uniform periodic microstructure is presented.The sensitivity formulae of hierarchical optimization,i.e.,material design,structure design and integrated design for porous metals,are given.On the base of the hierarchical optimization model,numerical experiments of an MBB beam and a cantilever one were carried out.Based on porous metals bearing multi-functionality,the differences and applicability of hierarchical optimization are discussed in the structure loading field.It is concluded that structure design is mainly oriented to structure efficiency,material design is mainly oriented to multi-functionality,and integrated design is oriented to structure efficiency and multi-functionality.This work provides some useful ideas for the selection of porous metals design method.