油气爆炸是海洋平台主要风险之一,基于爆炸风险的结构设计是设计技术发展趋势。该文梳理风险分析相关的技术法规、规范,总结了爆炸风险评估流程、结构抗爆性能评估方法及流程;以某浮式生产储卸油装置(floating production storage and o...油气爆炸是海洋平台主要风险之一,基于爆炸风险的结构设计是设计技术发展趋势。该文梳理风险分析相关的技术法规、规范,总结了爆炸风险评估流程、结构抗爆性能评估方法及流程;以某浮式生产储卸油装置(floating production storage and offloading unit,FPSO)海洋平台生活楼为依托对象,利用结构有限元分析软件,分别开展了筛选分析、强度水平分析和塑性水平分析,完成基于爆炸风险的生活楼结构性能评估;基于功能性、作业、生命安全这3个性能水平,开展不同爆炸风险水平的结构设计,得到满足各性能水平衡准的设计方案。展开更多
Three acceptor-donor-acceptor （A-D-A） small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d：2＇,3＇-d＇]benzo[1,2-b：4,5-b＇]dithiophene as the central building block, octyl cyanoacetate, 3-octylrhod...Three acceptor-donor-acceptor （A-D-A） small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d：2＇,3＇-d＇]benzo[1,2-b：4,5-b＇]dithiophene as the central building block, octyl cyanoacetate, 3-octylrhodanine and thiobarbituric acid as the end groups were designed and synthesized as donor materials in solution-processed photovoltaic cells （OPVs）. The impacts of these different electron withdrawing end groups on the photophysical properties, energy levels, charge carrier mobility, morphologies of blend films, and their photovoltaic properties have been systematically investigated. OPVs device based on DRDTBDT gave the best power conversion efficiency （PCE） of 8.34%, which was significantly higher than that based on DCAODTBDT （4.83%） or DTBDTBDT （3.39%）. These results indicate that rather dedicated and balanced consideration of absorption, energy levels, morphology, mobility, etc. for the design of small-molecule-based OPVs （SM-OPVs） and systematic investigations are highly needed to achieve high performance for SM-OPVs.展开更多
文摘油气爆炸是海洋平台主要风险之一,基于爆炸风险的结构设计是设计技术发展趋势。该文梳理风险分析相关的技术法规、规范,总结了爆炸风险评估流程、结构抗爆性能评估方法及流程;以某浮式生产储卸油装置(floating production storage and offloading unit,FPSO)海洋平台生活楼为依托对象,利用结构有限元分析软件,分别开展了筛选分析、强度水平分析和塑性水平分析,完成基于爆炸风险的生活楼结构性能评估;基于功能性、作业、生命安全这3个性能水平,开展不同爆炸风险水平的结构设计,得到满足各性能水平衡准的设计方案。
基金supported by the Ministry of Science and Technology(2014CB643502,2016YFA0200200)the Natural Science Foundation of China(21404060,51422304,91433101)
文摘Three acceptor-donor-acceptor （A-D-A） small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d：2＇,3＇-d＇]benzo[1,2-b：4,5-b＇]dithiophene as the central building block, octyl cyanoacetate, 3-octylrhodanine and thiobarbituric acid as the end groups were designed and synthesized as donor materials in solution-processed photovoltaic cells （OPVs）. The impacts of these different electron withdrawing end groups on the photophysical properties, energy levels, charge carrier mobility, morphologies of blend films, and their photovoltaic properties have been systematically investigated. OPVs device based on DRDTBDT gave the best power conversion efficiency （PCE） of 8.34%, which was significantly higher than that based on DCAODTBDT （4.83%） or DTBDTBDT （3.39%）. These results indicate that rather dedicated and balanced consideration of absorption, energy levels, morphology, mobility, etc. for the design of small-molecule-based OPVs （SM-OPVs） and systematic investigations are highly needed to achieve high performance for SM-OPVs.
