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总有机碳/总氮分析法测定清开灵注射液生产过程中总氮含量 被引量:6
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作者 高晓燕 谷雪蔷 +2 位作者 范强 李娜 乔延江 《药物分析杂志》 CAS CSCD 北大核心 2006年第2期204-206,共3页
目的:建立清开灵注射液及其生产过程中各中间体总氮含量的快速测定方法。方法:使用岛津公司的总有机碳(totalorganic carbon,TOC)分析仪及其总氮(total nitrogen,TN)测定附件 TNM-1测定清开灵注射液及各中间体的总氮含量,载气(高纯度空... 目的:建立清开灵注射液及其生产过程中各中间体总氮含量的快速测定方法。方法:使用岛津公司的总有机碳(totalorganic carbon,TOC)分析仪及其总氮(total nitrogen,TN)测定附件 TNM-1测定清开灵注射液及各中间体的总氮含量,载气(高纯度空气)流速为150mL·min^(-1),燃烧管温度720℃,检测器为化学发光检测器。各样品同时用凯氏定氮法测定总氮含量,将2种方法测得的结果进行相关性分析,验证 TOC/TN 法测量总氮的可行性。结果:TOC/TN 法测得的总氮含量和凯氏定氮测得的结果具有良好的相关性(r=0.9999,n=12)。结论:TOC/TN 法测定总氮含量简单、快速、准确,可用于清开灵注射液生产过程中总氮含量的快速测定。 展开更多
关键词 有机碳/分析 清开灵注射液 凯氏定
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尿素总氮蒸馏法测定影响因素的探讨
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作者 张青林 《化肥标准化与质量监测》 2003年第1期21-23,共3页
关键词 尿素 蒸馏 测定 影响因素
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车用尿素快速分析方法——甲醛法 被引量:1
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作者 常大顺 李云 《清洗世界》 CAS 2021年第4期32-33,38,共3页
早在2013年国家环保部规定柴油车必须使用车用尿素来降低汽车尾气氮氧化物的排放,以避免汽车尾气长期排放加重环境污染。海洋石油富岛公司从2020年5月份开始生产车用尿素,年产能达到5万t。车用尿素的主要成分是尿素溶液与纯水混合的32.5... 早在2013年国家环保部规定柴油车必须使用车用尿素来降低汽车尾气氮氧化物的排放,以避免汽车尾气长期排放加重环境污染。海洋石油富岛公司从2020年5月份开始生产车用尿素,年产能达到5万t。车用尿素的主要成分是尿素溶液与纯水混合的32.5%(±0.7%)的尿素溶液。国家标准(GB29518—2013)中对于车用尿素中尿素含量的分析使用总氮法,总氮法存在样品消解时间长,分析时间长的问题,且样品在蒸馏过程中使用了浓度达到350g/L的浓碱,对安全和环保的危害大。因此,笔者将分析尿液中总氮的分析方法-甲醛法应用于车用尿素总氮的分析,不需要浓碱且分析时间短,通过对其分析过程大量实验数据总结以及与总氮法的比对、回收率测试,发现其准确度及精密度完全可以满足中控分析的需要。 展开更多
关键词 车用尿素 甲醛 总氮法 回收率 准确度 精密度
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Effect of Long-Term Fertilization on Organic Nitrogen Forms in a Calcareous Alluvial Soil on the North China Plain 被引量:16
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作者 JU Xiao-Tang LIU Xue-Jun +1 位作者 ZHANG Fu-Suo P. CHRISTIE 《Pedosphere》 SCIE CAS CSCD 2006年第2期224-229,共6页
In order to illustrate the change of nitrogen (N) supply capacity after long-term application of manure and chemical fertilizer, as well as to properly manage soil fertility through fertilizer application under the ... In order to illustrate the change of nitrogen (N) supply capacity after long-term application of manure and chemical fertilizer, as well as to properly manage soil fertility through fertilizer application under the soil-climatic conditions of the North China Plain, organic N forms were quantified in the topsoil with different manure and chemical fertilizer treatments in a 15-year fertilizer experiment in a Chinese calcareous alluvial soil. Soil total N (TN) and various organic N forms were significantly influenced by long-term application of chemical fertilizer and manure. TN, total hydrolysable N, acid-lnsoluble N, amino acid N and ammonium N in the soil increased significantly (P 〈 0.05) with increasing manure and fertilizer N rates, but were not influenced by increasing P rates. Also, application of manure or N fertilizer or P fertilizer did not significantly influence either the quantity of amino sugar N or its proportion of TN. Application of manure significantly increased (P 〈 0.05) hydrolysable unknown N, but adding N or P did not. In addition, application of manure or N fertilizer or P fertilizer did not significantly influence the proportions of different soil organic N forms. 展开更多
