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感应铁电极激发过单硫酸盐对罗丹明B的降解 被引量:1
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作者 高玉琼 宁寒 +2 位作者 饶妍彦 周金强 高乃云 《净水技术》 CAS 2022年第11期94-101,159,共9页
采用电化学氧化(EC)耦合铁板(IP)感应电极激发过单硫酸盐(PMS)降解水中有机染料罗丹明B(RhB)。该体系中,以IP作为感应电极,Ti-IrO_(2)/RuO_(2)作为阳极,不锈钢板作为阴极,考察了不同体系(EC、PMS、EC/IP、EC/PMS及EC/IP/PMS)、电流、PM... 采用电化学氧化(EC)耦合铁板(IP)感应电极激发过单硫酸盐(PMS)降解水中有机染料罗丹明B(RhB)。该体系中,以IP作为感应电极,Ti-IrO_(2)/RuO_(2)作为阳极,不锈钢板作为阴极,考察了不同体系(EC、PMS、EC/IP、EC/PMS及EC/IP/PMS)、电流、PMS投加量、溶液初始pH、无机阴离子(HCO_(3)^(-)、Cl^(-)、NO_(3)^(-)、H_(2)PO_(4)^(-))以及腐植酸对RhB降解的影响。结果表明:相比于其他体系,EC/IP/PMS体系能够有效地去除水中的RhB;RhB的降解率随着电流的增大而增加,PMS的最佳投加量为0.5 mmol/L,较低的溶液pH有利于RhB的降解;溶液中存在的HCO_(3)^(-)、NO_(3)^(-)、H_(2)PO_(4)^(-)以及腐植酸均对RhB降解有不同程度的抑制作用,而Cl^(-)对RhB降解有促进作用;通过加入不同的淬灭剂,确定了体系中主要存在的自由基;利用XPS对反应过程中产生的絮体进行了表征;此外,使用LC/TOF/MS识别出10种中间产物,并据此提出反应路径。 展开更多
关键词 感应铁电极 过单硫酸盐 罗丹明 B 硫酸根自由基 降解机理
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钛酸铅晶体反铁电相至电场感应铁电相相变的研究 被引量:1
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作者 韩代朝 李玉杰 陈红叶 《军械工程学院学报》 2007年第1期73-75,共3页
仔细研究了PbTiO3电场感应铁电相的晶体结构。在初始反铁电相中,各离子位移方向与极轴垂直,但在外电场感应下,Pb离子沿极轴方向有相同方向0.17h的位移,从而使晶体呈现铁电相特征,发生反铁电一铁电相变。此铁电相称之为电场感应铁... 仔细研究了PbTiO3电场感应铁电相的晶体结构。在初始反铁电相中,各离子位移方向与极轴垂直,但在外电场感应下,Pb离子沿极轴方向有相同方向0.17h的位移,从而使晶体呈现铁电相特征,发生反铁电一铁电相变。此铁电相称之为电场感应铁(EFI)电相。通过结构对称性分析,确定EFI铁电相的对称性是C2mm(G2v),用极矢量Ps作为序参量来描述相变时对称性的变化是合适的。 展开更多
关键词 电相 电场感应铁电相 对称性 序参量
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PbZrO3晶体反铁电相至电场感应铁电相相变的研究
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作者 韩代朝 蔡玉平 陈红叶 《中国材料科技与设备》 2006年第5期71-72,77,共3页
仔细研究了电场感应PbZrO3铁电相的晶体结构。在PbZrO3处于反铁电相时,各离子位移方向与极轴垂直。在外电场感应下,Pb离子沿极轴方向有相同方向0.17A的位移,从而使晶体呈现铁电相特征,发生反铁电-铁电相变。此铁电相称之为电场感... 仔细研究了电场感应PbZrO3铁电相的晶体结构。在PbZrO3处于反铁电相时,各离子位移方向与极轴垂直。在外电场感应下,Pb离子沿极轴方向有相同方向0.17A的位移,从而使晶体呈现铁电相特征,发生反铁电-铁电相变。此铁电相称之为电场感应铁电相(EFI,Electric—Field—Induced)。通过结构对称性分析,确定EFI铁电相的对称性是C2mm(G2v),用极矢量Ps作为序参量来描述相变时对称性的变化是合适的。 展开更多
关键词 电相 电场感应铁电相 对称性 序参量
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响应曲面法优化感应电芬顿预处理染料废水的运行参数 被引量:8
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作者 胡耀笛 张利 +3 位作者 刘松 孙梅香 刘会应 戴捷 《科学技术与工程》 北大核心 2017年第27期338-342,共5页
在传统电芬顿技术的基础上引入感应铁电极以改变Fe^(2+)的投加方式,构建了以铁板为感应阳极、不锈钢板为阳极、高纯度TiO_2镀膜石墨板为阴极的感应电芬顿体系。为探究感应电芬顿处理染料废水的最优运行参数及参数间的交互作用,采用响应... 在传统电芬顿技术的基础上引入感应铁电极以改变Fe^(2+)的投加方式,构建了以铁板为感应阳极、不锈钢板为阳极、高纯度TiO_2镀膜石墨板为阴极的感应电芬顿体系。为探究感应电芬顿处理染料废水的最优运行参数及参数间的交互作用,采用响应曲面法建立连续变量曲面模型,优化试验并确定最佳水平范围。结果显示,经模型优化后的最佳工艺条件为:反应时间80 min,pH 2.59,电流密度30 m A·cm^(-2),在此条件下进行三组平行实验,得出染料废水的COD去除率平均值达到70.1%,而模型预测值为73.17%,实测值与预测值相对偏差为3.07%,两者能较好地吻合。 展开更多
关键词 染料废水 感应电芬顿 感应铁电极 响应曲面法
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植物应答缺铁胁迫的分子生理机制及其调控 被引量:33
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作者 张妮娜 上官周平 陈娟 《植物营养与肥料学报》 CAS CSCD 北大核心 2018年第5期1365-1377,共13页
铁是植物生长发育中所必需的微量营养元素。虽然土壤中铁的丰度很高,但其生物有效性非常低,特别是在碱性石灰性土壤上,高pH和高重碳酸盐含量严重降低了土壤中铁的有效性。因此如何有效地提高植物对铁的利用效率及增强植物对缺铁胁迫的... 铁是植物生长发育中所必需的微量营养元素。虽然土壤中铁的丰度很高,但其生物有效性非常低,特别是在碱性石灰性土壤上,高pH和高重碳酸盐含量严重降低了土壤中铁的有效性。因此如何有效地提高植物对铁的利用效率及增强植物对缺铁胁迫的响应已成为目前该领域的研究热点。本文重点阐述了植物两种不同的铁吸收机制,以及对缺铁胁迫的应答反应;对目前所发现的植物中调控缺铁胁迫的相关基因进行了全面的综述,包括新发现的吞噬机理中所涉及的NRAMP基因;同时也介绍了感应铁缺乏的众多相关信号,包括植物激素、气体信号分子及microRNAs等;此外,还提出利用铁吸收相关基因的转导、控制铁吸收相关因子以及各种农艺措施的实施来提高植物铁的生物有效性从而有效缓解缺铁胁迫。最后对未来有关植物吞噬机制、铁缺乏感应信号及改善植物铁营养新途径等研究方向作了初步展望。 展开更多
关键词 植物 生理机制 胁迫 吸收基因 感应信号 营养
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响应曲面法优化新型电化学系统深度处理垃圾渗滤液生化出水 被引量:2
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作者 李虹雨 王可 +1 位作者 邢璇 夏建新 《环境化学》 CAS CSCD 北大核心 2018年第4期713-719,共7页
