从准统一到分离:商事主体资格的回归路径——对商事登记行为的公私法性质解构

商事活动的开展离不开商事信用制度的建立,而作为商事信用表征的商事登记在我国商主体立法中占有重要的一席之地。从我国立法和实践的现状来看,商事主体资格登记和商事营业资格登记作为商事登记的两个重要方面存在定性不明、混淆不清、操作不统一的情形,而学者对其的讨论也大多集中在吊销营业执照的后果等实践性问题上,针对主体资格的回归和商事登记行为的公私法性质分析显得略有不足。因此有必要从我国商事资格登记准统一的立法模式出发,找到问题症结之所在,通过分离主义模式的构建和登记行为公私法性质的解构还原商事主体资格的本来面目。

理论的误读:论商事登记立法模式的重构

商事登记作为商事信用的表征,在商事活动的开展以及商主体立法中所处地位的重要性是不言而喻的。然而,从我国立法和实践的现状来看,作为商事登记两个组成部分,商事主体资格登记和商事营业资格登记却存在定性不明、混淆不清、操作不统一的情形。学者对其的讨论也大多集中在吊销营业执照的后果等实践性问题上,针对商事主体资格的定位以及商事登记立法模式的分析略显不足。因此有必要从我国商事资格登记流程的法律分析入手,找到现存立法模式症结之所在,通过从准统一到分离主义立法模式的构建和登记行为公私法性质的解构还原商事登记立法模式的应然形态。

Amorphous core-shell NiMoP@CuNWs rod-like structure with hydrophilicity feature for efficient hydrogen production in neutral media

Using interface engineering,a highly efficient catalyst with a shell@core structure was successfully synthesized by growing an amorphous material composed of Ni,Mo,and P on Cu nanowires(Ni-MoP@CuNWs).This catalyst only requires an overpotential of 35 mV to reach a current density of 10 mA cm^(-2).The exceptional hydrogen evolution reaction(HER)activity is attributed to the unique amorphous rod-like nature of NiMoP@CuNWs,which possesses a special hydrophilic feature,en-hances mass transfer,promotes effective contact between the electrode and electrolyte solution,and exposes more active sites during the catalytic process.Density functional theory revealed that the introduction of Mo weakens the binding strength of the Ni site on the catalyst surface with the H atom and promotes the desorption process of the H_(2) product significantly.Owing to its facile syn-thesis,low cost,and high catalytic performance,this electrocatalyst is a promising option for com-mercial applications as a water electrolysis catalyst.

Quantitative Effect of Soil Texture Composition on Retardation Factor of K^+ Transport

With six packed columns composed of < 1 μm and 5 μm～0.25 mm fractions from an Eum-Orthic An- throsol (Columns 1～6) and one column of the Eum-Orthic Anthrosol (Column 7), K～(+) transport experiments under the condition of saturated steady water flow were conducted to qualify the effects of soil texture com- position on the retardation factor (R) of K～(+) transport. The results showed that the retardation factor of K～ (+) transport in the tested soil columns greatly increased with increasing clay contents. In an attempt to use pedo-transfer function (PTF) approach in the solute transport study, a preliminary PTF was established through the six packed columns (Columns 1～6) with soil basic data including soil bulk density, volumet- ric water content and clay content to predict the retardation factor, and proved valid by the satisfactory prediction of R in Column 7.

Analysis of a functionally graded piezothermoelastic hollow cylinder

A long thick-walled hollow cylinder of piezothermoelastic materials was studied in this work. The gradient prop- erty of the piezoelectric parameter g31 was taken into account. The theory of elasticity was applied to obtain the exact solutions of the cylinder subjected simultaneously to thermal and electric loadings. As an application, these solutions have been success- fully used to study the inverse problems of the material. For comparison, numerical results have been carried out for both graded and double-layered cylinders.

The combined effects of lysozyme and ascorbic acid on microstructure and properties of zein-based films

Edible zein-based films containing lysozyme(LY) and ascorbic acid(AA) were developed in the presence of polyethylene glycol 400(PEG 400), the combined effects of LY and AA on the microstructure, mechanical properties and release properties of developed zein films were investigated in detail. The results of microstructure characterization indicated that zein-based films became compact and smooth, and LY aggregates were well distributed in the zein matrix because of the simultaneous addition of LY and AA. The results of mechanical tests showed that because of the synergistic effects of LY and AA on zein film, elongation at break of zein-based film could be up to 138%, which was 34.5 times higher than that of zein control film. LY release tests showed that when the concentration of AA was less than 3.1 mg·cm^(-2), the release rate of LY significantly decreased by 33.7%, and the total release increased by 80.6%. While the release profiles of AA showed that the release rate and total release of AA from the films containing LY increased by approximately 68.9% and 61.7% than the films without LY. Good antioxidant and sustained antimicrobial activities were found for the developed zein films.

