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不同氛围下烟草的热裂解行为研究 被引量:29
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作者 孔浩辉 鲁虹 +2 位作者 陈翠玲 周海云 周瑢 《分析测试学报》 CAS CSCD 北大核心 2010年第6期612-616,共5页
烟丝分别在He和空气环境中于600、700、800、900、1 000℃下进行热裂解,裂解产物用GC-MS进行在线检测,研究了烟丝样品分别在惰性和有氧氛围中不同温度下的热裂解行为。数据表明,烟丝在He气和空气中热裂解时的产物有较大差异,He气下的裂... 烟丝分别在He和空气环境中于600、700、800、900、1 000℃下进行热裂解,裂解产物用GC-MS进行在线检测,研究了烟丝样品分别在惰性和有氧氛围中不同温度下的热裂解行为。数据表明,烟丝在He气和空气中热裂解时的产物有较大差异,He气下的裂解产物以烯烃、苯和苯系物为主;在空气下裂解的主要产物为酮、醛、醇、酸和酯等羰基化合物。有氧氛围有益于异戊二烯和1,3-丁二烯的生成,但在一定程度上抑制了酚类物质的产生。在惰性和有氧氛围下,随着温度的升高,多环芳烃化合物的产生量均进一步增加。He氛围下得到的裂解产物类型接近卷烟燃烧时的热解区,而空气氛围下得到的裂解产物类型接近燃烧区。 展开更多
关键词 /气相色谱-质谱法 惰性裂解 有氧 烟丝 产物
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Effect of metallic content on mechanical property of Ni/(10NiO-NiFe_2O_4) cermets 被引量:4
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作者 李劼 张刚 +3 位作者 叶绍龙 赖延清 田忠良 孙小刚 《Journal of Central South University of Technology》 EI 2006年第4期347-352,共6页
Ni/ (10NiO-NiFe2O4) cermets were fabricated by using cold pressing-sintering method. The phase composition and effect of metallic content on the mechanical properties such as bending strength, Vickers’ hardness, fr... Ni/ (10NiO-NiFe2O4) cermets were fabricated by using cold pressing-sintering method. The phase composition and effect of metallic content on the mechanical properties such as bending strength, Vickers’ hardness, fracture toughness and thermal shock resistance were studied. The results show that the cermets consist of Ni, NiO and NiFe2O4. Within the range of metallic content from 0 to 17%(mass fraction), the relative density decreases with the increase of metallic content and the decrease of sintering temperature, Vickers’ hardness decreases from 7097MPa to 4814MPa and the bending strength increases from 110MPa to 157MPa, and the fracture toughness reaches the optimal value of 5.11MPa·m 1/2 at the metallic content of about 10%. The residual strength after thermal shock testing falls sharply as the thermal shock temperature difference is above 200℃.The cermets samples, whose metallic content is 10% and 15%, respectively, exhibit promising property of thermal shock resistance at 960℃ with six cycles of heating and quenching testing. 展开更多
关键词 aluminum electrolysis inert anode NIFE2O4 fracture toughness thermal shock resistance
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