在以掺硼金刚石膜(boron-doped diamond,BDD)电极为阳极,碳毡材料为阴极的传统二维电化学系统中,在阴阳极板间引入感应铁电极,构建新型电化学系统,将系统用于垃圾渗滤液生化出水的深度处理研究.利用Box-Behnken(BBD)模型的响应曲面法(re... 在以掺硼金刚石膜(boron-doped diamond,BDD)电极为阳极,碳毡材料为阴极的传统二维电化学系统中,在阴阳极板间引入感应铁电极,构建新型电化学系统,将系统用于垃圾渗滤液生化出水的深度处理研究.利用Box-Behnken(BBD)模型的响应曲面法(response surface methodology,RSM),考察电流密度、电解时间、p H值对出水COD及氨氮去除率的交互作用影响,并建立相关数学模型.结果表明,影响因子显著性顺序依次为:电解时间>电流密度>p H,模型回归性好,预测最大COD去除率为79.5%,氨氮去除率为97.8%,最佳实验条件为:电流密度0.1 A·cm-2,电解时间8.86 h,p H 10.86,实测结果为COD去除率78.0%,与预测值相比偏差为1.8%,氨氮去除率为94.2%,与预测值偏差为3.7%.由此可知,经响应曲面法优化后的实验方案可保证新型电化学系统处理垃圾渗滤液研究达到良好处理效果. 展开更多
关键词 响应曲面法 电化学氧化 BDD阳极 感应铁电极 垃圾渗滤液
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八嘴包装机作业过程控制和常见故障机电分析 被引量:1
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作者 林存平 王福宝 杨辉 《水泥工程》 CAS 2012年第6期62-64,共3页
简要介绍了八嘴回转式包机的结构组成和控制系统等基本概况;并对其作业过程控制功能——自动灌装、无袋不灌装、中途掉袋停止灌装、一圈装不满二次灌装、一圈装满后停止灌装、不到掉袋位置不掉袋等进行了一一分析;并从电气及机械相互结... 简要介绍了八嘴回转式包机的结构组成和控制系统等基本概况;并对其作业过程控制功能——自动灌装、无袋不灌装、中途掉袋停止灌装、一圈装不满二次灌装、一圈装满后停止灌装、不到掉袋位置不掉袋等进行了一一分析;并从电气及机械相互结合角度,就常见故障查找原因的方法进行了介绍。这是一种介于机械、电气之间的新型分析方法,能够快速有效地处理各类故障。 展开更多
关键词 八嘴包装机 灌装 感应铁 控制电路
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Influence of DSP controller on performance of a permanent magnet brushless AC drive in flux-weakening mode
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作者 HOWE D. 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第2期83-89,共7页
The flux-weakening performance of a permanent magnet brushless AC drive was investigated using both floating-point and fixed-point DSP controllers. A significant current oscillation was observed when the drive was ope... The flux-weakening performance of a permanent magnet brushless AC drive was investigated using both floating-point and fixed-point DSP controllers. A significant current oscillation was observed when the drive was operated at high-speed in the flux-weakening mode with the fixed-point DSP. The investigation showed that this was due to the on-line compensation of the winding resistance voltage drop and quantisation errors associated with the fixed-point architecture of the DSP. A simple look-up table scheme is proposed to eliminate the oscillation and to achieve extended flux-weakening capability. 展开更多
关键词 Brushless drive DSP Electrical machine FLUX-WEAKENING OSCILLATION QUANTISATION
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Characterization of acylated homoserine lactone derivatives and their influence on biofilms of Acidithiobacillus ferrooxidans BY-3 under arsenic stress 被引量:1
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作者 GAO Qi-yu TANG De-ping +2 位作者 SONG Peng ZHOU Jian-ping LI Hong-yu 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第1期52-63,共12页
Quorum sensing is one kind of cell-to-cell signalling system among microorganisms that works in response to their population density via autoinducers exemplified by AHL and oligopeptides. In this study, fourteen AHL d... Quorum sensing is one kind of cell-to-cell signalling system among microorganisms that works in response to their population density via autoinducers exemplified by AHL and oligopeptides. In this study, fourteen AHL derivatives were synthesised by a chemical synthesis method, and two types of AHL derivatives were measured and screened by crystal violet staining assay, which have more obvious inhibitory effects on A. ferrooxidans biofilms under arsenic environment. Their structures were verified through IR and NMR identification. The morphological changes of A. ferrooxidans under the influence of the AHL derivatives were compared. In addition, the effects of AHL derivatives(0.1 μg/mL and 1 μg/mL) on membrane formation of A. ferrooxidans under high concentration of arsenic