The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a const...The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a constant interfacial area cell with laminar flow were studied,just to elucidate the extraction mechanism and the mass transfer models.The data were analyzed in terms of pseudo-first-order constants.The effects of stirring speed,specific interfacial area and temperature on the extraction rate in both systems were discussed,suggesting that the extractions were mixed bulk phases-interfacial control process.Supported by the experimental data,the corresponding rate equations for Ce（Ⅳ） extraction system and Ce（Ⅳ）-F^- mixture extraction system were obtained.The experimental results indicated the rate-controlling step.The kinetics model was deduced from the rate-controlling step and consistent with the rate equation.展开更多
The hysteresis control combined with PWM control non-inverting buck-boost was proposed to improve the light load efficiency and power density.The constant inductor current control(CICC)was established to mitigate the ...The hysteresis control combined with PWM control non-inverting buck-boost was proposed to improve the light load efficiency and power density.The constant inductor current control(CICC)was established to mitigate the dependence on the external components and device variation and make smooth transition between hysteresis control loop and pulse width modulation(PWM)control loop.The small signal model was deduced for the buck and boost operation mode.The inductor current slope control(ICSC)was proposed to implement the automatic mode transition between buck and boost mode in one switching cycle.The results show that the converter prototype has good dynamic response capability,achieving 94%efficiency and 95%peak efficiency at full 10 A load current.展开更多
基金Project (2012CBA01202) supported by the National Basic Research Program of ChinaProject (51174184) supported by the National Natural Science Foundation of China+2 种基金Project (KGZD-EW-201-1) supported by the Key Research Program of the Chinese Academy of SciencesProject (BK2013030) supported by Science and Technology Plan of Nantong City,ChinaProject (RERU2014016) supported by Open Subject of Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,China
文摘The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a constant interfacial area cell with laminar flow were studied,just to elucidate the extraction mechanism and the mass transfer models.The data were analyzed in terms of pseudo-first-order constants.The effects of stirring speed,specific interfacial area and temperature on the extraction rate in both systems were discussed,suggesting that the extractions were mixed bulk phases-interfacial control process.Supported by the experimental data,the corresponding rate equations for Ce（Ⅳ） extraction system and Ce（Ⅳ）-F^- mixture extraction system were obtained.The experimental results indicated the rate-controlling step.The kinetics model was deduced from the rate-controlling step and consistent with the rate equation.
文摘The hysteresis control combined with PWM control non-inverting buck-boost was proposed to improve the light load efficiency and power density.The constant inductor current control(CICC)was established to mitigate the dependence on the external components and device variation and make smooth transition between hysteresis control loop and pulse width modulation(PWM)control loop.The small signal model was deduced for the buck and boost operation mode.The inductor current slope control(ICSC)was proposed to implement the automatic mode transition between buck and boost mode in one switching cycle.The results show that the converter prototype has good dynamic response capability,achieving 94%efficiency and 95%peak efficiency at full 10 A load current.
