According to the action law of gas flow during injecting inert gases as the research main line, and hydromechanics and thermodynamics theories, the characteristic of gas delamination that was caused by injecting inert...According to the action law of gas flow during injecting inert gases as the research main line, and hydromechanics and thermodynamics theories, the characteristic of gas delamination that was caused by injecting inert gases to closed fire zone was analyzed. The criterion was brought forward, which could scale disappearing probability of turbulent state. Formation mechanism of gas layer in turbulent state was discussed primarily. Simultaneously, the condition was pointed out, which could makc the gas in turbulent state by injecting different gases. The mathematical model about dynamic changes of oxygen and methane concentration in the process of injecting gases was erected. The mixture mechanism about injecting different flow inert gases and flammable gas layer in closed fire zone was revealed.展开更多
Spontaneous combustion(sponcom) is one of the issues of concern with the blasting gallery(BG) method of coal mining and has the potential to cause fires, and impact on production and safety, greenhouse gas(GHG) emissi...Spontaneous combustion(sponcom) is one of the issues of concern with the blasting gallery(BG) method of coal mining and has the potential to cause fires, and impact on production and safety, greenhouse gas(GHG) emissions and huge costs involved in controlling the aftermath situations. Some of the research attempts made to prevent and control coal mine fires and spontaneous combustion in thick seams worked with bord and pillar mining methods are presented in this paper. In the study, computational fluid dynamics(CFD) modelling techniques were used to simulate and assess the effects of various mining methods, layouts, designs, and different operational and ventilation parameters on the flow of goaf gases in BG panels. A wide range of parametric studies were conducted to develop proactive strategies to control and prevent ingress of oxygen into the goaf area preventing spontaneous combustion and mine fires.展开更多
Consider a two-phase liquid-solid coupling effect, using Euler - Euler two-fluid model is solved using standard viscous term with k- e model and the velocity pressure coupling a simple algorithm to simulate liquid-sol...Consider a two-phase liquid-solid coupling effect, using Euler - Euler two-fluid model is solved using standard viscous term with k- e model and the velocity pressure coupling a simple algorithm to simulate liquid-solid two-phase flow characteristics of the fluid flow method bed, the applicability of the model to assess the drag. Different effects of a two-stage flow characteristics of fluidized bed flow characteristics, fluid and operating conditions affect the physical properties of the paper. We found from the simulation is the use of different drag coefficient models will greatly affect the results, which drag force model Syamlal - O＇ Brien is more suited to study the coupling characteristics of liquid flow in a fluidized bed of solid than Gidaspow. And velocity of the inert particles increase with the viscosity of the liquid increase. Further, the maximum speed of the inert particles in a fluidized bed by a central, which means the settling velocity in the fluidized bed of inert particles is the slowest; increasing liquid density and lead to increased speed of the inert particles; volume of the inert particles Score changes can also affect the speed of the particle velocity distribution, and there is no linear relationship.展开更多
DAR （diffusion absorption refrigeration） cycle is driven by heat and has no moving parts. It is based on refrigerant and absorbent as the working fluid together with hydrogen as an auxiliary inert gas. To circulate ...DAR （diffusion absorption refrigeration） cycle is driven by heat and has no moving parts. It is based on refrigerant and absorbent as the working fluid together with hydrogen as an auxiliary inert gas. To circulate the working fluid without a mechanical pump, the diffusion absorption cycle relies on a bubble pump. Experimental system was designed and operated. Its aim was to investigate the performance of a bubble pump operating with three lifting tubes. The experimental results of the system were compared to existing models. The comparison showed that there was a bad agreement between the experimental and the theoretical results.展开更多
The construction of transition metal-based catalysts with high activity and stability has been widely regarded as a promising method to replace the precious metal Pt for oxygen reduction reaction(ORR).Herein,we synthe...The construction of transition metal-based catalysts with high activity and stability has been widely regarded as a promising method to replace the precious metal Pt for oxygen reduction reaction(ORR).Herein,we synthesized CoFe alloy nanoparticle-embedded N-doped graphitic carbon(CoFe/NC)nanostructures as ORR electrocatalysts.The ZIF-67(zeolitic imidazolate framework,ZIF)nanocubes were first synthesized,followed by an introduction of Fe2+ions to form CoFe-ZIF precursors via a simple ion-exchange route.Subsequently,the CoFe/NC composites were synthesized through a facile pyrolysis strategy.The ORR activity and the contents of cobalt and iron could be effectively adjusted by controlling the solution concentration of Fe2+ions used for the ion exchange and the pyrolysis temperature.The CoFe/NC-0.2-900 composite(synthesized with 0.2 mmol of FeSO4·7H2O at a pyrolysis temperature of 900℃)exhibited ORR activity that was superior to the other samples owing to a synergistic effect of the bimetal,especially considering the extremely high limiting current density of 6.4 mA cm^-2 compared with that of Pt/C(5.1 mA cm^-2).Rechargeable Zn-air batteries were assembled employing CoFe/NC-0.2-900 and NiFeP/NF(NiFeP supported on nickel foam(NF))as the catalysts for the discharging and charging processes,respectively,The above materials achieved reduced discharging and charging platforms,high power density,and prolonged cycling stability compared with conventional Pt/C+RuO2/C catalysts.展开更多
文摘According to the action law of gas flow during injecting inert gases as the research main line, and hydromechanics and thermodynamics theories, the characteristic of gas delamination that was caused by injecting inert gases to closed fire zone was analyzed. The criterion was brought forward, which could scale disappearing probability of turbulent state. Formation mechanism of gas layer in turbulent state was discussed primarily. Simultaneously, the condition was pointed out, which could makc the gas in turbulent state by injecting different gases. The mathematical model about dynamic changes of oxygen and methane concentration in the process of injecting gases was erected. The mixture mechanism about injecting different flow inert gases and flammable gas layer in closed fire zone was revealed.