resistance(1,600 mg/L) were explored. Solid experimental data firstly showed that a portion of logarithmic microorganisms were ruptured under the effect of high arsenic concentration. Secondly, the volume of the cell shrank and the number of extracellular polymeric substances decreased after the addition of the AHL derivatives at high concentrations. Therefore, we found here that two derivatives used at concentrations of 0.1 μg/mL and 1 μg/m L accompanied with high concentration of arsenic can both effectively restrict biofilms formation by A. ferrooxidans. 展开更多
关键词 acetylated homoserine lactone chemical synthesis Acidithiobacillus ferrooxidans Quorum sensing arsenic contamination
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Effect of Fe content on microstructure and mechanical properties of Cu-Fe-based composite coatings by laser induction hybrid rapid cladding 被引量:1
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作者 Sheng-feng ZHOU Jian-bo LEI +3 位作者 Zheng XIONG Jin-bo GUO Zhen-jie GU Hong-bo PAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第12期3196-3204,共9页
To select the proper composition and obtain an overall material?microstructure?property relationship for Cu?Fe alloy, theeffect of Fe content on microstructure and properties of Cu?Fe-based composite coatings by laser... To select the proper composition and obtain an overall material?microstructure?property relationship for Cu?Fe alloy, theeffect of Fe content on microstructure and properties of Cu?Fe-based composite coatings by laser induction hybrid rapid claddingwas investigated. Microstructure characterization of the composite coatings was tested utilizing SEM, XRD and EDS. Microhardnessmeasurement was executed to evaluate the mechanical properties of the composite coatings. The results show that for low Fe content,the composite coating presents a feature that Fe-rich equiaxed dendrites are embedded in the Cu-rich matrix. With increasing Fecontent, the Fe-rich particles are dispersed in the Cu-rich matrix. With further increasing Fe content, large amounts of Cu-richparticles are homogeneously dispersed in the interdendrite of the Fe-rich matrix. Correspondingly, the average microhardness of thecomposite coatings increases gradually with the increase of Fe content and the microhardness of Cu14.5Fe83Si2C0.5 coating is muchtwice higher than that of the substrate. 展开更多
关键词 composite coating laser induction hybrid rapid cladding Cu.Fe alloy liquid phase separation microstructure mechanical properties
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Analysis of Differences in Inductance of Ni-Cu-Zn Ferrite Chip Inductors during the Plating Process
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作者 Yin-Lai Chai Shih-Feng Chien +3 位作者 Wen-Hsi Lee Chin-Pei Lin Wen-Yu Lin Pei-Yi Wei 《Journal of Chemistry and Chemical Engineering》 2014年第12期1125-1134,共10页
Although plating is a necessary process for SMT components, it alters the magnetic characteristics and inductance level of Ni-Cu-Zn ferrite components. The results of this work show that the following three factors in... Although plating is a necessary process for SMT components, it alters the magnetic characteristics and inductance level of Ni-Cu-Zn ferrite components. The results of this work show that the following three factors in plating affect these components, and the effects are different for Ni- and Sn-plating: (1) Plating layers exert stresses and react with the residual stress of components to change the inductance level, and the effect of the tin layer is greater than that