The effects of SN5040 and polyethylene glycol(PEG) individually and in combination on the dispersion stability of nano-TiO2 aqueous suspension were investigated by ultraviolet-visible absorption spectroscopy. The ad...The effects of SN5040 and polyethylene glycol(PEG) individually and in combination on the dispersion stability of nano-TiO2 aqueous suspension were investigated by ultraviolet-visible absorption spectroscopy. The adsorption mechanism of these dispersants was detected by zeta potential, isothermal absorption and FTIR analysis. It is found that SN5040 is superior for stabilizing nano-TiO2 in aqueous suspension to PEG in basic region, and the optimum mass fraction of SN5040 addition is 3%. In the case of NaCl addition, the optimum value increases with .the increase of NaCl concentration in the solution. When the mixture of SN5040 and PEG is employed, the antagonism appears preponderant. When SN5040 and PEG are added sequentially, the synergistic reaction takes place. The synergistic reaction can be attributed to the mechanism that PEG adsorption decreases the electronic repulsion between SN5040 molecules, which results in the increase of SN5040 adsorption density. PEG is adsorbed by the interaction with the pre-adsorbed SN5040 layer. Furthermore, the modified inner wall latex paint with well dispersed nano-YiO2 suspension is endowed with excellent ultraviolet absorption and antibacterial properties.展开更多
This study aimed to explore the effect of 5% tembotrione oil dispersion(OD)-38% atrazine suspension concentrate(SC) tank mixture on the weeds in spring maize fields and the safety of the mixture. To be specific, rando...This study aimed to explore the effect of 5% tembotrione oil dispersion(OD)-38% atrazine suspension concentrate(SC) tank mixture on the weeds in spring maize fields and the safety of the mixture. To be specific, randomized block design was adopted for the field experiments. The results showed that the application of tankmixture of 5% tembotrione OD at 90 g a.i./hm^(2)and 38% atrazine SC at 570 g a.i./hm^(2)and the mixture of 5% tembotrione OD at 90 g a.i./hm^(2)and 38% atrazine SC at 1140 g a.i./hm^(2)respectively controlled 94.7%~96.3% and 94.0%~96.3% of the grass weeds, 94.7%~96.0% and 93.7%~95.7% fresh weight of grass weeds, 95.3%~96.3%and 93.3%~97.3% of broadleaf weeds, and 94.7%~96.0% and 93.3%~96.3% fresh weight of broadleaf weeds. The efficacy was better than that of the 5% tembotrione alone and the control herbicide and no phytotoxicity of the mixtures was identified.The tank mixture of tembotrione and atrazine should be promoted in the spring maize field for weed control and the recommended dosages were 90 g a.i./hm^(2)for 5%tembotrione and 570 g a.i./hm^(2)for 38% atrazine.展开更多
基金Project(04GK2007) supported by Hunan Industrial Key Project of Science and Technology
文摘The effects of SN5040 and polyethylene glycol(PEG) individually and in combination on the dispersion stability of nano-TiO2 aqueous suspension were investigated by ultraviolet-visible absorption spectroscopy. The adsorption mechanism of these dispersants was detected by zeta potential, isothermal absorption and FTIR analysis. It is found that SN5040 is superior for stabilizing nano-TiO2 in aqueous suspension to PEG in basic region, and the optimum mass fraction of SN5040 addition is 3%. In the case of NaCl addition, the optimum value increases with .the increase of NaCl concentration in the solution. When the mixture of SN5040 and PEG is employed, the antagonism appears preponderant. When SN5040 and PEG are added sequentially, the synergistic reaction takes place. The synergistic reaction can be attributed to the mechanism that PEG adsorption decreases the electronic repulsion between SN5040 molecules, which results in the increase of SN5040 adsorption density. PEG is adsorbed by the interaction with the pre-adsorbed SN5040 layer. Furthermore, the modified inner wall latex paint with well dispersed nano-YiO2 suspension is endowed with excellent ultraviolet absorption and antibacterial properties.
文摘This study aimed to explore the effect of 5% tembotrione oil dispersion(OD)-38% atrazine suspension concentrate(SC) tank mixture on the weeds in spring maize fields and the safety of the mixture. To be specific, randomized block design was adopted for the field experiments. The results showed that the application of tankmixture of 5% tembotrione OD at 90 g a.i./hm^(2)and 38% atrazine SC at 570 g a.i./hm^(2)and the mixture of 5% tembotrione OD at 90 g a.i./hm^(2)and 38% atrazine SC at 1140 g a.i./hm^(2)respectively controlled 94.7%~96.3% and 94.0%~96.3% of the grass weeds, 94.7%~96.0% and 93.7%~95.7% fresh weight of grass weeds, 95.3%~96.3%and 93.3%~97.3% of broadleaf weeds, and 94.7%~96.0% and 93.3%~96.3% fresh weight of broadleaf weeds. The efficacy was better than that of the 5% tembotrione alone and the control herbicide and no phytotoxicity of the mixtures was identified.The tank mixture of tembotrione and atrazine should be promoted in the spring maize field for weed control and the recommended dosages were 90 g a.i./hm^(2)for 5%tembotrione and 570 g a.i./hm^(2)for 38% atrazine.