A non equilibrium model for simulating suspension catalytic distillation of benzene and C 12 olefin has been set up It is shown that the simulation results are in good agreement with the experimental data, even though...A non equilibrium model for simulating suspension catalytic distillation of benzene and C 12 olefin has been set up It is shown that the simulation results are in good agreement with the experimental data, even though all parameters in the model have not been determined by fitting the simulation results with the展开更多
Suspension catalytic distillation (SCD) has been developed recently as an innovative technology in catalytic distillation. In this paper, a brief introduction to SCD is given and an equilibrium stage (EQ) modei is dev...Suspension catalytic distillation (SCD) has been developed recently as an innovative technology in catalytic distillation. In this paper, a brief introduction to SCD is given and an equilibrium stage (EQ) modei is developed to simulate this new process for synthesis of linear alkylbenzene (LAB) from benzene and 1-dodecene. Since non-ideality of this reaction systern is not strong, EQ modei developed could be applied to it successfully. Simulation results agree well with experimental data, and indicate some characteristics of SCD process as an advanced technology for the production of LAB: 100% conversion of olefins, low temperature (90-100℃) and low benzene/olefin mole ratio.展开更多
文摘A non equilibrium model for simulating suspension catalytic distillation of benzene and C 12 olefin has been set up It is shown that the simulation results are in good agreement with the experimental data, even though all parameters in the model have not been determined by fitting the simulation results with the
基金Major State Basic Research Development Program(No.G2000048006)
文摘Suspension catalytic distillation (SCD) has been developed recently as an innovative technology in catalytic distillation. In this paper, a brief introduction to SCD is given and an equilibrium stage (EQ) modei is developed to simulate this new process for synthesis of linear alkylbenzene (LAB) from benzene and 1-dodecene. Since non-ideality of this reaction systern is not strong, EQ modei developed could be applied to it successfully. Simulation results agree well with experimental data, and indicate some characteristics of SCD process as an advanced technology for the production of LAB: 100% conversion of olefins, low temperature (90-100℃) and low benzene/olefin mole ratio.