of the nickel one; (2) The plating current induces a magnetic field inside the components directly and indirectly, and this remains as remanence inside the components and reduces the inductance level, and the effect level of Ni-plating is greater than that of Sn-plating; (3) The plating solution corrodes the interface of the termination and ferrite core of the components to release the residual stress, and causes an increase in inductance, and the effect of Sn-plating is greater than that of Ni-plating. In addition, the inductance level is the result of the net effect of these three factors, and if the sintering temperature is increased to change in the type of residual stress, the net effect will be changed. 展开更多
关键词 PLATING FERRITE STRESS INDUCTORS
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Ferrimagnetic Properties of Bond Dilution Mixed Blume-Capel Model with Random Single-Ion Anisotropy
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作者 LIU Lei YAN Shi-Lei 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第4X期743-748,共6页
We study the ferrimagnetic properties of spin 1/2 and spin-1 systems by means of the effective field theory. The system is considered in the framework of bond dilution mixed Blume-Capel mode/ (BCM) with random singl... We study the ferrimagnetic properties of spin 1/2 and spin-1 systems by means of the effective field theory. The system is considered in the framework of bond dilution mixed Blume-Capel mode/ (BCM) with random single-ion anisotropy. The investigation of phase diagrams and magnetization curves indicates the existence of induced magnetic ordering and single or multi-compensation points. Special emphasis is placed on the influence of bond dilution and random single-ion anisotropy on normal or induced magnetic ordering states and single or multi-compensation points. Normal magnetic ordering states take on new phase diagrams with increasing randomness (bond and anisotropy), while anisotropy induced magnetic ordering states are always occurrence no matter whether concentration of anisotropy is large or small. Existence and disappearance of compensation points rely strongly on bond dilution and random singleion anisotropy. Some results have not been revealed in previous papers and predicted by Néel theory of ferrimagnetism. 展开更多
关键词 ferrimagnetic property mixed Blume-Capel model induced magnetic ordering compensation point bond dilution and random single-ion anisotropy
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Effect of catalytic activities of mixed nano ferrites of zinc and copper on decomposition kinetics of lanthanum oxalate hydrate
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作者 H.NAYAK 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第3期767-774,共8页
Nanostructured zinc-copper mixed ferrite was synthesized using sol-gel method. Different compositions of ferrite, Zn_((1-x))Cu_xFe_2O_4(x=0.0, 0.25, 0.50, 0.75), characterized by XRD, reveal single phase inverse spine... Nanostructured zinc-copper mixed ferrite was synthesized using sol-gel method. Different compositions of ferrite, Zn_((1-x))Cu_xFe_2O_4(x=0.0, 0.25, 0.50, 0.75), characterized by XRD, reveal single phase inverse spinel in all the samples. With increasing copper content, the crystallite size increases. The surface morphology of all the samples, studied by SEM, shows porous structure of particles. The prepared samples were also analyzed by FT-IR and TEM. Catalytic activity of the samples was studied on lanthanum oxalate decomposition by thermogravimety.The rate constant k has the