文摘Spontaneous combustion(sponcom) is one of the issues of concern with the blasting gallery(BG) method of coal mining and has the potential to cause fires, and impact on production and safety, greenhouse gas(GHG) emissions and huge costs involved in controlling the aftermath situations. Some of the research attempts made to prevent and control coal mine fires and spontaneous combustion in thick seams worked with bord and pillar mining methods are presented in this paper. In the study, computational fluid dynamics(CFD) modelling techniques were used to simulate and assess the effects of various mining methods, layouts, designs, and different operational and ventilation parameters on the flow of goaf gases in BG panels. A wide range of parametric studies were conducted to develop proactive strategies to control and prevent ingress of oxygen into the goaf area preventing spontaneous combustion and mine fires.
文摘Consider a two-phase liquid-solid coupling effect, using Euler - Euler two-fluid model is solved using standard viscous term with k- e model and the velocity pressure coupling a simple algorithm to simulate liquid-solid two-phase flow characteristics of the fluid flow method bed, the applicability of the model to assess the drag. Different effects of a two-stage flow characteristics of fluidized bed flow characteristics, fluid and operating conditions affect the physical properties of the paper. We found from the simulation is the use of different drag coefficient models will greatly affect the results, which drag force model Syamlal - O＇ Brien is more suited to study the coupling characteristics of liquid flow in a fluidized bed of solid than Gidaspow. And velocity of the inert particles increase with the viscosity of the liquid increase. Further, the maximum speed of the inert particles in a fluidized bed by a central, which means the settling velocity in the fluidized bed of inert particles is the slowest; increasing liquid density and lead to increased speed of the inert particles; volume of the inert particles Score changes can also affect the speed of the particle velocity distribution, and there is no linear relationship.
文摘DAR （diffusion absorption refrigeration） cycle is driven by heat and has no moving parts. It is based on refrigerant and absorbent as the working fluid together with hydrogen as an auxiliary inert gas. To circulate the working fluid without a mechanical pump, the diffusion absorption cycle relies on a bubble pump. Experimental system was designed and operated. Its aim was to investigate the performance of a bubble pump operating with three lifting tubes. The experimental results of the system were compared to existing models. The comparison showed that there was a bad agreement between the experimental and the theoretical results.
基金the support of the National Natural Science Foundation of China (21771059, 21631004 and 21571054)the Natural Science Foundation of Heilongjiang Province (JJ2019YX0122)+1 种基金Heilongjiang Provincial Postdoctoral Science Foundation (LBH-Q16194)the excellent Youth Foundation of Heilongjiang University (JC201706)
文摘The construction of transition metal-based catalysts with high activity and stability has been widely regarded as a promising method to replace the precious metal Pt for oxygen reduction reaction(ORR).Herein,we synthesized CoFe alloy nanoparticle-embedded N-doped graphitic carbon(CoFe/NC)nanostructures as ORR electrocatalysts.The ZIF-67(zeolitic imidazolate framework,ZIF)nanocubes were first synthesized,followed by an introduction of Fe2+ions to form CoFe-ZIF precursors via a simple ion-exchange route.Subsequently,the CoFe/NC composites were synthesized through a facile pyrolysis strategy.The ORR activity and the contents of cobalt and iron could be effectively adjusted by controlling the solution concentration of Fe2+ions used for the ion exchange and the pyrolysis temperature.The CoFe/NC-0.2-900 composite(synthesized with 0.2 mmol of FeSO4·7H2O at a pyrolysis temperature of 900℃)exhibited ORR activity that was superior to the other samples owing to a synergistic effect of the bimetal,especially considering the extremely high limiting current density of 6.4 mA cm^-2 compared with that of Pt/C(5.1 mA cm^-2).Rechargeable Zn-air batteries were assembled employing CoFe/NC-0.2-900 and NiFeP/NF(NiFeP supported on nickel foam(NF))as the catalysts for the discharging and charging processes,respectively,The above materials achieved reduced discharging and charging platforms,high power density,and prolonged cycling stability compared with conventional Pt/C+RuO2/C catalysts.