Anatomy of composition and nature of plate convergence： Insights for alternative thoughts for terminal India-Eurasia collision

The pattern and timing of collision between India and Eurasia have long been a major concern of the international community. However, no consensus has been reached hitherto. To explore and resolve the disagreements in the Himalayan study,in this paper we begin with the methodology and basic principles for the anatomy of composition and nature of convergent margins,then followed by an effort to conduct a similar anatomy for the India-Eurasia collision. One of the most common patterns of plate convergence involves a passive continental margin, an active continental margin and intra-oceanic basins together with accreted terranes in between. The ultimate configuration and location of the terminal suture zone are controlled by the basal surface of the accretionary wedge, which may show fairly complex morphology with Z-shape and fluctuant geometry. One plausible method to determine the terminal suture zone is to dissect the compositions and structures of active continental margins. It requires a focus on various tectonic elements belonging to the upper plate, such as accretionary wedges, high-pressure(HP)-ultra-high-pressure(UHP) metamorphic rocks, Barrovian-type metamorphic rocks and basement nappes, together with superimposed forearc basins.Such geological records can define the extreme limits and the intervening surface separating active margin from the passive one,thus offering a general sketch for the surface trace of the terminal suture zone often with a cryptic feature. Furthermore, the occurrence of the cryptic suture zone in depth may be constrained by geophysical data, which, in combination with outcrop studies of HP-UHP metamorphic rocks, enables us to outline the terminal suture zone. The southern part of the Himalayan orogen records complicated temporal and spatial features, which are hard to be fully explained by the classic "two-plate-one-ocean" template,therefore re-anatomy of the compositions and nature for this region is necessitated. Taking advantage of the methodology and basic principles of plate convergence anatomy and synthesizing previous studies together with our recent research, we may gain new insights into the evolution of the Himalayan orogeny.(1) The Yarlung-Zangbo ophiolite is composed of multiple tectonic units rather than a single terminal suture zone, and a group of different tectonic units were juxtaposed against each other in the backstop of the Gangdese forearc.(2) The Tethyan Himalayan Sequence(THS) contains mélanges with typical block-in-matrix structures, uniform southwards paleocurrents and age spectra of detrital zircons typical of Eurasia continent. All of these facts indicate that the THS belonged to Eurasia plate before the terminal collision, emplaced in the forearc of the Gangdese arc.(3) The Greater Himalayan Crystalline Complex(GHC) and Lesser Himalayan Sequence(LHS) comprise complex components including eclogites emplaced into the GHC and the upper part of the LHS. Judging from the fact that HP-UHP metamorphic rocks are exhumed and emplaced in the upper plate, the GHC and the upper part of the LHS where eclogite occur should be assigned to the upper plate, lying above the terminal subduction zone surface. It is the very surface along which the continuous subduction of the India subcontinent occurred, therefore acting as the terminal, cryptic suture. From the suture further southward, the bulk rock associations of the LHS and Sub-Himalayan Sequence(Siwalik) show little affinity of mélange, probably belonging to the foreland system of the India plate. By the anatomy of tectonic features of all the tectonic units in the Himalayan orogen as well as the ages of the subduction-accretion related deformation, we conclude that the terminal India-Eurasia collision occurred after 14 Ma, the timing of the metamorphism of the eclogites emplaced into the upper plate. The development of rifts stretching in N-S direction in Tibet and tectonic events with the transition from sinistral to dextral movements in shear zones, such as the Ailaoshan fault in East Tibet, can coordinately reflect the scale and geodynamic influence of the India-Eurasia convergence zone.By conducting a detailed anatomy of the southern Himalayas, we propose a new model for the final collision-accretion of the Himalayan orogeny. Our study indicates that the anatomy of structures, composition, and tectonic nature is the key to a better understanding of orogenic belts, which may apply to all the orogenic belts around the world. We also point out that several important issues regarding the detailed anatomy of the structures, compositions and tectonic nature of the Himalayan orogeny in future.

Pt/Zn heterostructure as efficient air-electrocatalyst for long-life neutral Zn-air batteries

Neutral Zn-air batteries(ZABs) have attracted much attention due to the enhanced lifespan and stability.However, their development is suppressed by the poor catalytic properties of the air-electrocatalysts for oxygen reduction reaction(ORR) and oxygen evolution reaction(OER). Hence,the exploration of highly efficient electrocatalysts for neutral ZABs is critical. Herein, we designed an economical heterostructure of Pt nanoparticle-modified Zn nanoplates(Pt/Zn NPs). Compared with commercial Pt/C electrocatalyst, our Pt/Zn heterostructure exhibits comparable catalytic properties and ultrahigh stability in neutral media. The heterostructure can reduce the dosage of Pt and offer sufficient active sites,resulting in enhanced catalytic properties for ORR/OER in neutral media. When applied to neutral ZABs as air cathode,our heterostructure exhibits a high power density of 45 mW cm^(-2) and excellent stability of more than 850 cycles with negligible decay, making it the most efficient and robust one in neutral electrolyte. This approach opens a new avenue to strategically design catalysts with high activity for neutral ZABs, rendering them potential in portable and wearable electronic devices.

Temperature-controlled synthesis of heterostructured Ru-Ru_(2)P nanoparticles embedded in carbon nanofibers for highly efficient hydrogen production

Developing highly efficient,cost-effective,and stable electrocatalysts for hydrogen evolution reaction(HER)is of considerable importance but remains challenging.Herein,we report the fabrication of a robust Ru-based electrocatalyst,which comprises heterostructured Ru-Ru_(2)P nanoparticles that are embedded in the N,P-codoped carbon nanofibers(CNFs),through a synthetic strategy involving electrospinning and temperature-controlled pyrolysis treatment.The as-prepared Ru-Ru_(2)P catalyst(Ru-Ru_(2)P@CNFs)shows excellent HER catalytic activities with low overpotentials of 11 and 14 mV in acidic and alkaline media,respectively,to achieve a current density of 10 mA cm^(−2),which are superior to the individual components of pure Ru and Ru_(2)P catalysts.Density functional theory calculations demonstrate the existence of electronic coupling effect between Ru and Ru_(2)P at the heterointerfaces,leading to a well-modulated electronic structure with optimized hydrogen adsorption strength and enhanced electrical conductivity for efficient HER electrocatalysis.In addition,the overall synthetic strategy can be generalized for the synthesis of a series of transitional metal phosphide-based nanofibers,thereby holding a remarkable capacity for various potential applications.