highest value with x=0.75 and 5%(mole fraction) of the catalyst and is attributed to high copper content, the mixed sites Cu^(2+)-Fe^+ and/or Cu^+-Fe^(2+) ion pairs besides the one component sites Cu^(2+)-Cu^+, Fe^(3+)-Fe^(2+), as a result of mutual charge interaction. In other words, the increasing activity of mixed oxides is attributed to increase in the content of active sites via creation of new ion pairs. With increasing Zn content, particle size increases. Variation of catalytic activity of ferrite powders is due to the changes of the valence state of catalytically active components of the ferrites, which oxidizes the carbon monoxide released from lanthanum oxalate. 展开更多
关键词 mixed ferrite SPINEL valence induction catalyst activity rate constant lanthanum oxalate
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A Study on an Airgap Control System in a Rotary-Small-Scaled Linear Induction Motor for Railway Vehicles
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作者 C.B. Park B.S. Lee 《Journal of Energy and Power Engineering》 2011年第12期1193-1198,共6页
In general, it is important to operate the; airgap length uniformly for improving the system efficiency independent of the flatness of the reaction plate in a railway propulsion system by a linear induction motor (LI... In general, it is important to operate the; airgap length uniformly for improving the system efficiency independent of the flatness of the reaction plate in a railway propulsion system by a linear induction motor (LIM). And it is possible to operate the LIM propulsion system efficiently without a change of the LIM capacity through the airgap length control on the sloped rail. So, in this research, the authors introduce an airgap control system to control the airgap length which depends on the flatness of the secondary reaction plate when the LIM is operated, and design a rotary small-scaled LIM and its airgap control system before manufacturing the real system. Then, the authors analyze some characteristics of the LIM (thrust and normal force, input current, efficiency and power factor), and through the LIM control modeling, the authors finally analyze an effect of the airgap-length control of the LIM by the airgap control system. 展开更多
关键词 Airgap control system linear induction motor PROPULSION railway vehicles.
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Design and Test of Inductive Adder Pulse Generator for KickerMagnet 被引量:2
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作者 刘超 尚雷 +1 位作者 刘祖平 郭亮 《Chinese Physics C》 SCIE CAS CSCD 北大核心 2008年第z1期40-42,共3页
The cell circuit design and test of inductive adder pulse generator for kicker magnet are presented in the paper.The 3.3kV IGBT,a large dimension nanocrystalline core and a 2.5kV 50uF energy storage capacitor are used... The cell circuit design and test of inductive adder pulse generator for kicker magnet are presented in the paper.The 3.3kV IGBT,a large dimension nanocrystalline core and a 2.5kV 50uF energy storage capacitor are used. The multi-channel trigger IGBT driver board is designed.IGBT failures under short circuit condition and protection scheme are explored.The multi-cell prototype is designed.The waveforms of experiments are presented.It turns out that the rise and fall time of the output pulse is fast and the pulse width is adjustable.The maximum current of pulse reaches 2kA.It satisfies the higher requirement of beam injection technology. 展开更多
关键词 pulse generator CPLD solid state modulator inductive adder kicker
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