Suspended emulsion polymerization of vinyl chloride was carried out in a 5 L autoclave. The influence of agitation, polymerization conversion, dispersant and surfactant on the average particle size (PS) and particle s...Suspended emulsion polymerization of vinyl chloride was carried out in a 5 L autoclave. The influence of agitation, polymerization conversion, dispersant and surfactant on the average particle size (PS) and particle size distribution (PSD), particle morphology and porosity of polyvinyl chloride (PVC) resin was investigated. It showed that the agitator had great influence on the smooth operation of polymerization, PS and PSD. The PS increased and PSD became narrow as polymerization conversion became high. The porosity decreased with the increase of conversion. A convenient choice of additives, both dispersants and non-ionic surfactants, allows one to adjust PS and PSD. The PS decreased with the addition of polyvinyl alcohol or hydroxypropyl methylcellulose dispersants,and increased with the addition of Span surfactants. The addition of dispersants or surfactants also affected the morphology and porosity of resin, and PVC resin with looser agglomeration and homogeneous distribution of primary particles was prepared.展开更多
The structural,energetic and electronic properties of chiral(n,m)(3≤n≤6,n/2≤m≤n)single-wall copper nanotubes(CuNTs)have been investigated by using projector-augmented wave method based on density-functional theory...The structural,energetic and electronic properties of chiral(n,m)(3≤n≤6,n/2≤m≤n)single-wall copper nanotubes(CuNTs)have been investigated by using projector-augmented wave method based on density-functional theory.The(4,3)CuNT is energetically stable and should be observed experimentally in both free-standing and tip-suspended conditions,whereas the(5,5)and(6,4)CuNTs should be observed in free-standing and tip-suspended conditions,respectively.The number of conductance channels in the CuNTs does not always correspond to the number of atomic strands comprising the nanotube.Charge density contours show that there is an enhanced interatomic interaction in CuNTs compared with Cu bulk.Current transporting states display different periods and chirality,the combined effects of which lead to weaker chiral currents on CuNTs.展开更多
Using Masson pine as specimens, when drying mediums are overheated steam and hot-air respectively, preheating characteristics of wood under vacuum-floating pressure drying are discussed by measurement of internal temp...Using Masson pine as specimens, when drying mediums are overheated steam and hot-air respectively, preheating characteristics of wood under vacuum-floating pressure drying are discussed by measurement of internal temperature field and variation of moisture content during period of preheating. The relationship between drying medium conditions and drying rate of wood reveals that, firstly, compared with process of air-drying, time needed to be preheated under vacuum-floating decreased dramatically, meanwhile,the magnitude of condensation on the surface is relatively larger. Secondly, drying rate of wood under vacuum-floating pressure increases coupled with temperature of medium, reduction of absolute pressure,and raise of fluctuation rate of pressure. The sequence of factors contribution to drying rate is listed as following: temperature of medium (t) > fluctuation rate of pressure (f)> absolute pressure (p).展开更多
基金Supported by the National Natural Science Foundation of China (No. 29906009).
文摘Suspended emulsion polymerization of vinyl chloride was carried out in a 5 L autoclave. The influence of agitation, polymerization conversion, dispersant and surfactant on the average particle size (PS) and particle size distribution (PSD), particle morphology and porosity of polyvinyl chloride (PVC) resin was investigated. It showed that the agitator had great influence on the smooth operation of polymerization, PS and PSD. The PS increased and PSD became narrow as polymerization conversion became high. The porosity decreased with the increase of conversion. A convenient choice of additives, both dispersants and non-ionic surfactants, allows one to adjust PS and PSD. The PS decreased with the addition of polyvinyl alcohol or hydroxypropyl methylcellulose dispersants,and increased with the addition of Span surfactants. The addition of dispersants or surfactants also affected the morphology and porosity of resin, and PVC resin with looser agglomeration and homogeneous distribution of primary particles was prepared.
基金supported by the State Key Development for Basic Research of China(Grant No.2010CB631002) the National Natural Science Foundation of China(Grant Nos.51071098,11104175 and 11214216)
文摘The structural,energetic and electronic properties of chiral(n,m)(3≤n≤6,n/2≤m≤n)single-wall copper nanotubes(CuNTs)have been investigated by using projector-augmented wave method based on density-functional theory.The(4,3)CuNT is energetically stable and should be observed experimentally in both free-standing and tip-suspended conditions,whereas the(5,5)and(6,4)CuNTs should be observed in free-standing and tip-suspended conditions,respectively.The number of conductance channels in the CuNTs does not always correspond to the number of atomic strands comprising the nanotube.Charge density contours show that there is an enhanced interatomic interaction in CuNTs compared with Cu bulk.Current transporting states display different periods and chirality,the combined effects of which lead to weaker chiral currents on CuNTs.
文摘Using Masson pine as specimens, when drying mediums are overheated steam and hot-air respectively, preheating characteristics of wood under vacuum-floating pressure drying are discussed by measurement of internal temperature field and variation of moisture content during period of preheating. The relationship between drying medium conditions and drying rate of wood reveals that, firstly, compared with process of air-drying, time needed to be preheated under vacuum-floating decreased dramatically, meanwhile,the magnitude of condensation on the surface is relatively larger. Secondly, drying rate of wood under vacuum-floating pressure increases coupled with temperature of medium, reduction of absolute pressure,and raise of fluctuation rate of pressure. The sequence of factors contribution to drying rate is listed as following: temperature of medium (t) > fluctuation rate of pressure (f)> absolute pressure (p).