关键词 chemical fertilizer long-term fertilization MANURE North China Plain soil organic nitrogen forms
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A Modified HF-Kjeldahl Method for Determining Total Nitrogen in Soil 被引量:1
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作者 CHENBIYUN CHENGLILI 《Pedosphere》 SCIE CAS CSCD 1997年第4期375-378,共4页
关键词 fixed ammonium Kjeldahl-HF method total nitrogen
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Nutritional Aspects of Two Widely Consumed Wild Edible Mushrooms in Jordan
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作者 Ahmad Mohamad Almomany 《Journal of Life Sciences》 2013年第6期653-657,共5页
Two wild mushrooms frequently consumed in Jordan were collected form Jordan forests in spring 2012. Each sample was studied in the lab by taking measurements on the morphological structures of the cap, stem, and recor... Two wild mushrooms frequently consumed in Jordan were collected form Jordan forests in spring 2012. Each sample was studied in the lab by taking measurements on the morphological structures of the cap, stem, and recording gill's color, shape and dimensions. Also smell and taste for each fruiting structure were taken in consideration. Spore print for each sample was also defined. Spores of each mushroom were microscopically tested and measured. These mushrooms were identified as Pleurotus eryngi and Tricholoma terreum. The two mushrooms were evaluated for their physical properties, chemical and mineral composition. Contents of Ca, Na, K, Zn, Mn, Cu, Fe and Mg were determined. For each mushroom species two mixed samples were analyzed. Nitrogen content was detected with Kjeldahl method and protein content (%) was calculated by multiplying nitrogen content with the factor 4.38. The highest protein content calculated on oven dry weight basis was found in Pleurotus eryngi which was around 30.6%, while Tricholoma terreum contained lowest protein content (17.4%). Pleurotus eryngi accumulated trace elements at high ratios as for P, Ca and Na 0.99%, 0.65% and 0.57% respectively while Tricholoma terreum contained more K (5.1%) than the other wild mushroom. Total soluble carbohydrates (50.8%), crude fiber (13.4%) and ash (12.2%) percentages were higher in Tricholoma terreum than in Pleurotus eryngi. 展开更多
关键词 MUSHROOM PLEUROTUS TRICHOLOMA protein fat ash minerals.
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NMP废水的去除方法
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作者 何旭红 周国峰 《区域治理》 2023年第6期143-146,共4页
NPM废水是锂电池行业铁锂正极设备清洗废水的特征污染物,化学品中文名称:N-甲基吡咯烷酮,化学性质稳定,属于杂环类难降解污染物,其分子式为:C5H9NO。重要特点是COD浓度高,总氮浓度高,水量偏小。NPM废水的处理方法有:铁碳微电解法、光催... NPM废水是锂电池行业铁锂正极设备清洗废水的特征污染物,化学品中文名称:N-甲基吡咯烷酮,化学性质稳定,属于杂环类难降解污染物,其分子式为:C5H9NO。重要特点是COD浓度高,总氮浓度高,水量偏小。NPM废水的处理方法有:铁碳微电解法、光催化氧化法和生化法。 展开更多
关键词 NPM废水 微电解 光催化氧化 生化 去除
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