双惰性层包覆YOF纳米颗粒的荧光性能与细胞吞噬

为提升稀土基氟氧化物的荧光发射能力及细胞吞噬效果,采用双惰性层包覆工艺,同时利用功能性亲水聚合物进行表面修饰,制备获得YOF:Yb^(3+),Tm^(3+)@YOF:Yb^(3+)@mSiO_(2)-Py-FITC-β-CD纳米颗粒。使用透射电镜(TEM,含能谱分析)、紫外(UV-Vis)及荧光(PL)分光光度计、傅里叶变换红外光谱仪(FT-IR)及共聚焦激光扫描显微镜(CLSM)分别对试样的成分、形貌、荧光及细胞吞噬能力等进行表征。结果表明:双惰性层包覆的纳米颗粒尺寸范围30~35 nm,且具有较强的上转换荧光锐峰发射,在475 nm处(蓝色)荧光寿命可达58.696μs。样品在浓度较低时(50μg/mL)易被RAW264.7细胞大量吞噬。

动能侵彻弹装药起爆可靠性试验及敏感因素分析

为研究弹体结构设计对弹体装药起爆可靠性的影响,设计了一种低成本、便捷式引战静态匹配试验装置,开展了不同条件下引信与装药的传爆裕度试验。基于移动最小二乘法,构建了可表征起爆可靠性的多变量响应函数,定量分析了各敏感因素及其耦合作用对起爆可靠性的影响规律。结果表明:传爆间隙和缓冲层厚度对弹体装药起爆影响较大,而隔板厚度在预设3~5 mm范围内的影响较小;为保证动能侵彻弹在使用环境温度范围内可靠作用,引信相对偏离位置、隔板厚度、传爆间隙以及缓冲层厚度分别不应超过25、3.5、25以及22 mm。该试验装置、分析方法及研究成果可为动能侵彻弹结构设计及可靠性验证提供借鉴和指导。

利用乳糖酸的钝化效应提升K_(2)SiF_(6)∶Mn^(4+)的耐湿性

耐湿性差是掺Mn^(4+)氟化物红色荧光粉在高稳定性器件应用中面临的一个瓶颈问题。本工作提出利用乳糖酸的钝化效应清除K_(2)Si F_(6)∶Mn^(4+)表面的Mn^(4+),重构无Mn^(4+)的氟化物惰性壳层,以提升其耐湿性。结果表明,经乳糖酸钝化后的氟化物的晶相、形貌及发光强度几乎不变。水浸360 h后,钝化的氟化物的内量子效率为96.9%,远高于未处理的氟化物的59.8%。经乳糖酸处理,水解后的氟化物的内量子产率可以恢复到98.8%。在60 m A驱动电流下,将钝化后的氟化物作为红光成分,封装了相关色温为3518 K、显色指数为88.5、发光效率为130.61 lm·W^(-1)的暖白光LED。在高温(85℃)高湿(85%)环境中老化500 h后,该LED器件具有较高稳定性,光效可维持为初始值的90.5%,高于未经处理的氟化物所封装的白光器件(82.3%)。因此,简单的乳糖酸处理可以有效提升掺Mn^(4+)氟化物的耐湿性。本工作可为高稳定性氟化物红色荧光粉的工业化生产提供借鉴。

Irradiation Testing of Coated Particle Fuel at HANARO

TRISO （Tri-structural iso-tropic）-coated particle fuel is being developed to support the development of a VHTR （very high temperature reactor） in Korea. From August 2013, the first irradiation testing of coated particle fuel was begun to demonstrate and qualify TRISO fuel for use in the VHTR in HANARO （high-flux advanced neutron application reactor） at KAERI （Korea Atomic Energy Research Institute）. This experiment is currently undergoing under an atmosphere of a mixed inert gas without on-line temperature monitoring and control combined with on-line fission product monitoring of the sweep gas. The irradiation device contains two test rods, one contains nine fuel compacts and the other five compacts and eight graphite specimens. Each compact has 263 coated particles. After a peak bum-up of about 4% and a peak fast neutron fluence of about 1.7 × 1021 n/cm2, PIE （post irradiation examination） will be carried out at KAERI＇s irradiated material examination facility. This paper describes the characteristics of coated particle fuels, and the design of the test rod and irradiation device for the coated particle fuels, and discusses the technical results of irradiation testing at HANARO.